scholarly journals Forced laser nanostructuring of the surface of alumina-oxide ceramics

2021 ◽  
Vol 9 (3) ◽  
pp. 224-234
Author(s):  
Serafim Smirnov ◽  
Stanislav Shandarov ◽  
Vitaliy Karanskiy
Keyword(s):  
Laser Beam ◽  
Convective Instability ◽  
Ceramic Materials ◽  
Oxide Ceramics ◽  
Molten Layer ◽  
Insulator Interface ◽  
Diffraction Structure ◽  
Alumina Oxide ◽  
Beam Movement

The possibility of creating quasiperiodic nanostructures on the surface of articles made of ceramic materials based on -Al2O3 under the action of a laser beam moved by a two-coordinate linear stepping motor (LSM) is shown. It is shown that the cause of the arising non-uniformity of heat release and convective instability of the molten layer are electromagnetic surface waves at the "conductor-insulator" interface, while the "conductor" is the melt layer. The discreteness of the laser beam movement due to LSD makes it possible to create a regular wave-like relief on the melt surface, which plays the role of an input diffraction structure for gen-erating a surface wave of TM polarization.

scholarly journals Green Nanocoatings Based on the Deposition of Zirconium Oxide: The Role of the Substrate

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 1043
Author(s):  
Vitor Bonamigo Moreira ◽  
Anna Puiggalí-Jou ◽  
Emilio Jiménez-Piqué ◽  
Carlos Alemán ◽  
Alvaro Meneguzzi ◽  
...  
Keyword(s):  
Zirconium Oxide ◽  
Active Sites ◽  
Modified Electrodes ◽  
Chemical Conversion ◽  
Ceramic Materials ◽  
Point Of View ◽  
Oxide Coatings ◽  
Alloying Element ◽  
Substrate Nature

Herein, the influence of the substrate in the formation of zirconium oxide monolayer, from an aqueous hexafluorozirconic acid solution, by chemical conversion and by electro-assisted deposition, has been approached. The nanoscale dimensions of the ZrO2 film is affected by the substrate nature and roughness. This study evidenced that the mechanism of Zr-EAD is dependent on the potential applied and on the substrate composition, whereas conversion coating is uniquely dependent on the adsorption reaction time. The zirconium oxide based nanofilms were more homogenous in AA2024 substrates if compared to pure Al grade (AA1100). It was justified by the high content of Cu alloying element present in the grain boundaries of the latter. Such intermetallic active sites favor the obtaining of ZrO2 films, as demonstrated by XPS and AFM results. From a mechanistic point of view, the electrochemical reactions take place simultaneously with the conventional chemical conversion process driven by ions diffusion. Such findings will bring new perspectives for the generation of controlled oxide coatings in modified electrodes used, as for example, in the construction of battery cells; in automotive and in aerospace industries, to replace micrometric layers of zinc phosphate by light-weight zirconium oxide nanometric ones. This study is particularly addressed for the reduction of industrial waste by applying green bath solutions without the need of auxiliary compounds and using lightweight ceramic materials.

scholarly journals Role of Sintering Temperature in Production of Nepheline Ceramics-Based Geopolymer with Addition of Ultra-High Molecular Weight Polyethylene

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1077
Author(s):  
Romisuhani Ahmad ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Wan Mastura Wan Ibrahim ◽  
Kamarudin Hussin ◽  
Fakhryna Hannanee Ahmad Zaidi ◽  
...  
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Sintering Temperature ◽  
Ceramic Materials ◽  
Microstructural Properties ◽  
Sintering Process ◽  
Final Microstructure ◽  
Change Of Microstructure ◽  
Ultra High Molecular Weight

The primary motivation of developing ceramic materials using geopolymer method is to minimize the reliance on high sintering temperatures. The ultra-high molecular weight polyethylene (UHMWPE) was added as binder and reinforces the nepheline ceramics based geopolymer. The samples were sintered at 900 °C, 1000 °C, 1100 °C, and 1200 °C to elucidate the influence of sintering on the physical and microstructural properties. The results indicated that a maximum flexural strength of 92 MPa is attainable once the samples are used to be sintered at 1200 °C. It was also determined that the density, porosity, volumetric shrinkage, and water absorption of the samples also affected by the sintering due to the change of microstructure and crystallinity. The IR spectra reveal that the band at around 1400 cm−1 becomes weak, indicating that sodium carbonate decomposed and began to react with the silica and alumina released from gels to form nepheline phases. The sintering process influence in the development of the final microstructure thus improving the properties of the ceramic materials.

CERAMICS BASED ON ORGANOSILICON POLYMERS-PRECURSORS: MICROSTRUCTURE AND PROPERTIES (review). Part 2

2021 ◽  
pp. 22-32
Author(s):  
A.M. Shestakov ◽  
Keyword(s):  
Electron Microscopy ◽  
Nmr Spectroscopy ◽  
Material Properties ◽  
Structural Organization ◽  
Ceramic Materials ◽  
Special Role ◽  
Correct Interpretation ◽  
Instrumental Methods ◽  
Organosilicon Polymers

Shows the scientific approaches of various authors to the study of the microstructure of ceramics, the purpose of which is to elucidate its structural organization at the micro- and nanoscale, as well as the influence of the microstructure on the complex of material properties. Various instrumental methods for studying ceramics (NMR spectroscopy, electron microscopy, х-ray structural analysis, etc.) are considered, the permissible capabilities of research methods and analysis of the results obtained with their correct interpretation are shown. The special role of theoretical modeling in understanding the structure of the considered ceramic materials is noted.

scholarly journals Solute Driven Transient Convection in Layered Porous Media

2021 ◽  
pp. 3-9
Author(s):  
Emmanuel E. Luther ◽  
Seyed M. Shariatipour ◽  
Michael C. Dallaston ◽  
Ran Holtzman
Keyword(s):  
Convective Instability ◽  
Onset Time ◽  
Fluid Phase ◽  
Deep Saline Aquifer ◽  
Research Attention ◽  
Storage Security ◽  
Permeability Distribution ◽  
Layered Porous Media ◽  
Geological Formations

AbstractCO2 geological sequestration has been proposed as a climate change mitigation strategy that can contribute towards meeting the Paris Agreement. A key process on which successful injection of CO2 into deep saline aquifer relies on is the dissolution of CO2 in brine. CO2 dissolution improves storage security and reduces risk of leakage by (i) removing the CO2 from a highly mobile fluid phase and (ii) triggering gravity-induced convective instability which accelerates the downward migration of dissolved CO2. Our understanding of CO2 density-driven convection in geologic media is limited. Studies on transient convective instability are mostly in homogeneous systems or in systems with heterogeneity in the form of random permeability distribution or dispersed impermeable barriers. However, layering which exist naturally in sedimentary geological formations has not received much research attention on transient convection. Therefore, we investigate the role of layering on the onset time of convective instability and on the flow pattern beyond the onset time during CO2 storage. We find that while layering has no significant effect on the onset time, it has an impact on the CO2 flux. Our findings suggest that detailed reservoir characterisation is required to forecast the ability of a formation to sequester CO2.

scholarly journals Electroosmotic pressure in the process of a biocompatible coating applying on the inner surfaces of nanostructured ceramics

2019 ◽  
Keyword(s):  
Base Material ◽  
Ceramic Materials ◽  
Porous System ◽  
Chemical Additives ◽  
Biocompatible Coating ◽  
Internal Surfaces ◽  
Electrochemical Application ◽  
Average Size ◽  
Nanostructured Ceramics

The role of the effect of electroosmosis in the process of electrochemical deposition of a biocompatible coating on the inner surfaces of porous nanostructured ceramics, a material used to make endoprostheses and implants in medicine, is discussed. The biocompatibility of endoprostheses and implants with the human body is ensured by applying a special coating on the internal and external surfaces of the base material. The commonly acepted chemical compound used to form this coating is hydroxyapatite Ca10(PO4)6(OH)2. Multicomponent ceramic materials, from which the basis of endoprostheses and implants are made, are usually obtained by the traditional method of powder metallurgy - sintering, i.e., exposure of a mixture of powders at an elevated temperature under pressure. The material obtained in this way is a polycrystal. In addition, the structure of such a material contains a certain amount of voids in the form of individual pores or their associations (capillaries). The paper shows that the use of nano-structured ceramic materials with a characteristic average size of structural elements (grains, pores and their aggregations) of the order ≈(10–9–10–7)м as a material for the manufacture of implants may determine the greater efficiency of the process of electrochemical application of a biocompatible coating on them, since the resulting large electroosmotic pressure in the capillaries leads to a greater degree of filling of the porous system with electrolyte. The magnitude of the electroosmotic pressure can be increased by increasing the strength of the acting electric field or by decreasing the dielectric constant of the electrolyte ε when additional chemical additives are introduced into the electrolyte. The maximum degree of hollow channels (capillaries) filling with electrolyte, and, consequently, the efficiency of applying a biocompatible coating to the internal surfaces of ceramics using the electrochemical method, is achieved with the capillary system of the material being completely open.

A Study on Ultrasonic Torsional Vibration-Assisted Abrasive Waterjet Polishing of Ceramic Materials

2016 ◽  
Vol 1136 ◽  
pp. 400-405 ◽  
Author(s):  
Yong Wang ◽  
Hong Tao Zhu ◽  
Chuan Zhen Huang ◽  
Jun Wang ◽  
Peng Yao
Keyword(s):  
Torsional Vibration ◽  
Abrasive Particle ◽  
Ceramic Materials ◽  
Abrasive Waterjet ◽  
Critical Depth ◽  
Particle Movement ◽  
Promising Technique ◽  
Abrasive Waterjet Machining ◽  
Waterjet Machining

Abrasive waterjet machining is considered as a promising technique in hard-brittle material polishing. In this paper, The ultrasonic torsional vibration is considered to apply on the workpiece to improve the abrasive waterjet polishing quality and efficiency. The process parameters in the ultrasonic torsional vibration-assisted abrasive waterjet polishing are optimized. The ultrasonic torsional vibration in the role of the abrasive waterjet polishing is investigated. The results show that the application of ultrasonic torsional vibration can effect of abrasive particle movement and increase the critical depth of the ceramic materials.

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