Swelling of Constrained Rubber Layers: Effect on Free Energy of Detachment
Abstract The degree of swelling of a rubber layer by a compatible liquid has been calculated for cases when the layer is constrained, for example when it is bonded to a rigid substrate. The stored energy residing in swollen layers is also computed. From these results the amount of energy is determined that becomes available if a bonded layer separates from a substrate and then becomes free to swell further. The released energy is shown to be quite high, of the order of 10 MJ/m3 in a representative case. Attention is drawn to the importance of the layer thickness when this energy is applied to bond rupture. For layers having a thickness of the order of 1 mm or greater, the available energy is greater than the intrinsic strength of the bond or of the swollen elastomer itself. In accord with this conclusion, soft rubber layers, sandwiched between and bonded to flexible but inextensible backings, are observed to separate spontaneously and then tear away from the backing when swollen by a compatible liquid. And layers that are still attached to the backing become sharply curved before tearing loose, in rough agreement with the theoretical predictions.