scholarly journals Status of Surface Water from Selected Areas of Coastal Guyana and the Removal of Toxic Contaminants, using a Suitable Adsorbent

This study was done, to compare the status of surface water taken from two different locations within the coastal areas of Guyana, before and after treatment with a peanut biomass adsorbent. The water samples were collected from Parika Bushy Park and Vreed En Hoop and stored in water bottles. It was then submitted for physical and chemical analyses using versatile standard methods. These include test for heavy metals cations (Pb, Fe, Zn, Cd, and Al), test for anions (chlorides, sulphates, phosphates) along with the physical parameters (turbidity and conductivity). There was no detection for the toxic lead and cadmium cations at either surface water. The adsorbent was effective in removing Fe<sup>2+</sup> at both surface water as there was a decrease in concentration. For example, at Vreed En Hoop surface water, the concentration of Fe<sup>2+</sup> decrease from (8.42 ± 2.14 mg/L) to (5.56± 3.42 mg/L), 33.96% reduction, after treatment with the adsorbent. For the Al<sup>3+</sup> cation, there was a decrease in the concentration of Al<sup>3+</sup> from (5.97 ± 0.67mg/L) to (4.20 ± 1.90 mg/L ), 29.65%. For the SO<sub>4</sub><sup>2-</sup> and Cl- anions, there was a decrease in concentration at the Vreed En Hoop surface water, after treatment with the adsorbent. With SO42-, the concentration decrease from 346 ± 3.15 mg/L to 293 ± 1.77 mg/L, 15.31%, whilst that for chloride, Cl-, decrease from 116 ± 1.75 mg/L to 102 ± 1.70 mg/L, 12.07% reduction. Thus, the peanut shell should find application in the removal of selective cations and anions from surface water.

Author(s):  
Krzysztof Pulikowski ◽  
Stanisław Kostrzewa ◽  
Julian Paluch ◽  
Szymon Szewrański

Load of heavy metals in drainage waters in the Middle Sudety Mountains Research were carried out in study site located in Stare Bogaczowice near Wałbrzych. The daily drainage runoff measurements and periodical chemical analyses of water samples from selected drainage plots had been made. Concentrations of heavy metals: Cu, Zn, Zn, Pb, Cr i Cd had been measured. Drainage waters do not include significant amounts of heavy metals. Concentration of zinc, which is very common in nature, ranged from 0.018 to 0.675 mg Zn·dm-3, cadmium concentrations was somewhat larger then 0.001 mg Cd · dm-3. In spite of precipitations higher then in the other sites and because of low concentrations, the heavy metal loads had been very small. Regarding lead and nickel load did not exceed 70 g·ha-1·yr-1, and concerning copper, chromium and cadmium it was below 5.0 g·ha-1·yr-1. Heavy metals in drainage waters do not make serious threat on surface water body receivers.


1996 ◽  
Vol 118 (3) ◽  
pp. 681-686 ◽  
Author(s):  
Re´my Mas ◽  
Albert Magnin

Lithium soap and calcium complex soap-based lubricating greases are studied when fresh and after use in roller and ball bearings. Examination of the rheological properties of these greases using rotating rheometers reveals changes that have occurred during use in the bearings. These modifications are not uniform throughout the hearing. Physical and chemical analyses enable these modifications in rheological properties to be linked to variations in composition or structure, depending on the type of grease and bearing. Several mechanisms involved in lubricating a bearing with a lubricating grease are confirmed or clarified.


2018 ◽  
Vol 30 ◽  
pp. 01009
Author(s):  
D. Pietrzak ◽  
O. Mandryk ◽  
K. Wątor ◽  
E. Kmiecik ◽  
A. Zelmanowych

The article presents the results of the research carried out in order to assess the possibility of using surface water of the Bystrytsya-Nadvirnyans'ka River in Cherniiv (western Ukraine), for the public supply of water intended for human consumption. For this purpose an existing database that contains the results of analyses of surface water samples collected in 1999, 2002, 2005, 2008, 2011 and 2014 was used. Each year, from 8 to 13 samples were collected from the Bystrytsya-Nadvirnyans'ka River in Cherniiv. Physicochemical analyses of the samples taken included the determination of pH value, temperature, TDS, alkalinity, hardness, dissolved oxygen, BOD5, COD, suspended solids and ions: Ca2+, Mg2+, Na+, K+, Fe2+, NH4+, Cu2+, Cl-, SO42-, PO43-, HCO3-, NO2-, NO3-. These chemical analyses were verified by calculation of errors based on the ionic balance. The results of the analyses were referred to the polish applicable requirements for surface water used for public supply of water intended for human consumption and to the regulation regarding the classification of the surface water status and environmental quality standards for priority substances. The results indicate that water of the Bystrytsya-Nadvirnyans'ka River in the area of Cherniiv was out of the class in the years 1999 and 2002 due to exceeding the limit values for category A3 for Cu2+. On the basis of incomplete assessment of the status of the Bystrytsya-Nadvirnyans'ka River water (due to the tests limitation to the physical and chemical components) determined that the water has a bad status because it exceeded the limits for class II for Cl-, SO42-, NO3- and TDS. In the samples collected in 1999 and 2002 it is also observed exceeding the maximum limit concentrations for Cu2+.


2020 ◽  
Vol 99 (5) ◽  
pp. 478-482
Author(s):  
N. P. Setko ◽  
A. G. Setko ◽  
Ekaterina V. Bulycheva ◽  
A. V. Tyurin ◽  
E. Yu. Kalinina

Introduction. Changes in the body of children and adolescents aimed at adapting to environmental factors are determined by genetic polymorphism in xenobiotic biotransformation genes, determining the degree of susceptibility of the child’s body to pollutants, which is the basis of modern personalized preventive medicine when managing risks to the health of the child population under the influence of environmental factors. Material and methods. Trace elements, including heavy metals, lead and cadmium, were determined in the hair of 256 practically healthy teenagers by atomic absorption spectrophotometry. Depending on the level of content of the latter, two groups of adolescents were formed to determine six genes of the cytochrome P-450 family. Group 1 consisted of adolescents whose cadmium lead content exceeded the average Russian indices. The second group included adolescents whose heavy metals were above the level of average Russian standards. Results. Studies have shown that in adolescents of the 1st group, compared with the data of adolescents of the 2nd group, an increase in the number of carriers of two mutant alleles at the locus rs 1048943 (gene CYP1A1) is 3.08 times, rs 464621 (gene CYP1A1) is 1. 8 times; locus rs 2069522 (CYP1A2 gene) 3.63 times; locus rs 1799853 (CYP2C9 * 2 gene) 4.5 times; locus rs 1057910 (gene CYP2C9 * 3) 3.8 times and locus rs 2279343 (gene CYP2B6) 4.25 times. Moreover, carriers of two normal alleles in adolescents of the first group at the locus rs 1048943 (gene CYP1A1) were 5.14 times; locus rs 2279343 (CYP2B6 gene) was 6.5 fold less than among adolescents of the 2nd group; and at the locus rs 464621 (gene CYP1A1), rs 2069522 (gene CYP1A2), rs 1799853 (gene CYP2C9 * 2), rs 1057910 (gene CYP2C9 * 3) there were no carriers of normal homozygotes. Conclusion. Group 1 adolescents with heavy metal contamination of the body are carriers significantly in a greater number of pathological mutations in the genes of the cytochrome P-450 detoxification system in comparison with data from group 2 adolescents.


2018 ◽  
Vol 15 (1) ◽  
pp. 55-72
Author(s):  
Herlin Hamimi ◽  
Abdul Ghafar Ismail ◽  
Muhammad Hasbi Zaenal

Zakat is one of the five pillars of Islam which has a function of faith, social and economic functions. Muslims who can pay zakat are required to give at least 2.5 per cent of their wealth. The problem of poverty prevalent in disadvantaged regions because of the difficulty of access to information and communication led to a gap that is so high in wealth and resources. The instrument of zakat provides a paradigm in the achievement of equitable wealth distribution and healthy circulation. Zakat potentially offers a better life and improves the quality of human being. There is a human quality improvement not only in economic terms but also in spiritual terms such as improving religiousity. This study aims to examine the role of zakat to alleviate humanitarian issues in disadvantaged regions such as Sijunjung, one of zakat beneficiaries and impoverished areas in Indonesia. The researcher attempted a Cibest method to capture the impact of zakat beneficiaries before and after becoming a member of Zakat Community Development (ZCD) Program in material and spiritual value. The overall analysis shows that zakat has a positive impact on disadvantaged regions development and enhance the quality of life of the community. There is an improvement in the average of mustahik household incomes after becoming a member of ZCD Program. Cibest model demonstrates that material, spiritual, and absolute poverty index decreased by 10, 5, and 6 per cent. Meanwhile, the welfare index is increased by 21 per cent. These findings have significant implications for developing the quality of life in disadvantaged regions in Sijunjung. Therefore, zakat is one of the instruments to change the status of disadvantaged areas to be equivalent to other areas.


Author(s):  
Mahmud Mohammed Imam ◽  
Zahra Muhammad ◽  
Amina Zakari

In this research work the concentration of zinc, copper, lead, chromium, cadmium, and nickel in cow milk samples obtained from four different grazing areas   (kakuri, kudendan, malali, kawo) of Kaduna metropolis. The samples were digested by wet digestion technique .The trace element were determined using bulk scientific model VPG 210 model  Atomic Absorption Spectrophotometer (AAS).. The concentration of the determined heavy metal were The result revealed that Cr,  Ni and Cd were not detected in milk samples from Kawo, Malali  and Kudendan whereas lead (Pb) is detected in all samples and found to be above  the stipulated limits of recommended dietary allowance (NRC,1989) given as 0.02mg/day. Cu and Zn are essential elements needed by the body for proper metabolism and as such their deficiency or excess is very dangerous for human health. However, they were found in all samples and are within the recommended limits while Cd (2.13 – 3.15 mg/kg) in milk samples from Kakuri was found to be above such limit (0.5mg/day). Cow milk samples analyzed for heavy metals in this research work pose a threat of lead and cadmium toxicity due to their exposure to direct sources of air, water and plants in these grazing areas, thereby, resulting to a potential health risk to the consumers.


2017 ◽  
Vol 1 (21) ◽  
pp. 49-63
Author(s):  
Zdzisław Kaliniewicz ◽  
Piotr Markowski ◽  
Andrzej Anders ◽  
Paweł Tylek ◽  
Zbigniew Krzysiak ◽  
...  

The basic dimensions and the mass of common beech nuts and seeds from five nut batches, harvested from tree stands in northern Poland, were determined. Environmental conditions had a greater influence on seed plumpness than the age of tree stands. The results of measurements were analyzed statistically by analysis of variance, correlation analysis and linear regression analysis. Despite differences in their plumpness, nuts were characterized by nearly identical cross-sections which resembled an equilateral triangle. The thickness of nuts and seeds was highly correlated with their mass, and this information can facilitate seed husking and separation into mass categories. Before and after husking, seeds should be separated with the use of a mesh screen with longitudinal openings. Medium-sized (most numerous) seeds were separated into the following plumpness categories using a screen separator with ≠6 mm and ≠7 mm openings: 84% of moderately plump seeds, 3% of seeds with reduced plumpness, and 13% of plump seeds.


2019 ◽  
Vol 70 (10) ◽  
pp. 3678-3680
Author(s):  
Alina Cochiorca ◽  
Narcis Barsan ◽  
Florin Marian Nedeff ◽  
Ion Sandu ◽  
Emilian Florin Mosnegutu ◽  
...  

This paper presents a study on assessment of water quality. According to a study, mining activities have a significant impact on water quality (lakes, surface water and groundwater), which has become a major problem globally. Due to mining and exploitation processes, lakes can be formed around these mines. Also, these lakes have been formed around the world and are steadily increasing. The purpose of this study is to watch the quality of water from the area around mining activities. This study refers to the, Groapa Burlacu lake around the mining exploitation Targu Ocna, Romania. This lake was formed on the northern bottle of the massive salt, strongly affected by the underground activities. Sampling for the determination the concentrations of Cl- and NaCl from the studied area was made at different depths (0 m, -5 m, -10 m, -15 m, -20 m, -25 m, -30 m, -35 m -40 m). Besides these concentrations, physical parameters of the water (pH, turbidity, electrical conductivity, dissolved oxygen and temperature) were also measured. To determine the physical parameters in the monitored area, sampling was done from four different points of the area and then put together for analysis. These parameters were measured on site using portable equipment. The data on the analyzed concentrations indicate that at depths of less than 5.0 m, the NaCl concentration values are more than 250 g/L.


1999 ◽  
Vol 39 (2) ◽  
pp. 201-208 ◽  
Author(s):  
C. Dierkes ◽  
W. F. Geiger

Runoff from highways contains significant loads of heavy metals and hydrocarbons. According to German regulations, it should be infiltrated over embankments to support groundwater-recharge. To investigate the decontaminating effect of greened embankments, soil-monoliths from highways with high traffic densities were taken. Soils were analyzed to characterize the contamination in relation to distance and depth for lead, zinc, copper, cadmium, PAH and MOTH. Lysimeters were charged in the field and laboratory with highway runoff to study the effluents under defined conditions. Concentrations of pollutants in roadside soils depend on the age of embankments and traffic density. Highest concentrations were found in the upper 5 cm of the soil and within a distance of up to two metres from the street. Concentrations of most pollutants decreased rapidly with depth and distance. Lead and cadmium could not be detected in lysimeter effluent. Zinc and copper were found in concentrations that did not exceed drinking water quality limits.


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