scholarly journals New insights into the  ∼ 74 ka Toba eruption from sulfur isotopes of polar ice cores

2021 ◽  
Vol 17 (5) ◽  
pp. 2119-2137
Author(s):  
Laura Crick ◽  
Andrea Burke ◽  
William Hutchison ◽  
Mika Kohno ◽  
Kathryn A. Moore ◽  
...  
Keyword(s):  
Sulfur Isotopes ◽  
Stratospheric Ozone ◽  
Ice Core ◽  
Ice Cores ◽  
High Temporal Resolution ◽  
Polar Ice ◽  
Volcanic Event ◽  
Ice Core Record ◽  
Amplifying Effect ◽  
The Impact

Abstract. The ∼74 ka Toba eruption was one of the largest volcanic events of the Quaternary. There is much interest in determining the impact of such a large event, particularly on the climate and hominid populations at the time. Although the Toba eruption has been identified in both land and marine archives as the Youngest Toba Tuff, its precise place in the ice core record is ambiguous. Several volcanic sulfate signals have been identified in both Antarctic and Greenland ice cores and span the Toba eruption 40Ar/39Ar age uncertainty. Here, we measure sulfur isotope compositions in Antarctic ice samples from the Dome C (EDC) and Dronning Maud Land (EDML) ice cores at high temporal resolution across 11 of these potential Toba sulfate peaks to identify candidates with sulfur mass-independent fractionation (S-MIF), indicative of an eruption whose plume reached altitudes at or above the stratospheric ozone layer. Using this method, we identify several candidate sulfate peaks that contain stratospheric sulfur. We further narrow down potential candidates based on the isotope signatures by identifying sulfate peaks that are due to a volcanic event at tropical latitudes. In one of these sulfate peaks at 73.67 ka, we find the largest ever reported magnitude of S-MIF in volcanic sulfate in polar ice, with a Δ33S value of −4.75 ‰. As there is a positive correlation between the magnitude of the S-MIF signal recorded in ice cores and eruptive plume height, this could be a likely candidate for the Toba super-eruption, with a plume top height in excess of 45 km. These results support the 73.7±0.3 ka (1σ) 40Ar/39Ar age estimate for the eruption, with ice core ages of our candidates with the largest magnitude S-MIF at 73.67 and 73.74 ka. Finally, since these candidate eruptions occurred on the transition into Greenland Stadial 20, the relative timing suggests that Toba was not the trigger for the large Northern Hemisphere cooling at this time although we cannot rule out an amplifying effect.

scholarly journals New insights into the ~74 ka Toba eruption from sulfur isotopes of polar ice cores

2021 ◽  
Author(s):  
Laura Crick ◽  
Andrea Burke ◽  
William Hutchison ◽  
Mika Kohno ◽  
Kathryn A. Moore ◽  
...  
Keyword(s):  
Sulfur Isotopes ◽  
Ice Core ◽  
Ice Cores ◽  
High Temporal Resolution ◽  
Polar Ice ◽  
Plume Height ◽  
Volcanic Event ◽  
Ice Core Record ◽  
Amplifying Effect ◽  
The Impact

Abstract. The ~74 ka Toba eruption was one of the largest volcanic events of the Quaternary. There is much interest in determining the impact of such a huge event, particularly on the climate and hominid populations at the time. Although the Toba eruption has been identified in both land and marine archives as the Youngest Toba Tuff, its precise place in the ice core record is ambiguous. Multiple volcanic sulfate signals have been identified in both Antarctic and Greenland ice cores within the uncertainty of age estimates as possible events for the Toba eruption. We measure sulfur isotope compositions in Antarctic ice samples at high temporal resolution across 11 of these potential Toba sulfate peaks in two cores to identify candidates with sulfur mass-independent fractionation (S-MIF), indicative of an eruption whose plume reached altitudes at or above the ozone layer in the stratosphere. Using this method, we identify several candidate sulfate peaks that contain stratospheric sulfur. We further narrow down potential candidates based on the isotope signatures by identifying sulfate peaks that are due to a volcanic event at tropical latitudes. In one of these sulfate peaks at 73.67 ka, we find the largest ever reported magnitude of S-MIF in volcanic sulfate in polar ice, with a Δ33S value of −4.75 ‰. As there is a positive correlation between the magnitude of the S-MIF signal recorded in ice cores and eruptive plume height, this could be a likely candidate for the Toba supereruption, with a plume height in excess of 45 km. These results support the 73.7 ± 0.3 ka (1σ) ka Ar/Ar age estimate for the eruption, with ice core ages of our candidates with the largest magnitude S-MIF at 73.67 and 73.74 ka. Finally, since these candidate eruptions occurred on the transition into Greenland Stadial 20, the relative timing suggests that Toba was not the trigger for the large Northern Hemisphere cooling at this time although we cannot rule out an amplifying effect.

Methane and nitrous oxide in the ice core record

2007 ◽  
Vol 365 (1856) ◽  
pp. 1775-1792 ◽  
Author(s):  
Eric Wolff ◽  
Renato Spahni
Keyword(s):  
Nitrous Oxide ◽  
Ice Core ◽  
Ice Cores ◽  
Atmospheric Gases ◽  
Last Glacial Period ◽  
Trapped Air ◽  
Ice Core Record ◽  
The Impact ◽  
Rule Out ◽  
The Last Glacial

Polar ice cores contain, in trapped air bubbles, an archive of the concentrations of stable atmospheric gases. Of the major non-CO 2 greenhouse gases, methane is measured quite routinely, while nitrous oxide is more challenging, with some artefacts occurring in the ice and so far limited interpretation. In the recent past, the ice cores provide the only direct measure of the changes that have occurred during the industrial period; they show that the current concentration of methane in the atmosphere is far outside the range experienced in the last 650 000 years; nitrous oxide is also elevated above its natural levels. There is controversy about whether changes in the pre-industrial Holocene are natural or anthropogenic in origin. Changes in wetland emissions are generally cited as the main cause of the large glacial–interglacial change in methane. However, changing sinks must also be considered, and the impact of possible newly described sources evaluated. Recent isotopic data appear to finally rule out any major impact of clathrate releases on methane at these time-scales. Any explanation must take into account that, at the rapid Dansgaard–Oeschger warmings of the last glacial period, methane rose by around half its glacial–interglacial range in only a few decades. The recent EPICA Dome C (Antarctica) record shows that methane tracked climate over the last 650 000 years, with lower methane concentrations in glacials than interglacials, and lower concentrations in cooler interglacials than in warmer ones. Nitrous oxide also shows Dansgaard–Oeschger and glacial–interglacial periodicity, but the pattern is less clear.

scholarly journals Impact of precipitation intermittency on NAO-temperature signals in proxy records

2013 ◽  
Vol 9 (2) ◽  
pp. 871-886 ◽  
Author(s):  
M. Casado ◽  
P. Ortega ◽  
V. Masson-Delmotte ◽  
C. Risi ◽  
D. Swingedouw ◽  
...  
Keyword(s):  
General Circulation ◽  
Ice Core ◽  
Circulation Model ◽  
Ice Cores ◽  
Stable Isotope Ratio ◽  
Global Network ◽  
Temporal Correlations ◽  
The North ◽  
The North Atlantic Oscillation ◽  
The Impact

Abstract. In mid and high latitudes, the stable isotope ratio in precipitation is driven by changes in temperature, which control atmospheric distillation. This relationship forms the basis for many continental paleoclimatic reconstructions using direct (e.g. ice cores) or indirect (e.g. tree ring cellulose, speleothem calcite) archives of past precipitation. However, the archiving process is inherently biased by intermittency of precipitation. Here, we use two sets of atmospheric reanalyses (NCEP (National Centers for Environmental Prediction) and ERA-interim) to quantify this precipitation intermittency bias, by comparing seasonal (winter and summer) temperatures estimated with and without precipitation weighting. We show that this bias reaches up to 10 °C and has large interannual variability. We then assess the impact of precipitation intermittency on the strength and stability of temporal correlations between seasonal temperatures and the North Atlantic Oscillation (NAO). Precipitation weighting reduces the correlation between winter NAO and temperature in some areas (e.g. Québec, South-East USA, East Greenland, East Siberia, Mediterranean sector) but does not alter the main patterns of correlation. The correlations between NAO, δ18O in precipitation, temperature and precipitation weighted temperature are investigated using outputs of an atmospheric general circulation model enabled with stable isotopes and nudged using reanalyses (LMDZiso (Laboratoire de Météorologie Dynamique Zoom)). In winter, LMDZiso shows similar correlation values between the NAO and both the precipitation weighted temperature and δ18O in precipitation, thus suggesting limited impacts of moisture origin. Correlations of comparable magnitude are obtained for the available observational evidence (GNIP (Global Network of Isotopes in Precipitation) and Greenland ice core data). Our findings support the use of archives of past δ18O for NAO reconstructions.

Tephra in the Greenland Ice cores: Insights into Icelandic volcano-climate impacts

2021 ◽  
Author(s):  
Imogen Gabriel ◽  
Gill Plunkett ◽  
Peter Abbott ◽  
Bergrún Óladóttir ◽  
Joseph McConnell ◽  
...  
Keyword(s):  
High Resolution ◽  
Ice Core ◽  
Ice Cores ◽  
Volcanic Eruptions ◽  
Climate Impacts ◽  
Geochemical Analysis ◽  
Volcanic Events ◽  
Societal Impacts ◽  
The Impact ◽  
Ice Core Records

<p>Volcanic eruptions are considered as one of the primary natural drivers for changes in the global climate system and understanding the impact of past eruptions on the climate is integral to adopt appropriate responses towards future volcanic eruptions.</p><p>The Greenland ice core records are dominated by Icelandic eruptions, with several volcanic systems (Katla, Hekla, Bárðarbunga-Veiðivötn and Grimsvötn) being highly active throughout the Holocene. A notable period of increased Icelandic volcanic activity occurred between 500-1250 AD and coincided with climatic changes in the North Atlantic region which may have facilitated the Viking settlement of Greenland and Iceland. However, a number of these volcanic events are poorly constrained (duration and magnitude). Consequently, the Greenland ice cores offer the opportunity to reliably reconstruct past Icelandic volcanism (duration, magnitude and frequency) due to their high-resolution, the proximity of Iceland to Greenland and subsequent increased likelihood of volcanic fallout deposits (tephra particles and sulphur aerosols) being preserved. However, both the high frequency of eruptions between 500-1250 AD and the geochemical similarity of Iceland’s volcanic centres present challenges in making the required robust geochemical correlations between the source volcano and the ice core records and ultimately reliably assessing the climatic-societal impacts of these eruptions.</p><p>To address this, we use two Greenland ice core records (TUNU2013 and B19) and undertake geochemical analysis on tephra from the volcanic events in the selected time window which have been detected and sampled using novel techniques (insoluble particle peaks and sulphur acidity peaks). Further geochemical analysis of proximal material enables robust correlations to be made between the events in the ice core records and their volcanic centres. The high-resolution of these polar archives provides a precise age for the event and when utilised alongside other proxies (i.e. sulphur aerosols), both the duration and magnitude of these eruptions can be constrained, and the climatic-societal impacts of these eruptions reliably assessed.</p>

On the relationship between stable isotopes and major impurity species as inferred from a two-dimensional firn sampling approach at EDML, East Antarctica

2021 ◽  
Author(s):  
Thomas Münch ◽  
Maria Hörhold ◽  
Johannes Freitag ◽  
Melanie Behrens ◽  
Thomas Laepple
Keyword(s):  
Isotopic Composition ◽  
Interannual Variability ◽  
Ice Core ◽  
Ice Cores ◽  
Temperature Changes ◽  
Impurity Species ◽  
Intermittent Precipitation ◽  
Ice Core Record ◽  
Stable Oxygen ◽  
Atmospheric Variations

<p>Ice cores constitute a major palaeoclimate archive by recording, among many others, the atmospheric variations of stable oxygen and hydrogen isotopic composition of water and of soluble ionic impurities. While impurities are used as proxies for, e.g., variations in sea ice, marine biological activity and volcanism, stable isotope records are the main source of information for the reconstruction of polar temperature changes.</p><p>However, such reconstruction efforts are complicated by the fact that temperature is by far not the only driver of isotopic composition changes. A single isotopic ice-core record will comprise variations caused by a multitude of processes, from variable atmospheric circulation and moisture pathways to the intermittency of precipitation and finally to the mixing and re-location of surface snow by wind drift (stratigraphic noise). Under the assumption that specific trace components are originally deposited with the precipitated snow and its isotopic composition, the retrieved impurity records should display a similar spatial and seasonal to interannual variability as the isotope records, caused by local stratigraphic noise as well as the time-variable and intermittent precipitation patterns, respectively.</p><p>In this contribution, we investigate the possible relationship between isotope and impurity data at the East Antarctic low-accumulation site EDML. We sampled and analysed isotopic composition and major impurity species on a four metre deep and 50 metre long trench. This enables us (1) to study the spatial (horizontal times vertical) relationship in the data, and (2) to analyse and compare the seasonal and interannual variability after removing the strong contribution of local stratigraphic noise. By this, the study improves our understanding of the depositional mechanisms that play an important role for the formation of ice-core records, and it offers to investigate the potential of using impurities to correct isotopic variability in order to improve temperature reconstructions.</p>

scholarly journals The magnitude and impact of the 431 CE Tierra Blanca Joven eruption of Ilopango, El Salvador

2020 ◽  
Vol 117 (42) ◽  
pp. 26061-26068 ◽  
Author(s):  
Victoria C. Smith ◽  
Antonio Costa ◽  
Gerardo Aguirre-Díaz ◽  
Dario Pedrazzi ◽  
Andrea Scifo ◽  
...  
Keyword(s):  
High Resolution ◽  
El Salvador ◽  
Central America ◽  
State Of The Art ◽  
Ice Core ◽  
Ice Cores ◽  
Ash Layer ◽  
Ice Core Record ◽  
Climatic Impacts ◽  
Eruption Magnitude

The Tierra Blanca Joven (TBJ) eruption from Ilopango volcano deposited thick ash over much of El Salvador when it was inhabited by the Maya, and rendered all areas within at least 80 km of the volcano uninhabitable for years to decades after the eruption. Nonetheless, the more widespread environmental and climatic impacts of this large eruption are not well known because the eruption magnitude and date are not well constrained. In this multifaceted study we have resolved the date of the eruption to 431 ± 2 CE by identifying the ash layer in a well-dated, high-resolution Greenland ice-core record that is >7,000 km from Ilopango; and calculated that between 37 and 82 km3of magma was dispersed from an eruption coignimbrite column that rose to ∼45 km by modeling the deposit thickness using state-of-the-art tephra dispersal methods. Sulfate records from an array of ice cores suggest stratospheric injection of 14 ± 2 Tg S associated with the TBJ eruption, exceeding those of the historic eruption of Pinatubo in 1991. Based on these estimates it is likely that the TBJ eruption produced a cooling of around 0.5 °C for a few years after the eruption. The modeled dispersal and higher sulfate concentrations recorded in Antarctic ice cores imply that the cooling would have been more pronounced in the Southern Hemisphere. The new date confirms the eruption occurred within the Early Classic phase when Maya expanded across Central America.

scholarly journals Black carbon variability since preindustrial times in Eastern part of Europe reconstructed from Mt Elbrus, Caucasus ice cores

2016 ◽  
Author(s):  
Saehee Lim ◽  
Xavier Faïn ◽  
Patrick Ginot ◽  
Vladimir Mikhalenko ◽  
Stanislav Kutuzov ◽  
...  
Keyword(s):  
Black Carbon ◽  
20Th Century ◽  
Biomass Burning ◽  
Mass Concentration ◽  
Ice Core ◽  
Ice Cores ◽  
Anthropogenic Emissions ◽  
Ice Core Record ◽  
Summer Time ◽  
Mass Concentrations

Abstract. Black carbon (BC), emitted by fossil fuel combustion and biomass burning, is the second largest man-made contributor to global warming after carbon dioxide (Bond et al., 2013). However, limited information exists on its past emissions and atmospheric variability. In this study, we present the first high-resolution record of refractory BC (rBC, including mass concentration and size) reconstructed from ice cores drilled at a high-altitude Eastern European site in Mt. Elbrus (ELB), Caucasus (5115 m a.s.l.). The ELB ice core record, covering the period 1825–2013, reflects the atmospheric load of rBC particles at the ELB site transported from the European continent with a larger rBC input from sources located in the Eastern part of Europe. In the first half of the 20th century, European anthropogenic emissions resulted in a 1.5-fold increase in the ice core rBC mass concentrations as respect to its level in the preindustrial era (before 1850). The rBC mass concentrations increased by a 5-fold in 1960–1980, followed by a decrease until ~ 2000. Over the last decade, the rBC signal for summer time slightly increased. We have compared the signal with the atmospheric BC load simulated using past BC emissions (ACCMIP and MACCity inventories) and taken into account the contribution of different geographical region to rBC distribution and deposition at the ELB site. Interestingly, the observed rBC variability in the ELB ice core record since the 1960s is not in perfect agreement with the simulated atmospheric BC load. Similar features between the ice core rBC record and the best scenarios for the atmospheric BC load support that anthropogenic BC increase in the 20th century is reflected in the ELB ice core record. However, the peak in BC mass concentration observed in ~ 1970 in the ice core is estimated to occur a decade later from past inventories. BC emission inventories for the period 1960s–1970s may be underestimating European anthropogenic emissions. Furthermore, for summer time snow layers of the last 2000s, the slightly increasing trend of rBC deposition likely reflects recent changes in anthropogenic and biomass burning BC emissions in the Eastern part of Europe. Our study highlights that the past changes in BC emissions of Eastern Europe need to be considered in assessing on-going air quality regulation.

scholarly journals The Elbrus (Caucasus, Russia) ice core record – Part 1: reconstruction of past anthropogenic sulfur emissions in south-eastern Europe

2019 ◽  
Vol 19 (22) ◽  
pp. 14119-14132 ◽  
Author(s):  
Susanne Preunkert ◽  
Michel Legrand ◽  
Stanislav Kutuzov ◽  
Patrick Ginot ◽  
Vladimir Mikhalenko ◽  
...  
Keyword(s):  
Eastern Europe ◽  
Western Europe ◽  
Ice Core ◽  
Ice Cores ◽  
Fold Increase ◽  
South Eastern ◽  
Basal Ice ◽  
Ice Core Record ◽  
South Eastern Europe ◽  
The 19Th Century

Abstract. This study reports on the glaciochemistry of a deep ice core (182 m long) drilled in 2009 at Mount Elbrus in the Caucasus, Russia. Radiocarbon dating of the particulate organic carbon fraction in the ice suggests that the basal ice dates to 280±400 CE (Common Era). Based on chemical stratigraphy, the upper 168.6 m of the core was dated by counting annual layers. The seasonally resolved chemical records cover the years 1774–2009 CE, thus being useful to reconstruct many aspects of atmospheric pollution in south-eastern Europe from pre-industrial times to the present day. After having examined the extent to which the arrival of large dust plumes originating from the Sahara and Middle East modifies the chemical composition of the Elbrus (ELB) snow and ice layers, we focus on the dust-free sulfur pollution. The ELB dust-free sulfate levels indicate a 6- and 7-fold increase from 1774–1900 to 1980–1995 in winter and summer, respectively. Remaining close to 55±10 ppb during the 19th century, the annual dust-free sulfate levels started to rise at a mean rate of ∼3 ppb per year from 1920 to 1950. The annual increase accelerated between 1950 and 1975 (8 ppb per year), with levels reaching a maximum between 1980 and 1990 (376±10 ppb) and subsequently decreasing to 270±18 ppb at the beginning of the 21st century. Long-term dust-free sulfate trends observed in the ELB ice cores are compared with those previously obtained in Alpine and Altai (Siberia) ice, with the most important differences consisting in a much earlier onset and a more pronounced decrease in the sulfur pollution over the last 3 decades in western Europe than south-eastern Europe and Siberia.

scholarly journals Polar ice stratigraphy from laser-light scattering: scattering from meltwater

1994 ◽  
Vol 40 (136) ◽  
pp. 504-508 ◽  
Author(s):  
Michael Ram ◽  
Matthias Illing
Keyword(s):  
Light Scattering ◽  
Sample Size ◽  
Tree Ring ◽  
Laser Light ◽  
Ice Core ◽  
Ice Cores ◽  
Laser Light Scattering ◽  
Polar Ice ◽  
The Core ◽  
Considerable Success

Abstract We describe a new laser-light-scattering instrument for measuring variations in dust concentration along polar ice cores. We have used this instrument with considerable success on the GISP2 ice core from central Greenland. Reproducibility is excellent and the required ice-sample size is relatively small. When combined with visual stratigraphy and ECM, the distinct annual spring/ summer dust peaks we observe can be used to date the core with tree-ring-like precision.

scholarly journals Towards radiocarbon dating of ice cores

2009 ◽  
Vol 55 (194) ◽  
pp. 985-996 ◽  
Author(s):  
M. Sigl ◽  
T.M. Jenk ◽  
T. Kellerhals ◽  
S. Szidat ◽  
H.W. Gäggeler ◽  
...  
Keyword(s):  
Aerosol Particles ◽  
Ice Core ◽  
Ice Cores ◽  
Swiss Alps ◽  
Carbonaceous Aerosol ◽  
Polar Ice ◽  
Low Latitude ◽  
Bolivian Andes ◽  
Glacier Ice ◽  
Dating Method

AbstractA recently developed dating method for glacier ice, based on the analysis of radiocarbon in carbonaceous aerosol particles, is thoroughly investigated. We discuss the potential of this method to achieve a reliable dating using examples from a mid- and a low-latitude ice core. Two series of samples from Colle Gnifetti (4450 m a.s.l., Swiss Alps) and Nevado Illimani (6300 m a.s.l., Bolivian Andes) demonstrate that the 14C ages deduced from the water-insoluble organic carbon fraction represent the age of the ice. Sample sizes ranged between 7 and 100 μg carbon. For validation we compare our results with those from independent dating. This new method is thought to have major implications for dating non-polar ice cores in the future, as it provides complementary age information for time periods not accessible with common dating techniques.

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