CARBON BLACK FOR RACING AND MOTORCYCLE TIRE TREADS. PERFORMANCE MODEL DEVELOPMENT

2011 ◽  
Vol 84 (4) ◽  
pp. 493-506
Author(s):  
Irene S. Yurovska ◽  
Michael D. Morris ◽  
Theo Al

Abstract Racing tires and motorcycle tires present individual segments of the tire market. For instance, while the average life of car and truck tires is 50 000 miles, the average life of race tires is 100 miles. Because tires play a critical role in a race, technical demands to assure safety and performance are growing. Similarly, tires have a large influence on safety, handling/grip, and performance of the rapidly growing world fleet of motorcycles, due to the fact of only two wheels being in contact with the ground. Thus, the common feature of both market segments is that the typical tire compromise of wear, rolling resistance, and traction is strongly weighted toward traction. Most of the recent efforts of rubber scientists have been directed toward lowering rolling resistance of the tread compounds, which left a certain void in the science of compounding for racing and motorcycle treads. Particularly, the industrial assortment of polymers and fillers used for motorcycle treads is commonly different from that used for car or truck treads, but it is not known how the filler properties affect the hysteresis–stiffness compromise. The objective of this study is to evaluate the effects of the carbon black characteristics on the important properties of a typical racing and motorcycle tire tread compound. More than 50 individual carbon blacks were mixed in a SBR formulation. The acquired data were statistically analyzed, and a linear multiple regression model was developed to relate rubber properties (responses), such as static modulus, complex dynamic modulus, hysteresis, and viscosity to the key carbon black characteristics (variables) of surface area, structure, aggregate size distribution, and surface activity. Prediction profiles created from the model demonstrate rubber performance limits for the range of carbon blacks tested, and indicate the niches to provide required combinations of the rubber properties.

2002 ◽  
Vol 75 (3) ◽  
pp. 527-548 ◽  
Author(s):  
John T. Byers

Abstract Strong demands for lower rolling resistance tires in Europe led to the introduction of a new filler system for auto tire treads in the early 1990s. Silica, in combination with a silane coupling agent, was used as the primary filler system despite the increased costs compared to carbon black. The adoption of silica/silane treads has been slower outside of Europe, but some conversion to silica/silane or alternative filler blends has taken place in North America and Japan. This paper is a review of the many reports related to the silica/silane filler system, as well as alternative approaches — including new carbon blacks — to lower rolling resistance, that have been generated since the introduction of the “green tire” concept in the early 1990s.


1974 ◽  
Vol 47 (5) ◽  
pp. 1082-1093 ◽  
Author(s):  
B. B. Boonstra ◽  
E. M. Dannenberg ◽  
F. A. Heckman

Abstract Mechanical processing of carbon blacks by a novel pressure-milling technique provides a controlled breakdown of primary carbon-black aggregates. In contrast, direct compression has a much smaller effect on aggregate size. In rubber vulcanizates, the pressure-milled carbon blacks give about the same vulcanizate properties as normal carbon blacks with the same void volume or DBP absorption value. Breakdown of aggregates occurs during the process of incorporating and dispersing carbon black in rubber. The retention of average aggregate size after mixing in rubber is in the range of 60–70 per cent for Vulcan M (N339), a new technology tread black. We have shown that the DBP absorption method cannot distinguish between loss in void volume by compaction of aggregates versus the actual breakdown of aggregates. The sedimentation method by centrifuging provides a means for measuring aggregate size independent of the original packing of the dry black. In order to carry out these studies, a number of new experimental techniques were used. These include: a) controlled aggregate size breakdown by pressure-milling. b) Stokes diameter distribution measurements by centrifuging aqueous dispersions in a Joyce Loebl apparatus. c) Quantimet analysis of projected aggregate areas from electron micrographs from specially prepared solvent dispersions of rubber-carbon black samples where the aggregates are clear of interference from adhering rubber. It has been shown for the first time that for both Vulcan M (N339) and Vulcan 6 (N220) the median Stokes diameters, DSt, obtained by the centrifuge method and the equivalent sphere diameter, De, from Quantimet projected image analysis are in the range of 123–153.


2021 ◽  
Vol 13 (1) ◽  
pp. 11-19
Author(s):  
Mingxing Gong

Machine learning models have been widely used in numerous classification problems and performance measures play a critical role in machine learning model development, selection, and evaluation. This paper covers a comprehensive overview of performance measures in machine learning classification. Besides, we proposed a framework to construct a novel evaluation metric that is based on the voting results of three performance measures, each of which has strengths and limitations. The new metric can be proved better than accuracy in terms of consistency and discriminancy.


1983 ◽  
Vol 56 (2) ◽  
pp. 390-417 ◽  
Author(s):  
W. M. Hess ◽  
W. K. Klamp

Abstract The rolling resistance of SBR/BR radial passenger tire treads was varied as a function of carbon black type and loading, as well as other compounding variables, such as oil content, high-viscosity oil and resin addition, and NR substitution. In all instances, the rolling loss variations showed a good correlation with either tan δ or resilience. The tan δ response was valid for a wide range of test temperatures, frequencies, and strain amplitudes. Wet (32 km/h) and dry (64 km/h) traction indicated a high positive correlation with loss compliance (D″). Here, the best correlations were obtained at lower dynamic testing temperatures (0–25°C.) and higher strain amplitudes. High-speed wet traction (97 km/h) appeared to be relatively independent of the tread compounding variables but did show a slight correlation with tan δ measured at ™25°C. The following patterns were observed relative to tread rolling resistance, traction, and wear as a function of compounding variables: 1. Black loading.—Reduced black loading lowers rolling resistance without much effect on traction. About 4% less black in the tread compound lowers rolling resistance by about 5–6% in the formulations which were evaluated. 2. Oil loading.—At a fixed black level, increased oil raises both rolling resistance and traction. About 2% higher rolling resistance was found for a 10 phr increase in oil loading, but the effect on wet traction appeared to be much greater (7–8%). 3. Black type.—Increasing black fineness raises both rolling resistance and traction, the latter effect being considerably less. Increased DBPA has very little effect on rolling resistance but reduces traction. At reduced black loadings, the finer and higher DBPA blacks show the least loss in treadwear resistance. Blacks with broad aggregate size distribution give lower rolling resistance at the same surface area and DBPA. For extreme blends (carcass and tread grades), however, the loss in treadwear resistance is quite severe (∼30%). 4. Curatives.—Increased sulfur and accelerator levels produced a significant reduction in tan δ, with a similar but lesser drop in D″. The same reduction in tan δ with increased accelerator (OBTS) level produced less effect on D″ than the sulfur increase. 5. Natural rubber substitution.—Compounds in which 30 phr of NR were substituted for 25 phr of SBR and 5 phr of BR indicated slightly better performance in terms of both rolling resistance and traction. 6. High-viscosity oil or resin substitution.—Replacing conventional extender oil with high-viscosity oil or resin appears to improve traction but has a greater adverse effect on rolling resistance. 7. Compound optimization.—N299 black gives the best overall balance of performance in terms of rolling resistance, traction, and treadwear at reduced black loadings. N121 confers about 10% better treadwear and equal traction in the same compound, but at about 4% higher rolling resistance.


2021 ◽  
Vol 30 ◽  
pp. 263498332110054
Author(s):  
Rungsima Chollakup ◽  
Supitta Suethao ◽  
Potjanart Suwanruji ◽  
Jirachaya Boonyarit ◽  
Wirasak Smitthipong

The effects of carbon black on the properties of rubber composites were studied in order to explore their value in producing low rolling resistance truck tires. Carbon black with different grades, N330 (coarser grade of 26–30 nm) and N220 (finer grade of 20–25 nm), was used as a reinforcing agent of natural rubber. The effects of different ratios of carbon black N330 at 40, 45, 50 and 55 parts per hundred rubber (phr) and N220 at 30, 35, 40 and 50 phr were investigated. Rubber composites with N220 had greater rubber/carbon black interaction than those with N330. The Mooney viscosity of rubber composite increased when the carbon black ratio increased. After vulcanisation of rubber, the samples were characterised by dynamic mechanical analysis, tensile strength and heat build-up. The results showed that the strength of rubber composites increased with increasing carbon black ratios. Interestingly, at the same bound rubber level, rubber composites with N220 presented lower dissipation energy, heat build-up and better mechanical properties than those with N330. This study indicated that reinforcement with an optimum amount of carbon black N220 would improve several desirable characteristics of rubber composites when used in low rolling resistance truck tires.


1952 ◽  
Vol 25 (4) ◽  
pp. 843-857 ◽  
Author(s):  
E. M. Dannenberg

Abstract Different mixing conditions were employed to obtain vulcanizates, varying only in degree of carbon black dispersion, with natural and synthetic rubbers, using a single sample of a commercial grade HAF black. Light transmittance measurements on dilute solutions of dissolved unvulcanized stocks prepared by an improved technique were used to evaluate the size of carbon black aggregates in cold GR-S and natural rubber stocks. Electron micrographs of films show the high degree of carbon black aggregation, even after prolonged mixing. A limiting degree of dispersion or a minimum aggregate size is obtained very rapidly as mixing is increased. Black incorporation and dispersion appear to take place simultaneously; a high degree of abrasion reinforcement was noted in most rubbers with mixing (less than 75 seconds) barely sufficient to incorporate the black. Carbon blacks in general respond rapidly to mixing, and the chainlike aggregates characteristic of reinforcing carbon blacks observed under the electron microscope are practically unchanged after mixing with rubber. Dispersion of carbon blacks during mixing depends on the packing and coherence of their agglomerates resulting from such factors as surface oxidation and extent of mechanical bulk densification. There is some evidence that oil-type furnace blacks disperse more easily than channel blacks. A major cause of the disappointing abrasion reinforcement with most noncarbon pigments possessing extreme fineness may be the tendency for excessively strong aggregate binding and resulting large aggregates in rubber. A striking rise in electrical resistivity was observed as the amount of mixing was increased. As the size of the aggregates did not change, the higher electrical resistivity cannot be explained by assuming better dispersion and breakdown of conductive carbon paths. Increased mixing might provide better distribution of the carbon aggregates in in the rubber matrix without change in size of aggregates.


2012 ◽  
Vol 9 (3) ◽  
pp. 1102-1112 ◽  
Author(s):  
Ramin Zafarmehrabian ◽  
Saeed Taghvaei Gangali ◽  
Mir Hamid Reza Ghoreishy ◽  
Mehran Davallu

NR is the major constituent in the rubber compound used for the tread on the truck tires. A general compound formulation of the tire tread includes NR and BR as polymer base and carbon black as the reinforcing filler, and curative components. In this paper the effects of dual filler system (carbon black and precipitated silica) on the dynamic properties of tire treat has been studied. The results show by increasing of precipitated silica, significant improvement was observed in fatigue resistance, rolling resistance and heat buildup of the tire. Tensile strength and modulus and wet grip of tire tread decrease with increasing of silica in rubber compound formulation.


Author(s):  
J. S. Bell ◽  
P. K. Chan ◽  
A. Prudil

Thorium-based fuel cycles can improve fuel sustainability within the nuclear power industry. The Canadian supercritical water-cooled reactor (SCWR) concept uses this path to achieve the sustainability requirement of the Gen-IV Forum. The study of thorium dioxide/thoria ThO2-based fuel irradiation behavior is significantly less advanced than that of uranium dioxide (UO2) fuel, although ThO2 possesses superior thermal conductivity, thermal expansion, higher melting temperature, and oxidation resistance that may improve both fuel performance and safety. The fuel and sheath modeling tool (FAST), a fuel performance model for UO2 fuel, was developed at the Royal Military College of Canada (RMCC). FAST capability has been extended to include thoria (ThO2), thorium uranium dioxide (Th,U)O2, and thorium plutonium dioxide (Th,Pu)O2 as fuel pellet materials, to aid in designing and performance assessment of Th-based fuels, including SCWR (Th,Pu)O2 fuel. The development and integration of ThO2 and (Th,U)O2 models into the existing FAST model led to the multipellet material FAST (MPM-FAST). Model development was performed in collaboration between RMCC and Canadian Nuclear Laboratories (CNL). This paper presents an outline of the ThO2 and (Th,U)O2 MPM-FAST model, a comparison between modeling results with postirradiation examination (PIE) data from a test conducted at CNL, and an account of the knowledge gap between our ability to model ThO2 and (Th,U)O2 fuel compared to UO2. Results are encouraging when compared to PIE data.


2013 ◽  
Vol 90 (3) ◽  
pp. 517-521 ◽  
Author(s):  
Lobat Tayebi ◽  
Masoud Mozafari ◽  
Rita El-khouri ◽  
Parvaneh Rouhani ◽  
Daryoosh Vashaee

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