Toward CO2 and CH4 measurements by ground-based observations of surface-scattered sunlight: Instrumentation and experiments

2020 ◽  
Author(s):  
Benedikt Hemmer ◽  
Philip Holzbeck ◽  
Ralph Kleinschek ◽  
Marvin Knapp ◽  
Julian Kostinek ◽  
...  
Keyword(s):  
Urban Areas ◽  
Tracking System ◽  
Lower Boundary ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Atmospheric Scattering ◽  
Horizontal Path ◽  
Precise Knowledge ◽  
Path Component

<div> <div>Precise knowledge of sources and sinks in the carbon cycle is desired to understand its sensitivity to climate change, and to account and verify man-made emissions. An important role herein play extended sources like urban areas. While in-situ measurements of carbon dioxide (CO<sub>2</sub>) and methane (CH<sub>4</sub>) are highly accurate but localized, satellites measure column-integrated concentrations over an extended footprint. Our innovative measurement technique aims at determining CO<sub>2</sub> and CH<sub>4</sub> concentrations on the scale of a few kilometers near the ground, and therefore fills the sensitivity gap between in-situ and satellite measurements.</div> <div> </div> <div>Our development starts out from the EM27/SUN Fourier transform spectrometer, which is a reliable, mobile and commercially available spectrometer for the measurement of CO<sub>2</sub> and CH<sub>4</sub> column densities using direct sunlight spectra. We increased the radiometric sensitivity of the instrument by enhancing optical throughput and replacing the detector module by a thermoelectrically cooled detector. This enables the measurement of surface scattered sunlight spectra in the range of 4000 - 11000 cm<sup>-1</sup> under various viewing directions. Our setup is independent of sun position and exhibits a high sensitivity to the concentrations in the lower boundary layer, due to the near ground horizontal path component.</div> <div> </div> <div>Here, we report progress on our instrumental developments, as well as first retrievals of column averaged CO<sub>2</sub> and CH<sub>4</sub> mole fractions from ground-scattered sunlight spectra recorded with this setup. We present the instrument modifications and extensions to the experimental setup: A Lambertian reflector allows for reference measurements without horizontal path component, a coaligned camera enables specific targeting and the motorized tracking system facilitates automated alternation between multiple targets. We characterize the setup with a spectral resolution of 0.54 ± 0.03 cm<sup>-1</sup> a signal to noise ratio above 200 for solar zenith angles < 85°, and precision of 1.8 ppm and 9 ppb regarding the inferred column averaged CO<sub>2</sub> and CH<sub>4</sub> mole fractions obtained from retrievals with a simple radiative transfer model, neglecting atmospheric scattering.</div> </div>

Toward CO2 and CH4 measurements by ground based observations of surface-scattered sunlight: Radiative transfer modeling

2020 ◽  
Author(s):  
Christin Proß ◽  
Benedikt Hemmer ◽  
Constanze Wellmann ◽  
Julian Kostinek ◽  
André Butz
Keyword(s):  
Radiative Transfer ◽  
Urban Areas ◽  
Scattered Light ◽  
Simultaneous Estimation ◽  
Atmospheric Scattering ◽  
Precise Knowledge ◽  
First Results ◽  
Extended Sources ◽  
Retrieval Software

<p>Precise knowledge of sources and sinks in the carbon cycle is desired to understand<br>its sensitivity to climate change and to account and verify man-made emissions. An<br>important role herein play extended sources like urban areas. While in-situ measure-<br>ments of carbon dioxide (CO<sub>2</sub>) and methane (CH<sub>4</sub>) are highly accurate but localized,<br>satellites measure column-integrated concentrations over an extended footprint. Our<br>innovative measurement technique aims at determining CO<sub>2</sub> and CH<sub>4</sub> concentrations<br>near to the ground on the scale of a few kilometers and therefore fills the sensitivity<br>gap between in-situ and satellite measurements.<br>Using a modified EM27/SUN Fourier transform spectrometer we are able to record<br>spectra of surface scattered sunlight in the range of 4000 − 11000 cm<sup>−1</sup> . To accurately<br>retrieve CO<sub>2</sub> and CH<sub>4</sub> concentrations an advanced retrieval method is required that<br>includes the simultaneous estimation of atmospheric scattering properties.<br>Based on our radiative transfer and retrieval software RemoTeC, we built a simulation<br>environment that includes atmospheric scattering processes. With this tool we can<br>generate and retrieve synthetic scattered light observations. Here we present our<br>simulation environment, first results and ongoing developments.</p>

Toward CO2 and CH4 measurements by ground-based observations of surface-scattered sunlight

2021 ◽  
Author(s):  
Benedikt Hemmer ◽  
Christin Proß ◽  
Stanley P. Sander ◽  
Thomas J. Pongetti ◽  
Zhao-Cheng Zeng ◽  
...  
Keyword(s):  
Los Angeles ◽  
Urban Areas ◽  
Near Infrared ◽  
Chem Phys ◽  
Retrieval Algorithm ◽  
Los Angeles Basin ◽  
Satellite Measurements ◽  
Precise Knowledge ◽  
Extended Sources

<div> <div>Precise knowledge of sources and sinks in the carbon cycle is desired to understand its sensitivity to climate change and to account and verify man-made emissions. In this context, extended sources like urban areas play an important role. While in-situ measurements of carbon dioxide (CO<sub>2</sub>) and methane (CH<sub>4</sub>) are highly accurate but localized, satellites measure column-integrated concentrations over an extended footprint. The CLARS-FTS [1, 2] stationed at the Mt. Wilson observatory looking downward into the Los Angeles basin has pioneered an innovative measurement technique that fills the sensitivity gap between in-situ and satellite measurements. The technique enables mapping the urban greenhouse gas concentration fields by collecting spectra of ground scattered sunlight and scanning through the region.</div> <div> </div> <div>Here, we report on progress developing a portable setup for a CLARS-FTS-like measurement geometry. The instrument is based on the EM27/SUN FTS with a modified pointing technique and a more sensitive detector. The retrieval algorithm is based on the RemoTeC software, previously employed for solar backscatter satellite measurements. We discuss first steps in terms of instrument performance and retrieval exercises. For the latter, we have carried out simulations on how the neglect of scattering by the retrieval affects the retrieved boundary layer concentrations of CO<sub>2</sub> and CH<sub>4</sub> for an ensemble of hypothetical scenes with variable complexity in aeorsol loadings and viewing geometry. We also report on a test to apply RemoTeC to a small set of CLARS-FTS spectra collected throughout the Los Angeles basin.</div> <div> </div> <div><em>References</em></div> <div>[1] Fu, D. et al., 2014: Near-infrared remote sensing of Los Angeles trace gas distributions from a mountaintop site, Atmos. Meas. Tech., 7, 713–729, https://doi.org/10.5194/amt-7-713-2014</div> [2] Wong, K. W. et al., 2015: Mapping CH4 : CO2 ratios in Los Angeles with CLARS-FTS from Mount Wilson, California, Atmos. Chem. Phys., 15, 241–252, https://doi.org/10.5194/acp-15-241-2015</div>

scholarly journals Level 2 processing for the imaging Fourier transform spectrometer GLORIA: derivation and validation of temperature and trace gas volume mixing ratios from calibrated dynamics mode spectra

2015 ◽  
Vol 8 (6) ◽  
pp. 2473-2489 ◽  
Author(s):  
J. Ungermann ◽  
J. Blank ◽  
M. Dick ◽  
A. Ebersoldt ◽  
F. Friedl-Vallon ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Horizontal Resolution ◽  
Trace Gas ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Ionization Mass ◽  
Fourier Transform Spectrometer ◽  
Upper Troposphere ◽  
Mixing Ratios

Abstract. The Gimballed Limb Observer for Radiance Imaging of the Atmosphere (GLORIA) is an airborne infrared limb imager combining a two-dimensional infrared detector with a Fourier transform spectrometer. It was operated aboard the new German Gulfstream G550 High Altitude LOng Range (HALO) research aircraft during the Transport And Composition in the upper Troposphere/lowermost Stratosphere (TACTS) and Earth System Model Validation (ESMVAL) campaigns in summer 2012. This paper describes the retrieval of temperature and trace gas (H2O, O3, HNO3) volume mixing ratios from GLORIA dynamics mode spectra that are spectrally sampled every 0.625 cm−1. A total of 26 integrated spectral windows are employed in a joint fit to retrieve seven targets using consecutively a fast and an accurate tabulated radiative transfer model. Typical diagnostic quantities are provided including effects of uncertainties in the calibration and horizontal resolution along the line of sight. Simultaneous in situ observations by the Basic Halo Measurement and Sensor System (BAHAMAS), the Fast In-situ Stratospheric Hygrometer (FISH), an ozone detector named Fairo, and the Atmospheric chemical Ionization Mass Spectrometer (AIMS) allow a validation of retrieved values for three flights in the upper troposphere/lowermost stratosphere region spanning polar and sub-tropical latitudes. A high correlation is achieved between the remote sensing and the in situ trace gas data, and discrepancies can to a large extent be attributed to differences in the probed air masses caused by different sampling characteristics of the instruments. This 1-D processing of GLORIA dynamics mode spectra provides the basis for future tomographic inversions from circular and linear flight paths to better understand selected dynamical processes of the upper troposphere and lowermost stratosphere.

scholarly journals SEVIRI Hyper-Fast Forward Model with Application to Emissivity Retrieval

Sensors ◽  
2019 ◽  
Vol 19 (7) ◽  
pp. 1532 ◽  
Author(s):  
Guido Masiello ◽  
Carmine Serio ◽  
Sara Venafra ◽  
Laurent Poutier ◽  
Frank-M. Göttsche
Keyword(s):  
Radiative Transfer ◽  
Real Time ◽  
Forward Model ◽  
Radiative Transfer Model ◽  
Computational Time ◽  
Transfer Model ◽  
Real Time Processing ◽  
In Situ Observations ◽  
Infrared Radiances

Timely processing of observations from multi-spectral imagers, such as SEVIRI (Spinning Enhanced Visible and Infrared Imager), largely depends on fast radiative transfer calculations. This paper mostly concerns the development and implementation of a new forward model for SEVIRI to be applied to real time processing of infrared radiances. The new radiative transfer model improves computational time by a factor of ≈7 compared to the previous versions and makes it possible to process SEVIRI data at nearly real time. The new forward model has been applied for the retrieval of surface parameters. Although the scheme can be applied for the simultaneous retrieval of temperature and emissivity, the paper mostly focuses on emissivity. The inverse scheme relies on a Kalman filter approach, which allows us to exploit a sequential processing of SEVIRI observations. Based on the new forward model, the paper also presents a validation retrieval performed with in situ observations acquired during a field experiment carried out in 2017 at Gobabeb (Namib desert) validation station. Furthermore, a comparison with IASI (Infrared Atmospheric Sounder Interferometer) emissivity retrievals has been performed as well. It has been found that the retrieved emissivities are in good agreement with each other and with in situ observations, i.e., average differences are generally well below 0.01.

scholarly journals Influence of spatial heterogeneity of local surface albedo on the area-averaged surface albedo retrieved from airborne irradiance measurements

2013 ◽  
Vol 6 (3) ◽  
pp. 527-537 ◽  
Author(s):  
E. Jäkel ◽  
M. Wendisch ◽  
B. Mayer
Keyword(s):  
Optical Depth ◽  
Surface Albedo ◽  
Radiative Transfer Model ◽  
Small Scale ◽  
Mean Deviation ◽  
Transfer Model ◽  
Horizontal Distance ◽  
Local Surface ◽  
Atmospheric Scattering ◽  
The Mean

Abstract. Spectral airborne upward and downward irradiance measurements are used to derive the area-averaged surface albedo. Real surfaces are not homogeneous in their reflectivity. Therefore, this work studies the effects of the heterogeneity of surface reflectivity on the area-averaged surface albedo to quantify how well aircraft measurements can resolve the small-scale variability of the local surface albedo. For that purpose spatially heterogeneous surface albedo maps were input into a 3-dimensional (3-D) Monte Carlo radiative transfer model to simulate 3-D irradiance fields. The calculated up- and downward irradiances in altitudes between 0.1 and 5 km are used to derive the area-averaged surface albedo using an iterative retrieval method that removes the effects due to atmospheric scattering and absorption within the layer beneath the considered level. For the case of adjacent land and sea surfaces, parametrizations are presented which quantify the horizontal distance from the coastline that is required to reduce surface heterogeneity effects on the area-averaged surface albedo to a given limit. The parametrization which is a function of altitude, aerosol optical depth, single scattering albedo, and the ratio of local land and sea albedo was applied for airborne spectral measurements. In addition, the deviation between area-averaged and local surface albedo is determined for more complex surface albedo maps. For moderate aerosol conditions (optical depth less than 0.4) and a wavelength range between 400 and 1000 nm, the altitude and the heterogeneity of the surface albedo are the dominant factors determining the mean deviation between local and area-averaged surface albedo. A parametrization of the mean deviation is applied to an albedo map that was derived from a Landsat image of an area in East Anglia (UK). Parametrization and direct comparison of local and area-averaged surface albedo show similar mean deviations (20% vs. 25%) over land.

scholarly journals Carbon monoxide total column retrievals from TROPOMI shortwave infrared measurements

2016 ◽  
Vol 9 (10) ◽  
pp. 4955-4975 ◽  
Author(s):  
Jochen Landgraf ◽  
Joost aan de Brugh ◽  
Remco Scheepmaker ◽  
Tobias Borsdorff ◽  
Haili Hu ◽  
...  
Keyword(s):  
Boundary Layer ◽  
Carbon Monoxide ◽  
Transport Model ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Atmospheric Scattering ◽  
Clear Sky ◽  
Infrared Measurements ◽  
Shortwave Infrared ◽  
Total Column

Abstract. The Tropospheric Monitoring Instrument (TROPOMI) spectrometer is the single payload of the Copernicus Sentinel 5 Precursor (S5P) mission. It measures Earth radiance spectra in the shortwave infrared spectral range around 2.3 µm with a dedicated instrument module. These measurements provide carbon monoxide (CO) total column densities over land, which for clear sky conditions are highly sensitive to the tropospheric boundary layer. For cloudy atmospheres over land and ocean, the column sensitivity changes according to the light path through the atmosphere. In this study, we present the physics-based operational S5P algorithm to infer atmospheric CO columns satisfying the envisaged accuracy ( <  15 %) and precision ( <  10 %) both for clear sky and cloudy observations with low cloud height. Here, methane absorption in the 2.3 µm range is combined with methane abundances from a global chemical transport model to infer information on atmospheric scattering. For efficient processing, we deploy a linearized two-stream radiative transfer model as forward model and a profile scaling approach to adjust the CO abundance in the inversion. Based on generic measurement ensembles, including clear sky and cloudy observations, we estimated the CO retrieval precision to be  ≤  11 % for surface albedo  ≥  0.03 and solar zenith angle  ≤  70°. CO biases of  ≤  3 % are introduced by inaccuracies in the methane a priori knowledge. For strongly enhanced CO concentrations in the tropospheric boundary layer and for cloudy conditions, CO errors in the order of 8 % can be introduced by the retrieval of cloud parameters of our algorithm. Moreover, we estimated the effect of a distorted spectral instrument response due to the inhomogeneous illumination of the instrument entrance slit in the flight direction to be  <  2 % with pseudo-random characteristics when averaging over space and time. Finally, the CO data exploitation is demonstrated for a TROPOMI orbit of simulated shortwave infrared measurements. Overall, the study demonstrates that for an instrument that performs in compliance with the pre-flight specifications, the CO product will meet the required product performance well.

scholarly journals Retrieval of total column and surface NO<sub>2</sub> from Pandora zenith-sky measurements

2019 ◽  
Author(s):  
Xiaoyi Zhao ◽  
Debora Griffin ◽  
Vitali Fioletov ◽  
Chris McLinden ◽  
Jonathan Davies ◽  
...  
Keyword(s):  
Transport Model ◽  
Surface Concentration ◽  
In Situ Measurements ◽  
Radiative Transfer Model ◽  
Retrieval Algorithm ◽  
Transfer Model ◽  
Chemical Transport Model ◽  
High Quality ◽  
Vertical Column

Abstract. Pandora spectrometers can retrieve nitrogen dioxide (NO2) vertical column densities (VCDs) via two viewing geometries: direct-sun and zenith-sky. The direct-sun NO2 VCD measurements have high quality (0.1 DU accuracy in clear-sky conditions) and do not rely on any radiative transfer model to calculate air mass factors (AMFs); however, they are not available when the sun is obscured by clouds. To perform NO2 measurements in cloudy conditions, a simple but robust NO2 retrieval algorithm is developed for Pandora zenith-sky measurements. This algorithm derives empirical zenith-sky NO2 AMFs from coincident high-quality direct-sun NO2 observations. Moreover, the retrieved Pandora zenith-sky NO2 VCD data are converted to surface NO2 concentrations with a scaling algorithm that uses chemical-transport-model predictions and satellite measurements as inputs. NO2 VCDs and surface concentrations are retrieved from Pandora zenith-sky measurements made in Toronto, Canada, from 2015 to 2017. The retrieved Pandora zenith-sky NO2 data (VCD and surface concentration) show good agreement with both satellite and in situ measurements. The diurnal and seasonal variations of derived Pandora zenith-sky surface NO2 data also agree well with in situ measurements (diurnal difference within ±2 ppbv). Overall, this work shows that the new Pandora zenith-sky NO2 products have the potential to be used in various applications such as future satellite validation in moderate cloudy scenes and air quality monitoring.

scholarly journals A Refined Four-Stream Radiative Transfer Model for Row-Planted Crops

2020 ◽  
Vol 12 (8) ◽  
pp. 1290 ◽  
Author(s):  
Xu Ma ◽  
Tiejun Wang ◽  
Lei Lu
Keyword(s):  
Radiative Transfer ◽  
Computer Simulations ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Growth Stages ◽  
Canopy Reflectance ◽  
Transfer Equations ◽  
Radiative Transfer Equations ◽  
Different Growth Stages

In modeling the canopy reflectance of row-planted crops, neglecting horizontal radiative transfer may lead to an inaccurate representation of vegetation energy balance and further cause uncertainty in the simulation of canopy reflectance at larger viewing zenith angles. To reduce this systematic deviation, here we refined the four-stream radiative transfer equations by considering horizontal radiation through the lateral “walls”, considered the radiative transfer between rows, then proposed a modified four-stream (MFS) radiative transfer model using single and multiple scattering. We validated the MFS model using both computer simulations and in situ measurements, and found that the MFS model can be used to simulate crop canopy reflectance at different growth stages with an accuracy comparable to the computer simulations (RMSE < 0.002 in the red band, RMSE < 0.019 in NIR band). Moreover, the MFS model can be successfully used to simulate the reflectance of continuous (RMSE = 0.012) and row crop canopies (RMSE < 0.023), and therefore addressed the large viewing zenith angle problems in the previous row model based on four-stream radiative transfer equations. Our results demonstrate that horizontal radiation is an important factor that needs to be considered in modeling the canopy reflectance of row-planted crops. Hence, the refined four-stream radiative transfer model is applicable to the real world.

scholarly journals A fast visible-wavelength 3D radiative transfer model for numerical weather prediction visualization and forward modeling

2020 ◽  
Vol 13 (6) ◽  
pp. 3235-3261
Author(s):  
Steven Albers ◽  
Stephen M. Saleeby ◽  
Sonia Kreidenweis ◽  
Qijing Bian ◽  
Peng Xian ◽  
...  
Keyword(s):  
Solar Radiation ◽  
Radiative Transfer ◽  
Numerical Weather Prediction ◽  
Land Surface ◽  
Weather Prediction ◽  
Lower Boundary ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Numerical Weather ◽  
Visible Wavelength

Abstract. Solar radiation is the ultimate source of energy flowing through the atmosphere; it fuels all atmospheric motions. The visible-wavelength range of solar radiation represents a significant contribution to the earth's energy budget, and visible light is a vital indicator for the composition and thermodynamic processes of the atmosphere from the smallest weather scales to the largest climate scales. The accurate and fast description of light propagation in the atmosphere and its lower-boundary environment is therefore of critical importance for the simulation and prediction of weather and climate. Simulated Weather Imagery (SWIm) is a new, fast, and physically based visible-wavelength three-dimensional radiative transfer model. Given the location and intensity of the sources of light (natural or artificial) and the composition (e.g., clear or turbid air with aerosols, liquid or ice clouds, precipitating rain, snow, and ice hydrometeors) of the atmosphere, it describes the propagation of light and produces visually and physically realistic hemispheric or 360∘ spherical panoramic color images of the atmosphere and the underlying terrain from any specified vantage point either on or above the earth's surface. Applications of SWIm include the visualization of atmospheric and land surface conditions simulated or forecast by numerical weather or climate analysis and prediction systems for either scientific or lay audiences. Simulated SWIm imagery can also be generated for and compared with observed camera images to (i) assess the fidelity and (ii) improve the performance of numerical atmospheric and land surface models. Through the use of the latter in a data assimilation scheme, it can also (iii) improve the estimate of the state of atmospheric and land surface initial conditions for situational awareness and numerical weather prediction forecast initialization purposes.

scholarly journals Aerosol trends as a potential driver of regional climate in the central United States: evidence from observations

2017 ◽  
Vol 17 (22) ◽  
pp. 13559-13572 ◽  
Author(s):  
Daniel H. Cusworth ◽  
Loretta J. Mickley ◽  
Eric M. Leibensperger ◽  
Michael J. Iacono
Keyword(s):  
United States ◽  
Radiative Transfer ◽  
Southeastern United States ◽  
Radiant Energy ◽  
Surface Radiation ◽  
Radiation Budget ◽  
Radiative Transfer Model ◽  
Transfer Model ◽  
Clear Sky

Abstract. In situ surface observations show that downward surface solar radiation (SWdn) over the central and southeastern United States (US) has increased by 0.58–1.0 Wm−2 a−1 over the 2000–2014 time frame, simultaneously with reductions in US aerosol optical depth (AOD) of 3.3–5.0  ×  10−3 a−1. Establishing a link between these two trends, however, is challenging due to complex interactions between aerosols, clouds, and radiation. Here we investigate the clear-sky aerosol–radiation effects of decreasing US aerosols on SWdn and other surface variables by applying a one-dimensional radiative transfer to 2000–2014 measurements of AOD at two Surface Radiation Budget Network (SURFRAD) sites in the central and southeastern United States. Observations characterized as clear-sky may in fact include the effects of thin cirrus clouds, and we consider these effects by imposing satellite data from the Clouds and Earth's Radiant Energy System (CERES) into the radiative transfer model. The model predicts that 2000–2014 trends in aerosols may have driven clear-sky SWdn trends of +1.35 Wm−2 a−1 at Goodwin Creek, MS, and +0.93 Wm−2 a−1 at Bondville, IL. While these results are consistent in sign with observed trends, a cross-validated multivariate regression analysis shows that AOD reproduces 20–26 % of the seasonal (June–September, JJAS) variability in clear-sky direct and diffuse SWdn at Bondville, IL, but none of the JJAS variability at Goodwin Creek, MS. Using in situ soil and surface flux measurements from the Ameriflux network and Illinois Climate Network (ICN) together with assimilated meteorology from the North American Land Data Assimilation System (NLDAS), we find that sunnier summers tend to coincide with increased surface air temperature and soil moisture deficits in the central US. The 1990–2015 trends in the NLDAS SWdn over the central US are also of a similar magnitude to our modeled 2000–2014 clear-sky trends. Taken together, these results suggest that climate and regional hydrology in the central US are sensitive to the recent reductions in aerosol concentrations. Our work has implications for severely polluted regions outside the US, where improvements in air quality due to reductions in the aerosol burden could inadvertently pose an enhanced climate risk.

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