scholarly journals Ore Formation During Jurassic Subduction of the Tethys Along the Eurasian Margin: Constraints from the Kapan District, Lesser Caucasus, Southern Armenia

2019 ◽  
Vol 114 (7) ◽  
pp. 1251-1284 ◽  
Author(s):  
Johannes Mederer ◽  
Robert Moritz ◽  
Massimo Chiaradia ◽  
Richard Spikings ◽  
Jorge E. Spangenberg ◽  
...  

Abstract The Kapan mining district in the southernmost Lesser Caucasus is one of the few locations along the central Tethyan metallogenic belt where ore-forming processes were associated with magmatic arc growth during Jurassic Tethys subduction along the Eurasian margin. Three ore deposits of the Kapan district were investigated in this study: Centralni West, Centralni East, and Shahumyan. The ore deposits are hosted by Middle Jurassic andesitic to dacitic volcanic and volcaniclastic rocks of tholeiitic to transitional affinities below a late Oxfordian unconformity, which is covered by calc-alkaline to transitional Late Jurassic-Early Cretaceous volcanic rocks interlayered with sedimentary rocks. The mineralization consists of veins, subsidiary stockwork, and partial matrix replacement of breccia host rocks, with chalcopyrite, pyrite, tennantite-tetrahedrite, sphalerite, and galena as the main ore minerals. Centralni West is a dominantly Cu deposit, and its host rocks are altered to chlorite, carbonate, epidote, and sericite. At Centralni East, Au is associated with Cu, and the Shahumyan deposit is enriched in Pb and Zn as well as precious metals. Both deposits contain high-sulfidation mineral assemblages with enargite and luzonite. Dickite, sericite, and diaspore prevail in altered host rocks in the Centralni East deposit. At the Shahumyan deposit, phyllic to argillic alteration with sericite, quartz, pyrite, and dickite is dominant with polymetallic veins, and advanced argillic alteration with quartz-alunite ± kaolinite and dickite is locally developed. The lead isotope composition of sulfides and alunite (206Pb/204Pb = 18.17–18.32, 207Pb/204Pb = 15.57–15.61, 208Pb/204Pb = 38.17–38.41) indicates a common metal source for the three deposits and suggests that metals were derived from magmatic fluids that were exsolved upon crystallization of Middle Jurassic intrusive rocks or leached from Middle Jurassic country rocks. The δ18O values of hydrothermal quartz (8.3–16.4‰) and the δ34S values of sulfides (2.0–6.5‰) reveal a dominantly magmatic source at all three deposits. Combined oxygen, carbon, and strontium isotope compositions of hydrothermal calcite (δ18O = 7.7–15.4‰, δ13C = −3.4−+0.7‰, 87Sr/86Sr = 0.70537–0.70586) support mixing of magmatic-derived fluids with seawater during the last stages of ore formation at Shahumyan and Centralni West. 40Ar/39Ar dating of hydrothermal muscovite at Centralni West and of magmatic-hydrothermal alunite at Shahumyan yield, respectively, a robust plateau age of 161.78 ± 0.79 Ma and a disturbed plateau age of 156.14 ± 0.79 Ma. Re-Os dating of pyrite from the Centralni East deposit yields an isochron age of 144.7 ± 4.2 Ma and a weighted average age of the model dates of 146.2 ± 3.4 Ma, which are younger than the age of the immediate host rocks. Two different models are offered, depending on the reliability attributed to the disturbed 40Ar/39Ar alunite age and the young Re-Os age. The preferred interpretation is that the Centralni West Cu deposit is a volcanogenic massive sulfide deposit and the Shahumyan and Centralni East deposits are parts of porphyryepithermal systems, with the three deposits being broadly coeval or formed within a short time interval in a nascent magmatic arc setting, before the late Oxfordian. Alternatively, but less likely, the three deposits could represent different mineralization styles successively emplaced during evolution and growth of a magmatic arc during a longer time frame between the Middle and Late Jurassic.

Author(s):  
Wolfgang D. Maier ◽  
Marina Yudovskaya ◽  
Pedro Jugo

AbstractMore than 30 years ago, Cox and Singer (1986) suggested that magmatic platinum-group element (PGE)-Ni-Cu deposits are amongst the best understood of ore deposits, yet the origin of PGE mineralization in the Bushveld Igneous Complex (BIC) remains controversial after a century of study. In the northern limb of the BIC, the unravelling of ore formation proved particularly difficult due to relatively poor outcrop, which is typically affected by contamination of the intruding magmas with the host rocks and expressed in the form of abundant xenoliths, footwall rafts and disturbance of magmatic stratigraphy. In this thematic issue, we present contributions on the Flatreef, a recently discovered world-class PGE-Ni-Cu deposit constituting a downdip extension of the mineralized unit of the Platreef of the northern limb. Two deep shafts are currently being sunk, making the Flatreef one of the most significant new mine development on the Bushveld in several decades.


1974 ◽  
Vol 11 (2) ◽  
pp. 211-223 ◽  
Author(s):  
F. W. Beales ◽  
J. C. Carracedo ◽  
D. W. Strangway

Paleomagnetism can provide useful information about the stratigraphic relationships between the host rocks and the ore of some ore deposits.Four North American mines with stratabound ore deposits of Mississippi Valley type were sampled and the direction and intensity of the natural remanent magnetization (NRM) were measured. Two of the sites sampled (Newfoundland Zinc Co. property near Daniel's Harbour in western Newfoundland and the St. Joe Minerals Co., #8 Mine in southeast Missouri) had a weak, but measurable NRM in both host and ore rocks. This magnetization proved to be highly stable upon alternating field (AF) demagnetization. The other two mines (Magmont Mine, southeast Missouri, and Pine Point Mine, Northwest Territories, Canada) had intensities of magnetization too low to be measured after demagnetization.The pole positions computed for the ores and their corresponding hosts are identical within the statistical uncertainty, strongly suggesting that the ore and the host are, geologically speaking, of roughly the same age. This study gives two reliable pole positions, one for late lower Ordovician dolostone and sphalerite ore from Newfoundland of 26 °N, 126 °E, and the other for the upper Cambrian, based on the Bonneterre dolostone and galena ore from southeast Missouri of 35 °S, 170 °W.Within the present limitations of the method the results agree with published opinions concerning the age of the ore, i.e. that host rock and ore formation were relatively close in time. Therefore, when significant time differences occur between epigenetic ores and their host rocks, the method may be expected to define this. The method will become progressively more valuable as the apparent polar wandering curves for various continental areas become better defined.


Author(s):  
Dina Klimentyeva ◽  
Thomas Driesner ◽  
Albrecht von Quadt ◽  
Trajča Tončić ◽  
Christoph Heinrich

AbstractThe Cu-Au deposit of Bor (Serbia) represents a continuum of mineralization styles, from porphyry-style ore occurring in quartz-magnetite-chalcopyrite veins and chalcopyrite disseminations to high-sulfidation epithermal Cu-Au ores in pyrite-chalcopyrite and anhydrite-sulfide veins. Decisive for the great economic importance of Bor is the presence of exceptionally rich high-sulfidation massive sulfide orebodies, composed of pyrite + covellite + chalcocite/digenite and minor anhydrite and enargite. They form irregular bodies measuring 0.5–10 million tons of ore grading up to 7% Cu, hosted by andesites and surrounded by intense argillic alteration. This study focuses on a small but rich underground orebody mined out recently, where limited drillcore is preserved for quantitative geochemical study. This paper documents the vein relationships within the deep porphyry-style orebody of Borska Reka, the transitional porphyry-epithermal veins, and the overlying and laterally surrounding epithermal massive sulfides of the Bor deposit. Geological observations indicate that the formation of massive sulfide orebodies concludes the ore formation. Mass balance calculations, recast into geologically realistic bulk fluid-rock reactions, confirm textural evidence that near-isovolumetric replacement of andesite host rocks is the dominant formation mechanism of massive sulfide orebodies at Bor, whereby all lithophile elements including Si are dissolved and only Ti stays relatively immobile. While net volume changes for individual mineralization styles within the massive sulfide orebody vary from − 16% volume loss to + 127% volume gain, overall volume change for the whole massive sulfide orebody was probably slightly negative. Brecciation is important only as means of creating channelways for reactive fluid that turns the andesite protolith into massive sulfide, whereas net breccia infill occurred only locally.


2021 ◽  
Author(s):  
Valentina Taranovic ◽  
Stephen J. Barnes ◽  
Steve Beresford ◽  
Morgan Williams ◽  
Colin MacRae ◽  
...  

Abstract The Nova-Bollinger Ni-Cu sulfide ore deposit is the first economic Ni-Cu-Co sulfide deposit to have been discovered in the Albany-Fraser orogen in Western Australia. The host rocks are mafic-ultramafic intrusive cumulates subdivided into two connected intrusions, designated Upper and Lower. The Upper Intrusion is bowl-shaped and modally layered with alternating peridotite and norite mesocumulate layers, with a Basal Series of dominantly orthocumulate mafic lithologies. The Lower Intrusion is a much thinner, semiconformable chonolith (flattened tube-shaped intrusion) consisting of mostly unlayered mafic to ultramafic orthocumulates. The Lower Intrusion hosts all the high-grade mineralization and most of the disseminated ores. A distinctive plagioclase-bearing lherzolite containing both orthopyroxene and olivine as cumulus phases is a characteristic of the Lower Intrusion and the Basal Series of the Upper. The intrusions differ slightly in olivine and spinel chemistry, the differences being largely attributable to the more orthocumulate character of the Lower Intrusion. Sector zoning in Cr content of pyroxenes is observed in the Lower Intrusion and in the lower marginal zone of the Upper and is attributed to crystallization under supercooled conditions. Symplectite pyroxene-spinel-amphibole coronas at olivine-plagioclase contacts are ubiquitous and are attributed to near-solidus peritectic reaction between olivine, plagioclase, and liquid during and after high-pressure emplacement, consistent with high Al contents in igneous pyroxenes and estimates of the peak regional metamorphism. Original cumulus olivines had compositions around Fo86 and were variably Ni depleted, interpreted as the result of preintrusion equilibration with sulfide liquid. The Upper and Lower Intrusion rocks represent cumulates from a similar parental magma, a high-Al tholeiite with MgO between 10 and 12%, low TiO2 (0.5–0.6%), and high Al2O3 (14–17%). Modeling using alphaMELTS indicates a primary water content of around 2 wt %. The cumulates of both intrusions were derived via multiple magma pulses of liquid-olivine-sulfide slurries with variable amounts of orthopyroxene, emplaced into the deep crust at pressures of around 0.7 GPa during the peak of regional metamorphism. The intrusions developed initially as a bifurcating sill, the lower arm developing into the ore-bearing Lower Intrusion chonolith and the upper arm inflating into the cyclically layered Upper Intrusion.


2015 ◽  
Vol 19 (2) ◽  
pp. 141-145 ◽  
Author(s):  
Mansoureh Mahdavi ◽  
Rahim Dabiri ◽  
Elham Shah Hosseini

<p>The manganese (Mn) deposits of Iran date from late Proterozoic to Pliocene but the major high-grade Mn ore deposits are associated with tertiary basic to intermediate volcanic rocks. The Venarch Mn deposit is located in the SW Qom city and considered as one of the largest in Iran. The Mn mineralization is mostly hosted by Eocene high-k volcanic and pyroclastic rocks of Urmia-Dokhtar Magmatic Arc (UDMA). The study area mainly consists of basalt, trachybasalt, andesite, and basaltic-andesite that are intruded by Eocene-Oligocene monzodiorite, monzonite, and granodiorite intrusions. The Venarch Mn ore bodies are mostly hosted by shale beds and wrapped by altered mega-porphyritic andesites and spilitic lavas both in the foot and hanging walls. Petrographic studies show that the principal ore minerals are pyrolusite, psilomelane, and other Mn-oxides,and quartz and calcite were determined as the gang minerals. Integration of field geology, petrography, and geochemical results suggest a hydrothermal origin for the Venarch Mn deposit. Our geochemical data furthermore suggest the volcanic host rocks to be comparable to high-K series of subduction zones.</p><p> </p><p><strong>Evolución Magmática y Características de Composición en Rocas Volcánicas Terciarias Asociadas con la Mineralización de Manganeso en la Mina de Venarch, al Suroeste de Qom, en la Región Central de Irán</strong></p><p> </p><p><strong>Resumen</strong></p>Los yacimientos de manganeso (Mn) en Irán datan del Proterozoico tardío hasta el Plioceno, pero el mayor grado de los depósitos de la mena de manganeso se asocian a rocas volcánicas básicas a intermedias de edad Terciaria. El yacimiento de manganeso en la mina de Venarch se localiza al suroeste de la ciudad de Qom y está considerado como uno de los más grandes de Irán. La mineralización de manganeso se presenta en su mayoría en las rocas piroclásticas y volcánicas de alto contenido de K del Eoceno en el Arco Magmático Urmia-Dokhtar (UDMA, en inglés). El área de estudio presenta basaltos, traquibasaltos, andesitas y andesitas basálticas que están intruidas por monzodioritas, monzonitas y granodioritas del Eoceno-Oligoceno. Los cuerpos de mineral de manganeso en Venarch en su mayoría están dentro de capas de pizarra y envueltos por lavas espiliticas y andesitas megaporfiroides tanto en las paredes del piso como en las colgantes. Los estudios petrográficos muestran que los minerales son pirolusitas, silomelanas y otros óxidos de manganeso, mientras que los cuarzos y las calcitas constituyen los minerales de ganga. La integración de los trabajos de geología de campo, petrográficos y geoquímicos sugieren un origen hidrotérmal del yacimiento de manganeso de Venarch. Los datos geoquímicos de este estudio también sugieren que la roca volcánica anfitriona es comparable con las series ricas en K de las zonas de subducción.</p>


1989 ◽  
Vol 26 (10) ◽  
pp. 2032-2043 ◽  
Author(s):  
Christian V. Pitre ◽  
Jean M. Richardson

The Duck Pond tin prospect is a vein- and strata-bound cassiterite prospect that is located 2 km west of the East Kemptville open-pit tin mine in southwestern Nova Scotia. The host rocks of the Duck Pond prospect are interbedded metawacke and meta-argillite that belong to the transition unit of the Meguma Group. These rocks contain quartz, sericite, chlorite, hematite, rutile, manganese oxides, feldspar, and porphyroblastic garnet, but not detrital cassiterite. The prospect is structurally controlled and contains several cross-cutting vein sets that have alkalic, chloritic, or argillic alteration assemblages. Muscovite is the main indicator mineral for alkalic alteration and occurs in veins that contain anorthoclase or quartz. Cassiterite is associated with chloritic alteration and occurs as subhedral to euhedral grains, acicular needles, and colloform layers in veins in meta-argillite and as strata-bound disseminations in metawacke. Most cassiterite precipitated under externally buffered conditions with respect to oxygen. Fe, Cu, Zn, and As sulphide minerals and quartz were deposited during argillic alteration. Late-stage processes such as recrystallization, sulphidation, and oxidation also occurred. Chalcopyrite is replaced by bornite and covellite; pyrite is replaced by marcasite.Unlike the F-rich East Kemptville deposit, fluorine-rich and tin-sulphide minerals are not present in the Duck Pond prospect. Trace tourmaline, absent at East Kemptville, is found at Duck Pond. However, the source of tin-mineralizing fluids at Duck Pond and East Kemptville was likely the granitic magma of the Davis Lake complex, which also hosts the East Kemptville deposit. From the mineral assemblages and textural relationships, it appears that as the temperature dropped from 425–405 °C to less than 200 °C at Duck Pond, the pH dropped from 5.2 to no lower than 3. Log [Formula: see text] dropped from at least −19 to −43. Log [Formula: see text] rose from < −15 to > −10. Cassiterite precipitated at the higher ends of the temperature and pH ranges and the lower end of the log [Formula: see text] range.


2012 ◽  
Vol 183 (4) ◽  
pp. 307-318 ◽  
Author(s):  
Ugur Kagan Tekin ◽  
M. Cemal Göncüoglu ◽  
Seda Uzuncimen

Abstract The Bornova Flysch Zone (BFZ) in NW Anatolia comprises several olistoliths or tectonic slivers, representing various parts of the Izmir-Ankara ocean. Radiolarian assemblages extracted from one of the olistoliths of the BFZ, cropping out along the Sögütlü section, to the NE Manisa city, were studied in detail. The lowermost part of the section contains latest Bajocian – early Callovian radiolarian taxa, followed by radiolarian assemblages indicating Late Jurassic to early Late Cretaceous (Cenomanian) ages. Previous studies reveal that the Izmir-Ankara oceanic basin was initially opened during late Ladinian – early Carnian. The new radiolarian data obtained from this olistolith reveals that relatively condensed, and possibly more or less continuous, pelagic sedimentation took place during the late Middle Jurassic to early Late Cretaceous in a non-volcanic oceanic basin closer to the Tauride-Anatolide platform margin.


2020 ◽  
Vol 3 ◽  
pp. 61-65
Author(s):  
Anvar Aliyev ◽  

The northeastern part of the Lesser Caucasus encompasses the western part of the Republic of Azerbaijan and is characterized with a prevalence of unique flora and fauna and the availability of rich natural resources, particularly metals. It is known that the long-term exploitation of these resources by surface mining has led to technogenic contamination in the area. Exploitation of ore deposits is associated with the origination of huge hills of waste which cause heavy degradation of pastures, forests, and croplands. A significant part of widely degraded areas in the northeastern Lesser Caucasus is found in the territory of the Gedabek administrative district. This paper deals with the problem of restoration for contaminated lands formed due to raw material extraction on territory of valuable mountain forests and meadows over a long historical period as well as the use of collected technogenic wastes for different purposes (e.g. in land reclamation, construction of motorways etc.).


2019 ◽  
Vol 61 (1) ◽  
pp. 18-38
Author(s):  
L. B. Damdinova ◽  
B. B. Damdinov ◽  
M. O. Rampilov ◽  
S. V. Kanakin

This study examines the compositions of the ore and the ore formation solutions, conditions of formation, and sources of Be mineralization using the Aunikskoye F-Be deposit, which is an integral part of the Western Transbaikal beryllium-bearing provinces, as a representative example. Further, the main factors responsible for the formation of beryllium mineralization were evaluated. The ore deposits are presented by the feldsparic–fluorspar–phenacite–bertrandite metasomatites formed in the carboniferous limestones during their metasomatic alternation with hydrothermal solutions by introducing F, Be, and other associated elements. The formation of early phenacite–fluorspar association occurred in high-fluorite СО2-containing solutions of elevated alkalinity with a salinity of ~10.5%–12% wt eq. NaCl in a temperature range of ~ 370–260 °С at pressures ranging from 1873 to 1248 bar. More recent fluorite and bertrandite deposits were formed by solutions with a salinity of 6.4%–7.7% wt eq. NaCl in a temperature range of ~156 °C–110 °C and a pressure range of 639–427 bar. The examination of the isotopic signature of the ore association minerals confirmed the apocarbonate nature of the main ore deposit and allowed the determination of the magmatogene nature of the ore-forming paleothermal springs, which are the source of subalkaline leucogranites. The primary factors that influenced the formation of the F-Be ore included the reduction of the F activity in solutions because of the binding of Ca and F in fluorite as well as because of the decrease in temperature during the ore deposition process. The elevated alkalinity of the ore-formation solutions resulted in the low solubility of the Be complexes, which caused a relatively low Be content in the ore and a relatively small amount of mineralization in the deposit.


2019 ◽  
Author(s):  
Walter G. Joyce ◽  
Jérémy Anquetin

The fossil record of non-baenid paracryptodires ranges from the Late Jurassic (Kimmeridgian) tothe Paleocene of North America and Europe only. Earlier remains may be present as early as the Middle Jurassic (Bathonian). Only a single dispersal event is documented between the two continents following their breakup during the Cretaceous in the form of the appearance of the Compsemys lineage in the Paleocene of France. Non-baenid paracryptodires were restricted to freshwater aquatic environments, but display adaptations to diverse feeding strategies consistent with generalist, gape-and-suction, and hypercarnivorous feeding. Current phylogenies recognize two species rich subclades within Paracryptodira, Baenidae and Pleurosternidae, which jointly form the clade Baenoidea. A taxonomic review of non-baenid paracryptodires concludes that of 34 named taxa, 11 are nomina valida, 15 nomina invalida, and 8 nomina dubia.


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