The Youngest Toba Tuff (74 ka) Crystals Characterization

2020 ◽  
Author(s):  
Gabriela Nogo Retnaningtyas Bunga Naen ◽  
Atsushi Toramaru ◽  
Tomoharu Miyamoto ◽  
Haryo Edi Wibowo
Keyword(s):  
Magma Chamber ◽  
Fractional Crystallization ◽  
Optical Microscope ◽  
Oscillatory Zoning ◽  
Geochemical Data ◽  
Thin Sections ◽  
Decompression Rate ◽  
Wide Range ◽  
Different Characteristics ◽  
Toba Caldera

<p>Toba Caldera Complex, Indonesia is well known as the largest Quaternary caldera (87x33 km) that formed by four major eruptions among which the biggest one is the eruption of the Youngest Toba Tuff (YTT) about 74,000 years ago. Textural study of the pumice clast from YTT has been done to estimate the decompression rate by using bubble number density data. The result shows that decompression rate of Toba Caldera forming eruption varies in two order magnitude ranging from 10<sup>6 </sup>– 10<sup>8</sup> Pa/s. Southern pumices show the lower value than pumices from northern caldera. Similarly, new data about lithic distributions and mineral components of YTT from the northern and southern caldera showed several different characteristics. This fact suggests possibility of different processes which is distinguish production of southern and northern deposits. Therefore, understanding both conduit and chamber processes is needed to reveal the origin of differences in deposits. This study aims to elucidate magma chamber condition by characterizing the deposit especially crystals from YTT eruption.</p><p>Characterizations of Toba Tuffs have been made but not been enough to discuss YTT in detail. In this study, we focus on spatial differences in YTT deposits. Samples from four different locations were employed for the analyses. Component analysis was carried out on components larger than 2 mm. Whole-rock geochemical data were obtained by XRF. Petrography analysis for 37 thin sections was conducted using optical microscope. Textural analysis was carried out for 84 free crystals and 25 selected thin sections using microphotographs taken by SEM and further analyzed using image processing software. Chemical analysis for free crystal was carried out by SEM-EDS, while for pumices grain of 22 thin sections was conducted using EPMA.</p><p>Geochemical data showed that YTT magma is rhyodacitic to rhyolitic in whole-rock compositions with wide range of SiO<sub>2</sub> (69.15–76.83 wt.%). There are differences in abundance and type of pumices, free crystals, and lithic in each location<strong>.</strong> Major minerals are plagioclase, biotite, sanidine, and quartz. Common characteristics of northern and southern part deposit is that most of crystals are fractured, some forming aggregates, has anhedral shape and wide variation in size (0.003 mm<sup>2</sup>-13.113 mm<sup>2</sup>). However, there are differences between northern and southern deposits: presence of amphibole with larger size, orange quartz, sieve texture, patchy zoning, oscillatory zoning, crystal clots, and wider range of anorthite (An<sub>25</sub>– An<sub>87</sub>) is mostly found in northern deposits.</p><p>Plagioclase composition from northern part shows bimodal distribution suggesting that crystallization does not occur simultaneously by single process. Furthermore, plots of anorthite number versus size and of average anorthite number versus crystal content show random distribution, suggesting the complex crystallization of plagioclase: other processes than fractional crystallization in magma chamber. Moreover, presence of antecryst and disequilibrium textures in northern deposit indicates intervention from older rocks or even other systems. Different characteristics between northern and southern deposits suggest that YTT deposits are generated by multiple eruptions from independent, at least two magma chambers.</p><p>Keywords: Toba Caldera, the Youngest Toba Tuff (YTT), Crystal Characterization, Conduit Process, Chamber Process, Fractional Crystallization, Multiple eruptions</p>

Micro X-ray diffraction (µXRD): a versatile technique for characterization of Earth and planetary materials

2007 ◽  
Vol 44 (9) ◽  
pp. 1333-1346 ◽  
Author(s):  
Roberta L Flemming
Keyword(s):  
Ccd Camera ◽  
Optical Microscope ◽  
X Ray Diffraction ◽  
Thin Sections ◽  
X Ray ◽  
Area Detector ◽  
Wide Range ◽  
Individual Grains ◽  
Planetary Materials

Recent developments in laboratory-based micro X-ray diffraction (µXRD) have extended X-ray examination of geomaterials to the microscopic level (50–500 µm), greatly expanding the applicability of XRD to mineralogy, petrology, materials, environmental, and planetary sciences. Laboratory-based µXRD has been accomplished using a Bruker™ D8 Discover diffractometer, having a sealed-tube Cu source, theta–theta geometry, Gobel mirror parallel optics with 50–500 µm collimation, and general area detector diffraction system (GADDS). A wide range of samples, including polished thin sections, electron probe microanalysis (EPMA) mounts, rock slabs, whole rocks, and powders have been examined with µXRD using a remote-controlled XYZ sample stage, with imaging by optical microscope monitor and charge-coupled device (CCD) camera. Individual grains in heterogeneous samples have been examined in situ, with little or no sample preparation. The two-dimensional GADDS preserves textural and crystallinity information (e.g., bioapatite) and easily discriminates between multiple phases of utility for synthetic or natural samples (e.g., mine tailings). In situ µXRD of minerals preserves spatial relationships, enabling study of orientational phenomena, such as strain-related mosaicity (giving “streaked” diffraction lines). Examples include strained quartz (La Malbaie quartzite, Quebec) and shocked clinopyroxenes (Shergottite NWA 3171). Mineral mapping has been demonstrated by reproducing exsolution textures of kamacite from taenite (Widmanstätten pattern) in the Toluca iron meteorite. Diffraction data obtained from single crystals (by the omega scan method) have enabled grain-by-grain correlation between unit cell (µXRD) and chemical composition (EPMA), as demonstrated by kimberlite indicator garnets. The examples shown herein demonstrate the breadth of information that can be obtained by µXRD of Earth and planetary materials.

Some early history of replica techniques for electron microscopy

1992 ◽  
Vol 50 (2) ◽  
pp. 1076-1077
Author(s):  
Robert M. Fisher
Keyword(s):  
Thin Film ◽  
Electron Microscopy ◽  
Optical Microscope ◽  
Early History ◽  
Bulk Materials ◽  
Thin Sections ◽  
Transmission Electron ◽  
Reflected Light ◽  
History Of ◽  
Electron Microscopes

By 1940, a half dozen or so commercial or home-built transmission electron microscopes were in use for studies of the ultrastructure of matter. These operated at 30-60 kV and most pioneering microscopists were preoccupied with their search for electron transparent substrates to support dispersions of particulates or bacteria for TEM examination and did not contemplate studies of bulk materials. Metallurgist H. Mahl and other physical scientists, accustomed to examining etched, deformed or machined specimens by reflected light in the optical microscope, were also highly motivated to capitalize on the superior resolution of the electron microscope. Mahl originated several methods of preparing thin oxide or lacquer impressions of surfaces that were transparent in his 50 kV TEM. The utility of replication was recognized immediately and many variations on the theme, including two-step negative-positive replicas, soon appeared. Intense development of replica techniques slowed after 1955 but important advances still occur. The availability of 100 kV instruments, advent of thin film methods for metals and ceramics and microtoming of thin sections for biological specimens largely eliminated any need to resort to replicas.

scholarly journals Petrology and mineralogy of the Viñales meteorite, the latest fall in Cuba

2021 ◽  
Vol 104 (2) ◽  
pp. 003685042110198
Author(s):  
Feng Yin ◽  
Deqiu Dai
Keyword(s):  
Microprobe Analysis ◽  
Electron Microprobe Analysis ◽  
Optical Microscope ◽  
Chemical Compositions ◽  
Atmospheric Entry ◽  
Thin Sections ◽  
Homogeneous Chemical ◽  
Del Rio ◽  
The Masses ◽  
Metal Phases

The new Cuban chondrite, Viñales, fell on February first, 2019 at Pinar del Rio, northwest of Cuba (22°37′10″N, 83°44′34″W). A total of about 50–100 kg of the meteorite were collected and the masses of individual samples are in a range 2–1100 g. Two polished thin sections were studied by optical microscope, Raman spectroscopy and electron microprobe analysis in this study. The meteorite mainly consists of olivine (Fa24.6), low-Ca pyroxene (Fs20.5), and troilite and Fe-Ni metal, with minor amounts of feldspar (Ab82.4-84.7). Three poorly metamorphosed porphyritic olivine-pyroxene and barred olivine chondrules are observed. The homogeneous chemical compositions and petrographic textures indicate that Viñales is a L6 chondrite. The Viñales has fresh black fusion crust with layered structure, indicating it experienced a high temperature of ∼1650°C during atmospheric entry. Black shock melt veins with width of 100–600 μm are pervasive in the Viñales and olivine, bronzite, and metal phases are dominate minerals of the shock melt vein. The shock features of major silicate minerals suggest a shock stage S3, partly S4, and the shock pressure could be >10 GPa.

scholarly journals Mantle Melting and Magmatic Processes Under La Picada Stratovolcano (CSVZ, Chile)

2019 ◽  
Vol 60 (5) ◽  
pp. 907-944 ◽  
Author(s):  
Jacqueline Vander Auwera ◽  
Olivier Namur ◽  
Adeline Dutrieux ◽  
Camilla Maya Wilkinson ◽  
Morgan Ganerød ◽  
...  
Keyword(s):  
Fractional Crystallization ◽  
Geochemical Data ◽  
Upper Crust ◽  
Volcanic Zone ◽  
Nazca Plate ◽  
Southern Volcanic Zone ◽  
Magmatic Processes ◽  
Crystal Accumulation ◽  
Primary Magmas ◽  
Differentiation Trend

Abstract Where and how arc magmas are generated and differentiated are still debated and these questions are investigated in the context of part of the Andean arc (Chilean Southern Volcanic Zone) where the continental crust is thin. Results are presented for the La Picada stratovolcano (41°S) that belongs to the Central Southern Volcanic Zone (CSVZ) (38°S–41·5°S, Chile) which results from the subduction of the Nazca plate beneath the western margin of the South American continent. Forty-seven representative samples collected from different units of the volcano define a differentiation trend from basalt to basaltic andesite and dacite (50·9 to 65·6 wt % SiO2). This trend straddles the tholeiitic and calc-alkaline fields and displays a conspicuous compositional Daly Gap between 57·0 and 62·7 wt % SiO2. Interstitial, mostly dacitic, glass pockets extend the trend to 76·0 wt % SiO2. Mineral compositions and geochemical data indicate that differentiation from the basaltic parent magmas to the dacites occurred in the upper crust (∼0·2 GPa) with no sign of an intermediate fractionation stage in the lower crust. However, we have currently no precise constraint on the depth of differentiation from the primary magmas to the basaltic parent magmas. Stalling of the basaltic parent magmas in the upper crust could have been controlled by the occurrence of a major crustal discontinuity, by vapor saturation that induced volatile exsolution resulting in an increase of melt viscosity, or by both processes acting concomitantly. The observed Daly Gap thus results from upper crustal magmatic processes. Samples from both sides of the Daly Gap show contrasting textures: basalts and basaltic andesites, found as lavas, are rich in macrocrysts, whereas dacites, only observed in crosscutting dykes, are very poor in macrocrysts. Moreover, modelling of the fractional crystallization process indicates a total fractionation of 43% to reach the most evolved basaltic andesites. The Daly Gap is thus interpreted as resulting from critical crystallinity that was reached in the basaltic andesites within the main storage region, precluding eruption of more evolved lavas. Some interstitial dacitic melt was extracted from the crystal mush and emplaced as dykes, possibly connected to small dacitic domes, now eroded away. In addition to the overall differentiation trend, the basalts to basaltic andesites display variable MgO, Cr and Ni contents at a given SiO2. Crystal accumulation and high pressure fractionation fail to predict this geochemical variability which is interpreted as resulting from variable extents of fractional crystallization. Geothermobarometry using recalculated primary magmas indicates last equilibration at about 1·3–1·5 GPa and at a temperature higher than the anhydrous peridotite solidus, pointing to a potential role of decompression melting. However, because the basalts are enriched in slab components and H2O compared to N-MORB, wet melting is highly likely.

Early Cretaceous crust–mantle interaction linked to rollback of the Palaeo-Pacific flat-subducting slab: constraints from the intermediate–felsic volcanic rocks of the northern Great Xing’an Range, NE China

2021 ◽  
pp. 1-22
Author(s):  
Jia-Hao Jing ◽  
Hao Yang ◽  
Wen-Chun Ge ◽  
Yu Dong ◽  
Zheng Ji ◽  
...  
Keyword(s):  
Early Cretaceous ◽  
Volcanic Rocks ◽  
Geochemical Data ◽  
Calc Alkaline ◽  
Ne China ◽  
Asthenospheric Mantle ◽  
High K ◽  
Wide Range ◽  
Great Xing’An Range ◽  
Subducting Slab

Abstract Late Mesozoic igneous rocks are important for deciphering the Mesozoic tectonic setting of NE China. In this paper, we present whole-rock geochemical data, zircon U–Pb ages and Lu–Hf isotope data for Early Cretaceous volcanic rocks from the Tulihe area of the northern Great Xing’an Range (GXR), with the aim of evaluating the petrogenesis and genetic relationships of these rocks, inferring crust–mantle interactions and better constraining extension-related geodynamic processes in the GXR. Zircon U–Pb ages indicate that the rhyolites and trachytic volcanic rocks formed during late Early Cretaceous time (c. 130–126 Ma). Geochemically, the highly fractionated I-type rhyolites exhibit high-K calc-alkaline, metaluminous to weakly peraluminous characteristics. They are enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs) but depleted in high-field-strength elements (HFSEs), with their magmatic zircons ϵHf(t) values ranging from +4.1 to +9.0. These features suggest that the rhyolites were derived from the partial melting of a dominantly juvenile, K-rich basaltic lower crust. The trachytic volcanic rocks are high-K calc-alkaline series and exhibit metaluminous characteristics. They have a wide range of zircon ϵHf(t) values (−17.8 to +12.9), indicating that these trachytic volcanic rocks originated from a dominantly lithospheric-mantle source with the involvement of asthenospheric mantle materials, and subsequently underwent extensive assimilation and fractional crystallization processes. Combining our results and the spatiotemporal migration of the late Early Cretaceous magmatic events, we propose that intense Early Cretaceous crust–mantle interaction took place within the northern GXR, and possibly the whole of NE China, and that it was related to the upwelling of asthenospheric mantle induced by rollback of the Palaeo-Pacific flat-subducting slab.

Rheo-Optics Studies in the Development of Hybrid Liquid Crystalline Based Mwir Polarizers

1999 ◽  
Vol 559 ◽  
Author(s):  
P.T. Mather ◽  
W. Barnes ◽  
P.J. Hood ◽  
T.J. Bunning
Keyword(s):  
Liquid Crystalline ◽  
Flow Behavior ◽  
Optical Microscope ◽  
Processing Technique ◽  
Strain Rates ◽  
Alignment Layer ◽  
Small Pitch ◽  
Wide Range ◽  
Measured Polarization ◽  
Free Films

ABSTRACTWe present here a rheo-optical study of the flow behavior of two cholesteric liquid crystals, one with a large pitch and one with a small pitch. The large pitch compound has been investigated as a possible fixed wavelength polarizer in the mid-wavelength infra-red region (3-5 micron). The investigation of these compounds is driven by their low melt viscosity and ability to vitrify order, and thus functionality, into films with a wide range of thickness. In our attempts to obtain consistent thin films with reproducible contrast ratios, we explored the defect textures of both compounds under a polarizing optical microscope. These materials were sheared at various strain rates and at various temperatures in an attempt to determine the best processing window for defect free films. The pitch lengths of the two materials investigated were 160 and 1330 nm. The flow behavior of the large pitch material resembles a pure nematic with defect refinement taking place under flow. The short pitch material exhibited the typical Grandjean oily streaks upon shearing followed by coarsening. Observations made during this rheological study were used to identify a processing technique for the large pitch materials. Upon application of a conventional buffed alignment layer, films with consistent quality were routinely made. The measured polarization contrast of >70:1 exceeds the values obtained from state-of-the art commercial polarizers in this wavelength regime.

scholarly journals Evidence of mingling between contrasting magmas in a deep plutonic environment: the example of Várzea Alegre, in the Ribeira Mobile Belt, Espírito Santo, Brazil

2001 ◽  
Vol 73 (1) ◽  
pp. 99-119 ◽  
Author(s):  
SILVIA R. MEDEIROS ◽  
CRISTINA M. WIEDEMANN-LEONARDOS ◽  
SIMON VRIEND
Keyword(s):  
Partial Melting ◽  
Granitic Magma ◽  
Geochemical Data ◽  
Mobile Belt ◽  
Tholeiitic Magma ◽  
Rock Types ◽  
Upper Proterozoic ◽  
Incompatible Elements ◽  
Wide Range ◽  
Intermediate Rock

At the end of the geotectonic cycle that shaped the northern segment of the Ribeira Mobile Belt (Upper Proterozoic to Paleozoic age), a late to post-collisional set of plutonic complexes, consisting of a wide range of lithotypes, intruded all metamorphic units. The Várzea Alegre Intrusive Complex is a post-collisional complex. The younger intrusion consists of an inversely zoned multistage structure envolved by a large early emplaced ring of megaporphyritic charnoenderbitic rocks. The combination of field, petrographic and geochemical data reveals the presence of at least two different series of igneous rocks. The first originated from the partial melting of the mantle. This was previously enriched in incompatible elements, low and intermediate REE and some HFS-elements. A second enrichment in LREE and incompatible elements in this series was due to the mingling with a crustal granitic magma. This mingling process changed the composition of the original tholeiitic magma towards a medium-K calc-alkalic magma to produce a suite of basic to intermediate rock types. The granitic magma from the second high-K, calc-alkalic suite originated from the partial melting of the continental crust, but with strong influence of mantle-derived melts.

scholarly journals Global whole-rock geochemical database compilation

2019 ◽  
Author(s):  
Matthew Gard ◽  
Derrick Hasterok ◽  
Jacqueline Halpin
Keyword(s):  
Database Management ◽  
Temporal Trends ◽  
Physical Property ◽  
Database Management System ◽  
Geochemical Data ◽  
Data Sets ◽  
Unique Contribution ◽  
Data Set ◽  
Wide Range ◽  
Geochemical Indices

Abstract. Dissemination and collation of geochemical data are critical to promote rapid, creative and accurate research and place new results in an appropriate global context. To this end, we have assembled a global whole-rock geochemical database, with other associated sample information and properties, sourced from various existing databases and supplemented with numerous individual publications and corrections. Currently the database stands at 1,023,490 samples with varying amounts of associated information including major and trace element concentrations, isotopic ratios, and location data. The distribution both spatially and temporally is quite heterogeneous, however temporal distributions are enhanced over some previous database compilations, particularly in terms of ages older than ~ 1000 Ma. Also included are a wide range of computed geochemical indices, physical property estimates and naming schema on a major element normalized version of the geochemical data for quick reference. This compilation will be useful for geochemical studies requiring extensive data sets, in particular those wishing to investigate secular temporal trends. The addition of physical properties, estimated by sample chemistry, represents a unique contribution to otherwise similar geochemical databases. The data is published in .csv format for the purposes of simple distribution but exists in a format acceptable for database management systems (e.g. SQL). One can either manipulate this data using conventional analysis tools such as MATLAB®, Microsoft® Excel, or R, or upload to a relational database management system for easy querying and management of the data as unique keys already exist. This data set will continue to grow, and we encourage readers to contact us or other database compilations contained within about any data that is yet to be included. The data files described in this paper are available at https://doi.org/10.5281/zenodo.2592823 (Gard et al., 2019).

Mineral chemistry and geothermobarometry of the Balıkesir Volcanites (NW Anatolia, Turkey) 

2021 ◽  
Author(s):  
Alp Ünal ◽  
Şafak Altunkaynak
Keyword(s):  
Mineral Composition ◽  
Magma Chamber ◽  
Magma Mixing ◽  
Textural Properties ◽  
Mineral Chemistry ◽  
Oscillatory Zoning ◽  
Magma Chamber Processes ◽  
Crystallization Conditions ◽  
Compositional Variations ◽  
Opaque Minerals

<p>Balıkesir Volcanites (BV) are included into the Balıkesir Volcanic Province and contain various products of Oligo-Miocene volcanic activity in NW Anatolia. BV are formed from trachyandesite, andesite and dacite lavas with associated pyroclastic rocks. In this study, we report the petrographical investigations, mineral chemistry results and geothermobarometry calculations of the Balıkesir Volcanites in order to deduce the magma chamber processes and crystallization conditions. Andesites present a mineral composition of plagioclase (An35–50) + amphibole (edenitic hornblende) +biotite ± quartz and opaque minerals. The major phenocryst phases in dacite lavas are plagioclase (An39–53), quartz, amphibole (magnesio-hornblende), biotite, sanidine and opaque minerals. The mineral composition of the trachyandesites, on the other hand, is represented by plagioclase (An38–57) + amphibole (pargasitic hornblende) + biotite + clinopyroxene (endiopside- augite) ± sanidine ± quartz ± opaque minerals. Balıkesir Volcanites present distinct textural properties such as rounded plagioclase phenocrysts with reaction rims, oscillatory zoning, honeycomb and sieve textures in plagioclase, reverse mantled biotite and hornblende crystals. The plagioclase- amphibole geothermobarometry calculations of Balıkesir volcanites indicate that, andesite and dacite lavas present similar crystallization temperature and pressures conditions of 798- 813°C and 1,98- 2.17 kbar. Oppositely, trachyandesites were crystallized under 857°C and 3,72 kbar temperature and pressure conditions. These results show that the andesite and dacite lavas were originated from the same magma chamber with the depth of 7km whereas trachyandesites were evolved in a deeper magma chamber with 13 km depth. Combined mineral chemistry, petrography and geothermobarometry studies indicate that the open system processes such as magma mixing/mingling and/or assimilation fractional crystallization (AFC) were responsible for the textural and compositional variations of the Balıkesir Volcanites.</p>

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