scholarly journals The Effects of Fire on Organic Functional Groups of Peat in Relation to Water Content

2015 ◽  
Vol 19 (3) ◽  
pp. 143
Author(s):  
Said Ramadhan ◽  
Fadly Hairannoor Yusran ◽  
Abdul Haris ◽  
Suhaili Asmawi
Keyword(s):  
Moisture Content ◽  
Water Content ◽  
Functional Groups ◽  
Functional Group ◽  
Water Levels ◽  
Time Interval ◽  
Total Acidity ◽  
Organic Functional Group ◽  
Organic Functional Groups ◽  
The Relationship

The aim of this research was to study the decline of organic functional group through the process of burning in peat. In addition, this study was also to examine the relationship between water content in peat and organic functional group after combustion (burning).  Peat drying was conducted in an oven at a temperature of 75°C with the interval of 0, 1, 2, 3, 4, 5 and 6 hours.  Each time interval had three replicates within two sets of experiments so that the total number of samples were 42 (experimental units).  Variables measured were moisture content, total acidity, COOH groups, and OH-phenolate.  The relationship between the water content with total acidity, COOH groups and OH-phenolate were determined by the equation y = bx + a.  The results showed that the relationship between the water content with organic functional group was linear.  While the relationship between peat water content with organic functional group after burning was irregular, although water levels through the process of burning have been greatly reduced. Keywords: Burning peat; organic functional groups; water content [How to Cite: Said R, FH Yusran, A Haris and S Asmawi. 2014. The Effects of Fire on Organic Functional Groups of Peat in Relation to Water Content. J Trop Soils 19: 143-149. Doi: 10.5400/jts.2014.19.3.143]    

scholarly journals Water Management “Tabat System” in Carbon Dioxide Mitigation and Vulnerability to Fire On Peatland

2017 ◽  
Vol 21 (1) ◽  
pp. 41 ◽  
Author(s):  
Siti Nurzakiah ◽  
. Nurita ◽  
Dedi Nursyamsi
Keyword(s):  
Water Management ◽  
Carbon Dioxide ◽  
Land Use ◽  
Water Content ◽  
Functional Groups ◽  
Water Levels ◽  
Survey Method ◽  
Drainage Channel ◽  
Water Gate ◽  
Carbon Dioxide Mitigation

The conservation measures of peat or peat maintain under natural conditions many proposed to address the increase in carbon emissions from land use change and efforts to minimize of fire, but it can not entirely implemented due to peat land has the potential for development of the agricultural commodities is supported by extensive area. Peatlands can be productive agricultural land with appropriate methods. Water management is required to regulate groundwater levels which is suitable for plants, nature conservation and restore hydrological conditions, such as reducing the vulnerability to fire. The percentage of water content vertically and functional groups of organic materials that have both hydrophilic and hydro phobic properties can be an indicator of vulner ability to fire. This research was conducted by survey method and then field sampling on land use rubber. Water management carried out with the installation of water-gate in the drainage channels (Tabat System). There are two experimental units in peatland, namely: 1) the drainage channel is equipped with the water-gate/Tabat (KST), Tabat size adjusted to the channel dimensions, and 2) there are no water-gate on the drainage channel (KNT). The parameters are observed of CO2 fluxes, ground water levels, water content and functional groups of organic matter. The purpose of this study was to determine the role of “tabat system” in mitigating CO2 emission sand vulner ability tofire. The results showed that the water management “tabat system” can reduce CO2 emissions by 47.6%, reducing hydrophobic properties of peat (0-50 cm soil depth) of 6.6% and is able to prevent loss of water-holding ability of fibric peat by 26.6%. This indicates that water management measures is required as one effort to maintain of peat to remain moist condition, so that changes in peat properties of hydrophilic become hydrophobic can be prevented, and reduce peat vulnerability to fire.Keywords: Carbon dioxide emissions, Peatland, Vulner ability to fire, Water management [How to Cite: Siti Nurzakiah, Nurita and Dedi Nursyamsi. 2016. Water Management “Tabat System” in Carbon Dioxide Mitigation and Vulnerability to Fire On Peatland. J Trop Soils 21: 41-47. Doi: 10.5400/jts.2016.21.1.41] 

scholarly journals ANGKA KAPANG DAN KHAMIR PADA LADA PUTIH ASAL BANGKA

2019 ◽  
Vol 5 (2) ◽  
pp. 101
Author(s):  
Oktavio Rosani ◽  
Devy Susanty ◽  
Ary Triyanto
Keyword(s):  
Moisture Content ◽  
Water Content ◽  
High Water ◽  
Quality Standard ◽  
High Water Content ◽  
White Pepper ◽  
Public Consumption ◽  
Mold And Yeast ◽  
The Relationship

Numbers of Mold and Yeast on White Pepper from BangkaWhite pepper is one of Indonesia's spices that are needed for both public consumption and exports. Post-harvest processing of white pepper by farmers is often done with unclean. Each source of white pepper has different water content and will affect the quality of white pepper. In this study, seven samples (S1, S2, S3, S4, S5, S6, S7) were from Bangka. All samples tested had higher water content than SNI quality standard (13%), but still below the quality standard 2 (18%). Sample S2 has the highest water content compared to other samples. Sample S1 and S2 have high Numbers of Mold and Yeast (AKK) and do not suitable with quality standart of BPOM. Of all samples, S2  had the highest AKK (5,51 x 104 colony / g) and sample S5 had the smallest AKK (8,8 x 102 colony / g). This shows the relationship between water content in white pepper with AKK. White pepper that has a high water content has a high AKK, whereas white pepper that has low moisture content has low AKK.Keywords: white pepper, Numbers of Mold and Yeast, moisture contentABSTRAKLada putih adalah salah satu rempah Indonesia  yang  banyak dibutuhkan baik untuk konsumsi masyarakat ataupun ekspor. Proses pengolahan pasca panen lada putih oleh petani sering dilakukan dengan tidak bersih. Setiap sumber lada putih memiliki kadar air yang berbeda dan akan mempengaruhi kualitas lada putih. Pada penelitian ini,tujuh sampel (S1, S2, S3, S4, S5, S6, S7)  berasal dari Bangka. Semua sampel yang di uji memiliki kadar air yang lebih tinggi dari standar mutu 1 SNI (13%), namun masih berada di bawah standar mutu 2 (18 %). Sampel S2 memiliki kadar air yang paling tinggi dibandingkan dengan sampel lainnya. Sampel S1 dan S2 memiliki  (Angka Kapang Khamir) AKK yang tinggi dan tidak memenuhi syarat mutu. BPOM. Dari semua sampel, sampel S2 memiliki AKK paling tinggi (5,51 x 104 koloni/g) dan sampel S5 memiliki AKK paling kecil (8,8 x 102 koloni/g). Hal ini menunjukan hubungan antara kadar air pada lada putih dengan AKK. Lada putih yang memiliki kadar air tinggi memiliki AKK yang juga tinggi, sedangkan lada putih yang memiliki kadar air rendah memiki AKK yang  rendah.Kata Kunci: Lada putih, Angka kapang khamir, Kadar Air

Analysis of the Influence of Water Content on Shanxi Loess CBR and Rebound Module

2014 ◽  
Vol 919-921 ◽  
pp. 820-823
Author(s):  
Xi Rong Wu ◽  
Li Li Zhu
Keyword(s):  
Moisture Content ◽  
Water Content ◽  
Resilient Modulus ◽  
Test Methods ◽  
Shanxi Province ◽  
Influence Of Water ◽  
The Times ◽  
Relationship Of ◽  
The Impact ◽  
The Relationship

Selection of five typical loess in Shanxi Province, the paper adopt the indoor test methods to prepares the different compaction and different moisture content specimens which were used to test CBR value and rebound module, analyzes the impact of compactness and moisture content on the CBR value and resilient modulus and establishes the relationship of CBR and moisture content. The result shows that the level of moisture content has great impact on CBR value and rebound module. The CBR value is maximal under optimum moisture content and maximum degree of compaction condition. The times of compaction have little effect on the improvement of CBR with increasing water content. The relationship of the soaking CBR,resilient modulus and the moisture content shows a certain regularity.Key words: Loess filler;the CBR;resilient modulus;compactness;moisture content;relationship

The Design of Moisture Content of Lubricating Oil Detecting System Based on AD5933

2013 ◽  
Vol 401-403 ◽  
pp. 1129-1134
Author(s):  
Qiang Liao ◽  
Wei Dong Fan ◽  
Jiang Wu ◽  
Tao Xu
Keyword(s):  
Mathematical Model ◽  
Moisture Content ◽  
Water Content ◽  
Capacitive Sensor ◽  
Lubricating Oil ◽  
Voltage Amplitude ◽  
Excitation Voltage ◽  
The Mathematical Model ◽  
The Relationship ◽  
Resistance Value

In order to detect lubricating oil moisture content quickly, and replace lubricating oil of equipment in time , impedance type moisture content of lubricating oil detecting system based on AD5933 and cylindrical coaxial capacitive sensor are explored. The paper selected the excitation voltage amplitude and frequency reasonably, and studied the relationship between water content of lubricating oil and impedance value. The result suggests that when the excitation voltage amplitude is 2V, the frequency ranges from 4 kHz to 6 kHz, moisture content of lubricating oil is closely related to impedance value and lubricating oil resistance value decreases with the increase of its moisture content. In addition, the mathematical model between moisture content of lubricating oil and the impedance value is established, moisture content of lubricating oil can be calculated according to the impedance value.

scholarly journals Improved AIOMFAC model parameterisation of the temperature dependence of activity coefficients for aqueous organic mixtures

2015 ◽  
Vol 15 (1) ◽  
pp. 447-493 ◽  
Author(s):  
G. Ganbavale ◽  
A. Zuend ◽  
C. Marcolli ◽  
T. Peter
Keyword(s):  
Experimental Data ◽  
Temperature Dependence ◽  
Functional Groups ◽  
Organic Compounds ◽  
Activity Coefficients ◽  
Low Temperatures ◽  
Functional Group ◽  
Organic Mixtures ◽  
Organic Functional Groups ◽  
Organic Solutions

Abstract. This study presents a new, improved parameterisation of the temperature dependence of activity coefficients in the AIOMFAC (Aerosol Inorganic–Organic Mixtures Functional groups Activity Coefficients) model applicable for aqueous as well as water-free organic solutions. For electrolyte-free organic and organic–water mixtures the AIOMFAC model uses a group-contribution approach based on UNIFAC (UNIversal quasi-chemical Functional-group Activity Coefficients). This group-contribution approach explicitly accounts for interactions among organic functional groups and between organic functional groups and water. The previous AIOMFAC version uses a simple parameterisation of the temperature dependence of activity coefficients, aimed to be applicable in the temperature range from ~ 275 to ~ 400 K. With the goal to improve the description of a wide variety of organic compounds found in atmospheric aerosols, we extend the AIOMFAC parameterisation for the functional groups carboxyl, hydroxyl, ketone, aldehyde, ether, ester, alkyl, aromatic carbon-alcohol, and aromatic hydrocarbon to atmospherically relevant low temperatures. To this end we introduce a new parameterisation for the temperature dependence. The improved temperature dependence parameterisation is derived from classical thermodynamic theory by describing effects from changes in molar enthalpy and heat capacity of a multi-component system. Thermodynamic equilibrium data of aqueous organic and water-free organic mixtures from the literature are carefully assessed and complemented with new measurements to establish a comprehensive database, covering a wide temperature range (~ 190 to ~ 440 K) for many of the functional group combinations considered. Different experimental data types and their processing for the estimation of AIOMFAC model parameters are discussed. The new AIOMFAC parameterisation for the temperature dependence of activity coefficients from low to high temperatures shows an overall improvement of 28% in comparison to the previous model version, when both versions are compared to our database of experimentally determined activity coefficients and related thermodynamic data. When comparing the previous and new AIOMFAC model parameterisations to the subsets of experimental data with all temperatures below 274 K or all temperatures above 322 K (i.e. outside a 25 K margin of the reference temperature of 298 K), applying the new parameterisation leads to 37% improvement in each of the two temperature ranges considered. The new parameterisation of AIOMFAC agrees well with a large number of experimental data sets. Larger model–measurement discrepancies were found particularly for some of the systems containing multi-functional organic compounds. The affected systems were typically also poorly represented at room temperature and further improvements will be necessary to achieve better performance of AIOMFAC in these cases (assuming the experimental data are reliable). The performance of the AIOMFAC parameterisation is typically better for systems containing relatively small organic compounds and larger deviations may occur in mixtures where molecules of high structural complexity such as highly oxygenated compounds or molecules of high molecular mass (e.g. oligomers) prevail. Nevertheless, the new parameterisation enables the calculation of activity coefficients for a wide variety of different aqueous/water-free organic solutions down to the low temperatures present in the upper troposphere.

Study on the Relations of Strength Control Indicators of Road Subgrade in Shanxi Loess Region

2014 ◽  
Vol 919-921 ◽  
pp. 1160-1163
Author(s):  
Xi Rong Wu ◽  
Li Li Zhu
Keyword(s):  
Moisture Content ◽  
Key Words ◽  
Water Content ◽  
Test Section ◽  
Laboratory Experiments ◽  
Resilient Modulus ◽  
Poor Correlation ◽  
Bearing Plate ◽  
Loess Region ◽  
The Relationship

Typical loess areas of Shanxi test section as the basis, through on-site tests, the paper presents the relationship between filed CBR, compaction,moisture content and on-site bearing plate modulus. Through laboratory experiments, the paper examines the variation of resilient modulus and CBR in different water content and degree of compaction conditions. The correlation between site and interior strength indicators was analyzed and the result shows that indicators tested in laboratory have good correlation while indicators tested in field have poor correlation. Key words: loess; rebound modules; CBR; moisture content;compaction; correlation

scholarly journals Biogenic oxidized organic functional groups in aerosol particles from a mountain forest site and their similarities to laboratory chamber products

2010 ◽  
Vol 10 (2) ◽  
pp. 4789-4822 ◽  
Author(s):  
R. E. Schwartz ◽  
L. M. Russell ◽  
S. J. Sjosted ◽  
A. Vlasenko ◽  
J. G. Slowik ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Functional Groups ◽  
Functional Group ◽  
Group Composition ◽  
Organic Aerosol ◽  
Anthropogenic Sources ◽  
Forest Site ◽  
Aerosol Composition ◽  
X Ray ◽  
Organic Functional Groups

Abstract. Submicron particles collected at Whistler, British Columbia, at 1020 masl during May and June 2008 on Teflon filters were analyzed by Fourier transform infrared (FTIR) and X-ray fluorescence (XRF) techniques for organic functional groups (OFG) and elemental composition. Organic mass (OM) ranged from less than 0.5 to 3.1μg m−3, with a project mean and standard deviation of 1.3±1.0 μg m−3 and 0.21±0.16 μg m−3 for OM and sulfate, respectively. On average, organic hydroxyl, alkane, and carboxylic acid groups represented 34%, 33%, and 23% of OM, respectively. Ketone, amine and organosulfate groups constituted 6%, 5%, and <1% of the average organic aerosol composition, respectively. Measurements of volatile organic compounds (VOC), including isoprene and monoterpenes from biogenic VOC (BVOC) emissions and their oxidation products (methyl-vinylketone/methacrolein, MVK/MACR), were made using co-located proton transfer reaction mass spectrometry (PTR-MS). We present chemically-specific evidence of OFG associated with BVOC emissions. Positive matrix factorization (PMF) analysis attributed 65% of the campaign OM to biogenic sources, based on the correlations of one factor to monoterpenes and MVK/MACR. The remaining fraction was attributed to anthropogenic sources based on a correlation to sulfate. The functional group composition of the biogenic factor (consisting of 32% alkane, 25% carboxylic acid, 2% organic hydroxyl, 16% ketone, and 6% amine groups) was similar to that of secondary organic aerosol (SOA) reported from the oxidation of BVOCs in laboratory chamber studies, providing evidence that the magnitude and chemical composition of biogenic SOA simulated in the laboratory is similar to that found in actual atmospheric conditions. The biogenic factor OM is also correlated to dust elements, indicating that dust may act as a non-acidic SOA sink. This role is supported by the organic functional group composition and morphology of single particles, which were analyzed by scanning transmission X-ray microscopy near edge X-ray absorption fine structure (STXM-NEXAFS).

scholarly journals Improved AIOMFAC model parameterisation of the temperature dependence of activity coefficients for aqueous organic mixtures

2014 ◽  
Vol 14 (11) ◽  
pp. 16907-16995 ◽  
Author(s):  
G. Ganbavale ◽  
A. Zuend ◽  
C. Marcolli ◽  
T. Peter
Keyword(s):  
Temperature Dependence ◽  
Functional Groups ◽  
Activity Coefficients ◽  
Low Temperatures ◽  
Functional Group ◽  
Group Contribution ◽  
Organic Mixtures ◽  
Temperature Range ◽  
Organic Functional Groups ◽  
Organic Solutions

Abstract. This study presents a new, improved parameterisation of the temperature dependence of activity coefficients in the AIOMFAC (Aerosol Inorganic–Organic Mixtures Functional groups Activity Coefficients) model applicable for aqueous as well as water-free organic solutions. For electrolyte-free organic and organic–water mixtures the AIOMFAC model uses a group-contribution approach based on UNIFAC (UNIversal quasi-chemical Functional-group Activity Coefficients). This group-contribution approach explicitly accounts for interactions among organic functional groups and between organic functional groups and water. The previous AIOMFAC version uses a simple parameterisation of the temperature dependence of activity coefficients, aimed to be applicable in the temperature range from ~275 to ~400 K. With the goal to improve the description of a wide variety of organic compounds found in atmospheric aerosols, we extend the AIOMFAC parameterisation for the functional groups carboxyl, hydroxyl, ketone, aldehyde, ether, ester, alkyl, aromatic carbon-alcohol, and aromatic hydrocarbon to atmospherically relevant low temperatures with the introduction of a new temperature dependence parameterisation. The improved temperature dependence parameterisation is derived from classical thermodynamic theory by describing effects from changes in molar enthalpy and heat capacity of a multicomponent system. Thermodynamic equilibrium data of aqueous organic and water-free organic mixtures from the literature are carefully assessed and complemented with new measurements to establish a comprehensive database, covering a wide temperature range (~190 to ~440 K) for many of the functional group combinations considered. Different experimental data types and their processing for the estimation of AIOMFAC model parameters are discussed. The new AIOMFAC parameterisation for the temperature dependence of activity coefficients from low to high temperatures shows an overall improvement of 25% in comparison to the previous model version. The new parameterisation of AIOMFAC agrees well with a large number of experimental datasets and enables the calculation of activity coefficients of a wide variety of different aqueous/water-free organic solutions down to the low temperatures present in the upper troposphere.

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