The Oil Resistance of Rubber. IV. Mechanism of the Oil Resistance of Neoprene

1937 ◽  
Vol 10 (2) ◽  
pp. 312-316
Author(s):  
Shĭ Kambara

Abstract To study the mechanism of the oil resistance of Neoprene, the following points were investigated. 1. The dielectric properties of Neoprene and its comparison with the crude and purified natural rubber. 2. The viscosity of benzene solutions of Neoprene and natural rubber of various concentrations. From data on the relation between polarization, the chain-length of solute and the concentration, the state of solutes in solution was discussed, and the oil resistance of Neoprene is explained on the basis of its high polarization and its complex structure. In conclusion, the author wishes to express his thanks to Professor Yoshio Tanaka for valuable suggestions and criticisms.

1978 ◽  
Vol 51 (1) ◽  
pp. 72-80 ◽  
Author(s):  
R. Bakule ◽  
A. Havránek

Abstract The dielectric properties of natural rubber, synthetic polyisoprene, andpolybutadiene samples crosslinked with sulfur and of natural rubber samplescrosslinked simultaneously with sulfur and dicumyl peroxide were studied. Inthe investigated systems, the number of polar groups in unit volume and thecrosslink density may be changed independently over relatively wide ranges.The measurements were performed in the frequency range from 101 to 105 Hzat various temperatures, and macroscopic parameters describing the dielectricproperties of the samples were evaluated. The position and intensity of thedielectric dispersion peak in the main transition zone is only slightly dependenton the crosslink density of the samples. These two values are mainly influencedby the amount of combined sulfur, or more generally, by the number and thedipole moments of polar groups in the sample. The influence of crosslink densityon the width of the absorption curve is very strong; the width increases withincreasing crosslink density. The possibility of explaining this effect in termsof the dependence of the free volume distribution function on crosslink densityis discussed.


2017 ◽  
Vol 23 (2) ◽  
Author(s):  
Natalya Drohomyretska

Hemomicrocirculatory system – is a complex structure that reacts in every pathological process even before the clinical period and takes the first blow. The study of microhemocirculation will provide an opportunity to solve the important for practical medicine questions of pathogenesis of many diseases, as for the prevention and treatment of regional disorders of blood circulation.The objective of the research is to study the state of the hemomicrocirculatory bed (HMCB) of adventitia of varicose veins of the small pelvis (VVSP) in women with chronic inflammatory processes of the organs of the small pelvis (CIPOSP).Materials and methods of research. To evaluate the restructuring of the HMCB of adventitia of VVSP, the operating material of 12 women of reproductive age was used. Mainly, there were pieces of the ovarian vein. The study of the HMCB in the vein wall was performed by the non-injecting method of silver impregnation according to V.V. Kupriyanov. To standardize the results, the condition of the HMCB of adventitia of the venous wall in norm was studied in 5 women of reproductive age, who died as a result of various traumas.Results of the research. After the performed studies, the structural-morphological changes of the HMCB of the adventitia of the small pelvis veins were revealed. The dilation of capillaries, postcapillaries, postcapillary venules was observed. The diameter of the vessels of the HMCB of the ovarian vein adventitia was: venule – 94.21 ± 1.38 μM in comparison with the norm – 48.78 ± 1.60 μM (p<0.001); post-capillary venules – 46.76 ± 1.04 μM in comparison with the norm – 28.29 ± 1.1.01 μM (p<0.001); the capillaries were 11.22 ± 0.14 μM in comparison with the norm – 8.24 ± 0.16 μM (p<0.05), arterioles – 29.02 ± 0.76 μM in comparison with the norm – 25.19 ± 1.15 μM (p<0.01). The architectonics of the arterioles is almost unchanged. Lumen of venules is filled with formed elements. The structure of capillaries is polymorphic. The capillary net was localized and concentrated or was formed as a thick planar net, the capillaries were expanded. There were arterio-venulous anastomoses. Endothelial nuclei are shortened. In some preparations, the diameter of the arterioles corresponded to the diameter of the collection venules.  Conclusions:1. The first discovered by us changes in HMCB of adventitia of varicose veins of the small pelvis in women with CIPOSP can be one of the pathogenetic links of the development and progression of the varicose vein itself, which in turn aggravates the course of chronic inflammation.      2. The timely appointment of drugs that improve microcirculation will enable to prevent the development of dystrophic changes in the vein wall, improve the course of chronic inflammatory processes and reduce or completely eliminate the syndrome of “chronic pelvic pain”.


Author(s):  
Taisiia Barilovska

The purpose of the article is to clarify the external functions of the President of Ukraine in the context of ensuring the security of the state. The mechanism of performing the external functions of Ukraine is characterized by the complex structure of interrelated and interacting relations. Of particular importance in this mechanism is the President of Ukraine, who, in accordance with the powers enshrined in the Constitution of Ukraine and Ukrainian legislation, heads this mechanism and coordinates the operation of its parts. The foreign policy activities of the President of Ukraine are based on the general principles of separation of powers, of the rule of law, of constitutional responsibility, and on the specific principles of the unity and of the support of foreign policy. In order to improve the operation of the mechanism of implementing foreign policy, headed by the President of Ukraine, the measures aimed at intensifying foreign policy activities and enhancing the independence of the Government of Ukraine and developing the scientific component of this mechanism are required. The process of performing external functions of the state implies the existence of an appropriate mechanism. The mechanism of performing Ukraine’s external functions includes elements that are heterogeneous in their task, legal status, organization and other characteristics, which in their turn are interrelated and interacting. The President of Ukraine has a special place in this mechanism. In accordance with the Constitution of Ukraine, he directs the foreign policy of the country and as a head of state represents Ukraine in international relations. The logic of the current stage of the development of interstate relations strongly confirms that in order to effectively strengthen the common peace and international security, a unified strategy of interacting and regulating the external functions and powers of the presidents at the international level in ensuring this security must be developed. Perhaps, one of the most important functions of the President of Ukraine at the international level is the external function of ensuring the security of the state. Until the state has the security of its own territory and borders, other functions do not matter, because security is the guarantee of the stability, and therefore, the possibility of ensuring other functions.


1949 ◽  
Vol 22 (1) ◽  
pp. 232-244
Author(s):  
D. G. Fisher ◽  
J. R. Scott ◽  
W. H. Willott

Abstract Tests have been made on unloaded ebonites prepared from ordinary commercial types of natural rubber, special (deproteinized) rubbers having reduced contents of protein and(or) other water-absorbent substances, and a whole-latex rubber containing relatively large percentages of these substances, to determine to what extent these substances influence the electrical properties of the ebonite and, hence, whether any technically useful improvement can be effected by using specially prepared rubbers. Permittivity and power factor at 106 cycles per second, but particularly power factor, are somewhat improved by using the special rubbers, so that the dielectric loss can be reduced by about 30 per cent. In addition, the increase in dielectric loss caused by exposure to high humidity or by a rise of temperature is in general lessened by the use of these rubbers. Similar, though smaller, improvements in the properties of the ebonite are obtained by washing ordinary commercial rubber (smoked sheet). Although a definite improvement in dielectric loss is obtained, it does not seem probable that purification of natural rubber would lead to ebonites with dielectric properties approaching those of polystyrene, for instance. It seems unlikely that even complete elimination of the water-absorbent impurities would reduce the dielectric loss by more than 50 per cent; the rubber-sulfur compound itself thus appears to be responsible for a fair proportion of the loss normally observed. The large percentages of water-soluble substances present in whole-latex rubber increase the permittivity and especially the power factor of the ebonite made from it. The dielectric properties of ebonite are related, though not closely, to its water-absorbing capacity and that of the raw rubber used, low absorption being in general accompanied by low dielectric loss and reduced sensitiveness to humidity variations. There is only a rough parallelism between the water absorptions of raw rubbers and the corresponding ebonites. Probable reasons for this are indicated. It is concluded that water absorption tests on raw rubber form a useful, though only approximate, guide to its value for making electrical ebonite; electrical tests on the ebonite must be the final criterion. Apart from very impure whole-latex rubber, no correlation can be traced between the inorganic content (ash) of ebonite and its electrical properties. The probable reason for this is indicated. There is evidence that the dielectric loss of ebonite may increase with the passage of time. In view of its obvious theoretical and practical importance, this phenomenon requires further study. No technically useful advantage as regards breakdown strength, volume resistivity, surface resistivity, or stability to light, by the use of the special rubbers, is evident in the present work. The plastic yield characteristics of ebonite are not appreciably altered by using special rubbers. Estimations of uncombined sulfur and also plastic yield tests show that one of the deproteinized rubbers vulcanizes more rapidly than the rest, which differ little among themselves.


Author(s):  
Gustavo Xavier Bonifaz

The present paper aims at answering why a country that shared, with other Latin American states, a centralist tradition that was even strengthened in the aftermath of its 1952 revolution, became one of the most radical and complex decentralisers in the region. The present is a country case study in which, using a process-tracing analysis, the evolution of decentralisation in Bolivia will be explained up to its current complex structure from a perspective of the relationship between political legitimation under competitive elections and the way in which the party system processed longstanding tensions between the state and different segments of society.


2020 ◽  
Vol 1010 ◽  
pp. 292-297
Author(s):  
Suziey Syamimi Sukri ◽  
Syifa' Muhamad Sharifuddin ◽  
Mohd Shukri Mat Nor ◽  
Fathin Asila Mohd Pabli ◽  
Piyawadee Luangchuang ◽  
...  

Electroceramic with high magnetic properties such as ZnFe2O4 is widely used in many electronic device applications. One of the major drawbacks of electroceramic is the difficulty in molding and processing into desired shapes due to its brittle nature. Flexible electroceramic with the superior process and mold abilities can be made by mixing magnetic ceramic with a flexible matrix, for instance, rubber. In this present study, the aims were to produce ZnFe2O4 loaded epoxidized natural rubber (ENR 25) as well as to determine its electrical and curing properties. The magnetic ceramic of ZnFe2O4 was blended with ENR 25 at different loadings varying from 0 to 120 parts per hundred of rubber (phr) in an interval of 20. The properties of produced composites include scorch time, cure time, torque and dielectric properties were characterised. The results demonstrated that the increase of ZnFe2O4 concentration in ENR 25 leads to a significant increase in the dielectric constant from 4.94 to 5.62 at 1.15 MHz, and decrease in the dielectric loss curves of the composites start from 0.0827 to 0.0586. Furthermore, the results of curing property studies exhibited an increasing pattern of the composite torques, starting from 1.43 to 1.76 dN.m.


2007 ◽  
Vol 80 (4) ◽  
pp. 672-689 ◽  
Author(s):  
Ranimol Stephen ◽  
Sabu Thomas ◽  
K. V. S. N. Raju ◽  
Siby Varghese ◽  
Kuruvilla Joseph ◽  
...  

Abstract The viscoelastic and dielectric properties of nano structured layered silicates reinforced natural rubber (NR), carboxylated styrene butadiene rubber (XSBR) and their blends have been analyzed. The viscoelastic properties such as storage modulus, loss modulus, damping behavior and glass transition temperature of nano filled latices have been investigated. Upon the addition of filler, the storage modulus of nanocomposites was found to increase due to the enhancement in stiffness of the material. Due to the restricted mobility of polymer chain segments, the damping values decreased as a function of filler loading. An investigation of the viscoelastic properties revealed that there was a strong interaction between the polymer and the filler. Latex nanocomposites was characterized by X-ray diffraction technique. The enhanced d values indicated the intercalation of polymer chain into the layers of silicates. The dielectric properties of nanocomposites have been investigated as a function of frequency in the range of 50Hz–100KHz. The effect of frequency on dielectric permittivity (Ε′), dielectric loss (Ε″), dissipation factor (tan δ) and volume resistivity (ρv) of latex nanocomposite have been measured under alternating current. The dielectric permittivity of the samples was found to be higher upon the incorporation of nano fillers. The volume resistivity decreased due to the enhanced conductivity of filled samples.


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