scholarly journals N<sub>2</sub>O release from agro-biofuel production negates global warming reduction by replacing fossil fuels

2008 ◽  
Vol 8 (2) ◽  
pp. 389-395 ◽  
Author(s):  
P. J. Crutzen ◽  
A. R. Mosier ◽  
K. A. Smith ◽  
W. Winiwarter
Keyword(s):  
Global Warming ◽  
Large Scale ◽  
Fossil Fuels ◽  
Fossil Fuel ◽  
Conversion Factor ◽  
Production Systems ◽  
Climate Impacts ◽  
Biofuel Production ◽  
N2o Emissions ◽  
Agricultural Crop

Abstract. The relationship, on a global basis, between the amount of N fixed by chemical, biological or atmospheric processes entering the terrestrial biosphere, and the total emission of nitrous oxide (N2O), has been re-examined, using known global atmospheric removal rates and concentration growth of N2O as a proxy for overall emissions. For both the pre-industrial period and in recent times, after taking into account the large-scale changes in synthetic N fertiliser production, we find an overall conversion factor of 3–5% from newly fixed N to N2O-N. We assume the same factor to be valid for biofuel production systems. It is covered only in part by the default conversion factor for "direct" emissions from agricultural crop lands (1%) estimated by IPCC (2006), and the default factors for the "indirect" emissions (following volatilization/deposition and leaching/runoff of N: 0.35–0.45%) cited therein. However, as we show in the paper, when additional emissions included in the IPCC methodology, e.g. those from livestock production, are included, the total may not be inconsistent with that given by our "top-down" method. When the extra N2O emission from biofuel production is calculated in "CO2-equivalent" global warming terms, and compared with the quasi-cooling effect of "saving" emissions of fossil fuel derived CO2, the outcome is that the production of commonly used biofuels, such as biodiesel from rapeseed and bioethanol from corn (maize), depending on N fertilizer uptake efficiency by the plants, can contribute as much or more to global warming by N2O emissions than cooling by fossil fuel savings. Crops with less N demand, such as grasses and woody coppice species, have more favourable climate impacts. This analysis only considers the conversion of biomass to biofuel. It does not take into account the use of fossil fuel on the farms and for fertilizer and pesticide production, but it also neglects the production of useful co-products. Both factors partially compensate each other. This needs to be analyzed in a full life cycle assessment.

scholarly journals N<sub>2</sub>O release from agro-biofuel production negates global warming reduction by replacing fossil fuels

2007 ◽  
Vol 7 (4) ◽  
pp. 11191-11205 ◽  
Author(s):  
P. J. Crutzen ◽  
A. R. Mosier ◽  
K. A. Smith ◽  
W. Winiwarter
Keyword(s):  
Global Warming ◽  
Large Scale ◽  
Fossil Fuels ◽  
Fossil Fuel ◽  
N2o Emission ◽  
Climate Impacts ◽  
Biofuel Production ◽  
N2o Emissions ◽  
Agricultural Crop ◽  
The Relationship

Abstract. The relationship, on a global basis, between the amount of N fixed by chemical, biological or atmospheric processes entering the terrestrial biosphere, and the total emission of nitrous oxide (N2O), has been re-examined, using known global atmospheric removal rates and concentration growth of N2O as a proxy for overall emissions. The relationship, in both the pre-industrial period and in recent times, after taking into account the large-scale changes in synthetic N fertiliser production and deforestation, is consistent, showing an overall conversion factor of 3–5%. This factor is covered only in part by the ~1% of "direct" emissions from agricultural crop lands estimated by IPCC (2006), or the "indirect" emissions cited therein. This means that the extra N2O entering the atmosphere as a result of using N to produce crops for biofuels will also be correspondingly greater than that estimated just on the basis of IPCC (2006). When the extra N2O emission from biofuel production is calculated in "CO2-equivalent" global warming terms, and compared with the quasi-cooling effect of "saving" emissions of fossil fuel derived CO2, the outcome is that the production of commonly used biofuels, such as biodiesel from rapeseed and bioethanol from corn (maize), can contribute as much or more to global warming by N2O emissions than cooling by fossil fuel savings. Crops with less N demand, such as grasses and woody coppice species have more favourable climate impacts. This analysis only considers the conversion of biomass to biofuel. It does not take into account the use of fossil fuel on the farms and for fertilizer and pesticide production, but it also neglects the production of useful co-products. Both factors partially compensate each other. This needs to be analyzed in a full life cycle assessment.

scholarly journals The significance of nitrous oxide emission due to cropping of grain for biofuel production: a Swedish perspective

2011 ◽  
Vol 8 (12) ◽  
pp. 3581-3591 ◽  
Author(s):  
Å. Kasimir Klemedtsson ◽  
K. A. Smith
Keyword(s):  
Nitrous Oxide ◽  
Crop Production ◽  
Fossil Fuels ◽  
Agricultural Land ◽  
N2o Emission ◽  
Biofuel Production ◽  
Organic Soils ◽  
N2o Emissions ◽  
Agricultural Crop ◽  
The Eu

Abstract. The current regulations governing production of biofuels in the European Union require that they have to mitigate climate change, by producing >35% less greenhouse gases (GHG) than fossil fuels. There is a risk that this may not be achievable, since land use for crop production inevitably emits the potent GHG nitrous oxide (N2O), due to nitrogen fertilisation and cycling in the environment. We analyse first-generation biofuel production on agricultural land and conclude that efficient agricultural crop production resulting in a good harvest and low N2O emission can fulfil the EU standard, and is possible under certain conditions for the Swedish agricultural and bioethanol production systems. However, in years having low crop yields, and where cropping is on organic soils, total GHG emissions per unit of fuel produced can be even higher than those released by burning of fossil fuels. In general, the N2O emission size in Sweden and elsewhere in northern Europe is such that there is a >50% chance that the 35% saving requirement will not be met. Thus ecosystem N2O emissions have to be convincingly assessed. Here we compare Swedish emission data with values estimated by means of statistical models and by a global, top-down, approach; the measurements and the predictions often show higher values that would fail to meet the EU standard and thus prevent biofuel production development.

scholarly journals The significance of nitrous oxide emission from biofuel crops on arable land: a Swedish perspective

2011 ◽  
Vol 8 (4) ◽  
pp. 6743-6774
Author(s):  
Å. Kasimir Klemedtsson ◽  
K. A. Smith
Keyword(s):  
Nitrous Oxide ◽  
Crop Production ◽  
Fossil Fuels ◽  
Crop Yields ◽  
Arable Land ◽  
N2o Emission ◽  
Biofuel Production ◽  
N2o Emissions ◽  
Agricultural Crop ◽  
The Eu

Abstract. The current regulations governing biofuel production in the European Union require that they have to mitigate climate change, by producing >35 % less greenhouse gases (GHG) than fossil fuels. There is a risk that this may not be achievable, since land use for crop production inevitably emits the strong GHG nitrous oxide (N2O), due to nitrogen fertilisation and cycling in the environment. We conclude that efficient agricultural crop production resulting in a good harvest and low N2O emission can fulfill the EU standard, and is possible under certain conditions for the Swedish agricultural and refinery production systems. However, in years having low crop yields total GHG emissions can be even higher than those released by burning of fossil fuels. In general, the N2O emission size in Sweden and northern Europe is such that there is a >50 % chance that the 35 % saving requirement will not be met. Thus ecosystem N2O emissions have to be convincingly assessed. Here we compare Swedish emission data with values estimated by means of statistical models and by a global, top-down, procedure; the measurements and the predictions often show higher values that would fail to meet the EU standard and thus prevent biofuel production development.

scholarly journals A Modelling Framework for the Conceptual Design of Low-Emission Eco-Industrial Parks in the Circular Economy: A Case for Algae-Centered Business Consortia

Water ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 69
Author(s):  
Aldric S. Tumilar ◽  
Dia Milani ◽  
Zachary Cohn ◽  
Nick Florin ◽  
Ali Abbas
Keyword(s):  
Circular Economy ◽  
Carbon Capture ◽  
Fossil Fuel ◽  
Production Systems ◽  
Flow Analysis ◽  
Biofuel Production ◽  
Industrial Symbiosis ◽  
Modelling Framework ◽  
Low Emission ◽  
Energy Exchanges

This article describes a unique industrial symbiosis employing an algae cultivation unit (ACU) at the core of a novel eco-industrial park (EIP) integrating fossil-fuel fired power generation, carbon capture, biofuel production, aquaculture, and wastewater treatment. A new modelling framework capable of designing and evaluating materials and energy exchanges within an industrial eco-system is introduced. In this scalable model, an algorithm was developed to balance the material and energy exchanges and determine the optimal inputs and outputs based on the industrial symbiosis objectives and participating industries. Optimizing the functionality of the ACU not only achieved a substantial emission reduction, but also boosted aquaculture, biofuel, and other chemical productions. In a power-boosting scenario (PBS), by matching a 660 MW fossil fuel-fired power plant with an equivalent solar field in the presence of ACU, fish-producing aquaculture and biofuel industries, the net CO2 emissions were cut by 60% with the added benefit of producing 39 m3 biodiesel, 6.7 m3 bioethanol, 0.14 m3 methanol, and 19.55 tons of fish products annually. Significantly, this article shows the potential of this new flexible modelling framework for integrated materials and energy flow analysis. This integration is an important pathway for evaluating energy technology transitions towards future low-emission production systems, as required for a circular economy.

scholarly journals The Use of Urea and Kelp Waste Extract is A Promising Strategy for Maximizing the Biomass Productivity and Lipid Content in Chlorella sorokiniana

Plants ◽  
2020 ◽  
Vol 9 (4) ◽  
pp. 463 ◽  
Author(s):  
Ali Nawaz Kumbhar ◽  
Meilin He ◽  
Abdul Razzaque Rajper ◽  
Khalil Ahmed Memon ◽  
Muhammad Rizwan ◽  
...  
Keyword(s):  
Lipid Content ◽  
Fossil Fuels ◽  
Fossil Fuel ◽  
Lipid Production ◽  
Total Lipid Content ◽  
Biomass Productivity ◽  
Chlorella Sorokiniana ◽  
Biofuel Production ◽  
Promising Strategy ◽  
Waste Extract

The decline in fossil fuel reserves has forced researchers to seek out alternatives to fossil fuels. Microalgae are considered to be a promising feedstock for sustainable biofuel production. Previous studies have shown that urea is an important nitrogen source for cell growth and the lipid production of microalgae. The present study investigated the effect of different concentrations of urea combined with kelp waste extract on the biomass and lipid content of Chlorella sorokiniana. The results revealed that the highest cell density, 20.36 × 107 cells−1, and maximal dry biomass, 1.70 g/L, were achieved in the presence of 0.5 g/L of urea combined with 8% kelp waste extract. Similarly, the maximum chlorophyll a, b and beta carotenoid were 10.36 mg/L, 7.05, and 3.01 mg/L, respectively. The highest quantity of carbohydrate content, 290.51 µg/mL, was achieved in the presence of 0.2 g/L of urea and 8% kelp waste extract. The highest fluorescence intensity, 40.05 × 107 cells−1, and maximum total lipid content (30%) were achieved in the presence of 0.1 g/L of urea and 8% kelp waste extract. The current study suggests that the combination of urea and kelp waste extract is the best strategy to enhance the biomass and lipid content in Chlorella sorokiniana.

scholarly journals Biomass and lipid induction strategies in microalgae for biofuel production and other applications

2019 ◽  
Vol 18 (1) ◽  
Author(s):  
Hossein Alishah Aratboni ◽  
Nahid Rafiei ◽  
Raul Garcia-Granados ◽  
Abbas Alemzadeh ◽  
José Rubén Morones-Ramírez
Keyword(s):  
Lipid Content ◽  
Large Scale ◽  
Fossil Fuels ◽  
Low Cost ◽  
Lipid Production ◽  
Arable Land ◽  
Economic Cost ◽  
Biofuel Production ◽  
Scale Production ◽  
Microalgae Biomass

Abstract The use of fossil fuels has been strongly related to critical problems currently affecting society, such as: global warming, global greenhouse effects and pollution. These problems have affected the homeostasis of living organisms worldwide at an alarming rate. Due to this, it is imperative to look for alternatives to the use of fossil fuels and one of the relevant substitutes are biofuels. There are different types of biofuels (categories and generations) that have been previously explored, but recently, the use of microalgae has been strongly considered for the production of biofuels since they present a series of advantages over other biofuel production sources: (a) they don’t need arable land to grow and therefore do not compete with food crops (like biofuels produced from corn, sugar cane and other plants) and; (b) they exhibit rapid biomass production containing high oil contents, at least 15 to 20 times higher than land based oleaginous crops. Hence, these unicellular photosynthetic microorganisms have received great attention from researches to use them in the large-scale production of biofuels. However, one disadvantage of using microalgae is the high economic cost due to the low-yields of lipid content in the microalgae biomass. Thus, development of different methods to enhance microalgae biomass, as well as lipid content in the microalgae cells, would lead to the development of a sustainable low-cost process to produce biofuels. Within the last 10 years, many studies have reported different methods and strategies to induce lipid production to obtain higher lipid accumulation in the biomass of microalgae cells; however, there is not a comprehensive review in the literature that highlights, compares and discusses these strategies. Here, we review these strategies which include modulating light intensity in cultures, controlling and varying CO2 levels and temperature, inducing nutrient starvation in the culture, the implementation of stress by incorporating heavy metal or inducing a high salinity condition, and the use of metabolic and genetic engineering techniques coupled with nanotechnology.

scholarly journals Catalytic Production of Jet Fuels from Biomass

Molecules ◽  
2020 ◽  
Vol 25 (4) ◽  
pp. 802 ◽  
Author(s):  
Manuel Antonio Díaz-Pérez ◽  
Juan Carlos Serrano-Ruiz
Keyword(s):  
Molecular Weight ◽  
Global Warming ◽  
Natural Gas ◽  
Heterogeneous Catalysts ◽  
Fossil Fuels ◽  
Fossil Fuel ◽  
Liquid Hydrocarbon ◽  
Jet Fuels ◽  
Renewable Source ◽  
The World

Concerns about depleting fossil fuels and global warming effects are pushing our society to search for new renewable sources of energy with the potential to substitute coal, natural gas, and petroleum. In this sense, biomass, the only renewable source of carbon available on Earth, is the perfect replacement for petroleum in producing renewable fuels. The aviation sector is responsible for a significant fraction of greenhouse gas emissions, and two billion barrels of petroleum are being consumed annually to produce the jet fuels required to transport people and goods around the world. Governments are pushing directives to replace fossil fuel-derived jet fuels with those derived from biomass. The present mini review is aimed to summarize the main technologies available today for converting biomass into liquid hydrocarbon fuels with a molecular weight and structure suitable for being used as aviation fuels. Particular emphasis will be placed on those routes involving heterogeneous catalysts.

scholarly journals Foodshed analysis and its relevance to sustainability

2008 ◽  
Vol 24 (1) ◽  
pp. 1-7 ◽  
Author(s):  
Christian J. Peters ◽  
Nelson L. Bills ◽  
Jennifer L. Wilkins ◽  
Gary W. Fick
Keyword(s):  
Large Scale ◽  
Food System ◽  
Resource Constraints ◽  
Food Prices ◽  
Climate Impacts ◽  
Biofuel Production ◽  
Energy Prices ◽  
Critical Question ◽  
Long Distance ◽  
Adequate Food

AbstractProviding a wholesome and adequate food supply is the most basic tenet of agricultural sustainability. However, sharp increases in global food prices have occurred in the past 2 years, bringing the real price of food to the highest level seen in 30 years (FAO, 2008). This dramatic shift is a fundamental concern. The role of ‘local food’ in contributing to the solution of underlying problems is currently being debated, and the debate raises a critical question: To what degree can society continue to rely on large-scale, long-distance transportation of food? Growing concerns about climate change, the longevity of fossil fuel supplies and attempts to produce energy from agriculture suggest that energy efficiency will be critical to adapting to resource constraints and mitigating climate impacts. Moreover, these problems are urgent because energy prices, biofuel production and weather-related crop failures are partially responsible for the current world food price situation. Tools are needed to determine how the environmental impact and vulnerability of the food system are related to where food is produced in relation to where it is consumed. To this end, analyses of foodsheds, the geographic areas that feed population centers, can provide useful and unique insights.

scholarly journals Placing microalgae on the biofuels priority list: a review of the technological challenges

2009 ◽  
Vol 7 (46) ◽  
pp. 703-726 ◽  
Author(s):  
H. C. Greenwell ◽  
L. M. L. Laurens ◽  
R. J. Shields ◽  
R. W. Lovitt ◽  
K. J. Flynn
Keyword(s):  
Large Scale ◽  
Production Systems ◽  
Growth Models ◽  
Arable Land ◽  
Biofuel Production ◽  
Algal Culture ◽  
Priority List ◽  
Photosynthetic Productivity ◽  
Algal Lipid ◽  
Microalgal Culture

Microalgae provide various potential advantages for biofuel production when compared with ‘traditional’ crops. Specifically, large-scale microalgal culture need not compete for arable land, while in theory their productivity is greater. In consequence, there has been resurgence in interest and a proliferation of algae fuel projects. However, while on a theoretical basis, microalgae may produce between 10- and 100-fold more oil per acre, such capacities have not been validated on a commercial scale. We critically review current designs of algal culture facilities, including photobioreactors and open ponds, with regards to photosynthetic productivity and associated biomass and oil production and include an analysis of alternative approaches using models, balancing space needs, productivity and biomass concentrations, together with nutrient requirements. In the light of the current interest in synthetic genomics and genetic modifications, we also evaluate the options for potential metabolic engineering of the lipid biosynthesis pathways of microalgae. We conclude that although significant literature exists on microalgal growth and biochemistry, significantly more work needs to be undertaken to understand and potentially manipulate algal lipid metabolism. Furthermore, with regards to chemical upgrading of algal lipids and biomass, we describe alternative fuel synthesis routes, and discuss and evaluate the application of catalysts traditionally used for plant oils. Simulations that incorporate financial elements, along with fluid dynamics and algae growth models, are likely to be increasingly useful for predicting reactor design efficiency and life cycle analysis to determine the viability of the various options for large-scale culture. The greatest potential for cost reduction and increased yields most probably lies within closed or hybrid closed–open production systems.

scholarly journals Torrefied biomass in biofuel production system

2020 ◽  
Vol 93 (8) ◽  
pp. 9-12
Author(s):  
D. Ciolkosz ◽  
Keyword(s):  
Supply Chain ◽  
Large Scale ◽  
Crop Residues ◽  
Production Systems ◽  
Animal Feed ◽  
Energy Content ◽  
Value Added ◽  
Power Production ◽  
Biofuel Production ◽  
Added Value

Ukraine produces large amounts of crop residues every year, much which could be utilized to produce biofuel. However, efficient supply chains and system configurations are needed to make such systems efficient and cost effective. One option is to integrate torrefaction, power production and biofuel production into a single, coordinated system. This approach allows for high value product (i.e. biofuel), greater utilization of the energy content of the feedstock, and supply chain efficiency. Initial analyses indicate that revenues can be enhanced through this approach, and further analyses and optimization efforts could identify a sustainable approach to renewable fuel and power production for Ukraine. The question of scale and layout remains of interest as well, and a thorough logistical study is needed to identify the most suitable configuration. Agricultural operations often benefit from smaller scales of operation, whereas fuel production processes tend to operate profitably only at very large scale. Thus, a balance must be struck between the needs of both ends of the supply chain. The processing center concept helps to balance those needs. A system such as this also has potential to synergize with other agricultural production systems, such as the production of animal feed, fertilizer, and other bio-based products. The complexities of the Ukrainian agricultural market will need to be reflected carefully in any model that seeks to assess the system's potential. Presents a concept for coupling thermal pretreatment (torrefaction with biofuel and power production for the transformation of wheat straw into a value added product for Ukraine. Torrefaction provides supply chain savings, while conversion provides added value to the product. This paradigm has potential to utilize a widely produced waste material into a valuable source of energy and possibly other products for the country.

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