Oil recovery in carbonate reservoir rocks by reducing total salinity or NaCl in injection water for core flooding tests

Author(s):  
Oswaldo Ivan Klinger Cataño
2021 ◽  
Author(s):  
Yongsheng Tan ◽  
Qi Li ◽  
Liang Xu ◽  
Xiaoyan Zhang ◽  
Tao Yu

<p>The wettability, fingering effect and strong heterogeneity of carbonate reservoirs lead to low oil recovery. However, carbon dioxide (CO<sub>2</sub>) displacement is an effective method to improve oil recovery for carbonate reservoirs. Saturated CO<sub>2</sub> nanofluids combines the advantages of CO<sub>2</sub> and nanofluids, which can change the reservoir wettability and improve the sweep area to achieve the purpose of enhanced oil recovery (EOR), so it is a promising technique in petroleum industry. In this study, comparative experiments of CO<sub>2</sub> flooding and saturated CO<sub>2</sub> nanofluids flooding were carried out in carbonate reservoir cores. The nuclear magnetic resonance (NMR) instrument was used to clarify oil distribution during core flooding processes. For the CO<sub>2</sub> displacement experiment, the results show that viscous fingering and channeling are obvious during CO<sub>2</sub> flooding, the oil is mainly produced from the big pores, and the residual oil is trapped in the small pores. For the saturated CO<sub>2</sub> nanofluids displacement experiment, the results show that saturated CO<sub>2</sub> nanofluids inhibit CO<sub>2</sub> channeling and fingering, the oil is produced from the big pores and small pores, the residual oil is still trapped in the small pores, but the NMR signal intensity of the residual oil is significantly reduced. The final oil recovery of saturated CO<sub>2</sub> nanofluids displacement is higher than that of CO<sub>2</sub> displacement. This study provides a significant reference for EOR in carbonate reservoirs. Meanwhile, it promotes the application of nanofluids in energy exploitation and CO<sub>2</sub> utilization.</p>


2019 ◽  
Vol 17 (2) ◽  
pp. 393-408 ◽  
Author(s):  
Bisweswar Ghosh ◽  
Liying Sun ◽  
Nithin Chacko Thomas

Abstract Waterflood-assisted oil recovery with sulfate-spiked seawater would cause incompatibility scaling in carbonate reservoirs and reduce economic benefits. This research investigated the benefits of polyphosphate compounds in reducing scaling potential as well as its effect on oil recovery when mixed in high sulfate flood water. Severity of scaling potential of sulfate-spiked water in a carbonate reservoir environment was measured, followed by systematic screening of a polyphosphate compound, which successfully inhibited the sulfate scale precipitation at concentration as low as 100 ppm. The new formulation (seawater with four times sulfate and phosphate, SW4SP) was evaluated and compared with benchmark formulation (modified seawater with four times sulfate, SW4S). Contact angle, ζ-potential and drainage studies show that SW4SP changed the rock wettability from oil wet to water wet to a larger degree compared to SW4S. Improved recovery efficiency of SW4SP was confirmed through a set of core flooding studies in the tertiary and quaternary flood modes. Whereas SW4S recovered 7.7% of original oil in place (OOIP), SW4SP recovered about 8% of OOIP in the tertiary mode under approximately identical flow conditions. Flooding with SW4SP in the quaternary mode following a tertiary flood with SW4S on the same core resulted in 1.7% additional oil recovery, showing improved efficiency of the new flood water formulation.


Energies ◽  
2020 ◽  
Vol 13 (15) ◽  
pp. 3988 ◽  
Author(s):  
Omid Haghighi ◽  
Ghasem Zargar ◽  
Abbas Khaksar Manshad ◽  
Muhammad Ali ◽  
Mohammad Takassi ◽  
...  

Production from mature oil reservoirs can be optimized by using the surfactant flooding technique. This can be achieved by reducing oil and water interfacial tension (IFT) and modifying wettability to hydrophilic conditions. In this study, a novel green non-ionic surfactant (dodecanoyl-glucosamine surfactant) was synthesized and used to modify the wettability of carbonate reservoirs to hydrophilic conditions as well as to decrease the IFT of hydrophobic oil–water systems. The synthesized non-ionic surfactant was characterized by Fourier transform infrared spectroscopy (FTIR) and chemical shift nuclear magnetic resonance (HNMR) analyses. Further pH, turbidity, density, and conductivity were investigated to measure the critical micelle concentration (CMC) of surfactant solutions. The result shows that this surfactant alters wettability from 148.93° to 65.54° and IFT from 30 to 14 dynes/cm. Core-flooding results have shown that oil recovery was increased from 40% (by water flooding) to 59% (by surfactant flooding). In addition, it is identified that this novel non-ionic surfactant can be used in CO2 storage applications due to its ability to alter the hydrophobicity into hydrophilicity of the reservoir rocks.


Author(s):  
A. Koto

The objective of this paper is to determine the optimum anaerobic-thermophilic bacterium injection (Microbial Enhanced Oil Recovery) parameters using commercial simulator from core flooding experiments. From the previous experiment in the laboratory, Petrotoga sp AR80 microbe and yeast extract has been injected into core sample. The result show that the experiment with the treated microbe flooding has produced more oil than the experiment that treated by brine flooding. Moreover, this microbe classified into anaerobic thermophilic bacterium due to its ability to live in 80 degC and without oxygen. So, to find the optimum parameter that affect this microbe, the simulation experiment has been conducted. The simulator that is used is CMG – STAR 2015.10. There are five scenarios that have been made to forecast the performance of microbial flooding. Each of this scenario focus on the injection rate and shut in periods. In terms of the result, the best scenario on this research can yield an oil recovery up to 55.7%.


2015 ◽  
pp. 26-30
Author(s):  
A. V. Podnebesnykh ◽  
S. V. Kuznetsov ◽  
V. P. Ovchinnikov

On the example of the group of fields in the West Siberia North the basic types of secondary changes in reservoir rocks are reviewed. Some of the most common types of such changes in the West Siberian plate territory include the processes of zeolitization, carbonation and leaching. These processes have, as a rule, a regional character of distribution and are confined to the tectonically active zones of the earth's crust. Due to formation of different mineral paragenesises the secondary processes differently affect the reservoir rocks porosity and permeability: thus, zeolitization and carbonization promote to reducing the porosity and permeability and leaching improvement. All this, ultimately leads to a change of the oil recovery factor and hydrocarbons production levels. Study and taking into account of the reservoir rocks secondary change processes can considerably influence on placement of operating well stock and on planning of geological and technological actions.


Author(s):  
Jesper Kresten Nielsen ◽  
Nils-Martin Hanken

NOTE: This article was published in a former series of GEUS Bulletin. Please use the original series name when citing this article, for example: Kresten Nielsen, J., & Hanken, N.-M. (2002). Late Permian carbonate concretions in the marine siliciclastic sediments of the Ravnefjeld Formation, East Greenland. Geology of Greenland Survey Bulletin, 191, 126-132. https://doi.org/10.34194/ggub.v191.5140 _______________ This investigation of carbonate concretions from the Late Permian Ravnefjeld Formation in East Greenland forms part of the multi-disciplinary research project Resources of the sedimentary basins of North and East Greenland (TUPOLAR; Stemmerik et al. 1996, 1999). The TUPOLAR project focuses on investigations and evaluation of potential hydrocarbon and mineral resources of the Upper Permian – Mesozoic sedimentary basins. In this context, the Upper Permian Ravnefjeld Formation occupies a pivotal position because it contains local mineralisations and has source rock potential for hydrocarbons adjacent to potential carbonate reservoir rocks of the partly time-equivalent Wegener Halvø Formation (Harpøth et al. 1986; Surlyk et al. 1986; Stemmerik et al. 1998; Pedersen & Stendal 2000). A better understanding of the sedimentary facies and diagenesis of the Ravnefjeld Formation is therefore crucial for an evaluation of the economic potential of East Greenland.


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