scholarly journals Physicochemical Insights of the Organic Matter Particles Dispersed in Wastewaters Induced by Bio-Polyelectrolytes

2021 ◽  
Author(s):  
Carlos A. Quintero Gonzalez ◽  
Eduardo A. López-Maldonado ◽  
Mercedes T. Oropeza-Guzmán
Keyword(s):  
Water Reuse ◽  
Colloidal Particles ◽  
Oxygen Demand ◽  
Processing Industry ◽  
Charged Species ◽  
Fine Filter ◽  
Long Time ◽  
Pass Through ◽  
By Products ◽  
Flocculation Process

The turbidity and color of the water are mainly caused by colloidal particles. These particles remain in suspension for a long time and can even pass through a very fine filter medium, since they do not have a tendency to agglomerate. Due to this, polyelectrolytes such as chitosan have been used in coagulation-flocculation processes because they dissociate into charged species in solution and these contribute to charges or dissociable groups which are covalently bound to its structure. With the zeta potential measurements (ζ) vs. pH and particle size, the ideal dose of bio-polyelectrolyte was determined with which, the isoelectric point (IEP) was reached, generating electroneutrality in the system, removing 92% of the chemical oxygen demand (COD). The results discussed here represent a sustainable alternative to the water reuse and sanitation problem of the fish processing industry. The use of bio-polyelectrolytes offers that the by-products obtained from the coagulation-flocculation process can be reused and recovered for other uses.

scholarly journals Treatment of fish processing industry wastewater using hydrodynamic cavitational reactor with biodegradability improvement

2019 ◽  
Vol 80 (12) ◽  
pp. 2310-2319 ◽  
Author(s):  
Prashant Dhanke ◽  
Sameer Wagh ◽  
Abhijeet Patil
Keyword(s):  
Organic Matter ◽  
New Technology ◽  
Oxygen Demand ◽  
Operating Conditions ◽  
Hydrodynamic Cavitation ◽  
Inlet Pressure ◽  
Fish Processing ◽  
Processing Industry ◽  
Cavitation Effect ◽  
Processing Plants

Abstract Water generated from the fish processing industry is contaminated with organic matter. This organic matter present in wastewater increases the biochemical oxygen demand (BOD) and chemical oxygen demand (COD). A new technology, hydrodynamic cavitation (HC) is used to deal with this wastewater produced in fish processing plants. The orifice plate is used in the HC reactor to generate a cavitation effect. The intensification of this technique was carried out with the help of hydrogen peroxide (H2O2) and TiO2. The treatment of this wastewater is reported in terms of percent degradation in BOD and COD and in biodegradability index (BI). Operating parameters like inlet pressure, pH, operating temperature and H2O2 doses were used to find the optimum condition. 15 g/L of H2O2 gave 69.5% reduction of COD in the 120 min of treatment that also increases BI value to 0.93 at inlet pressure 8 bar, Plate-5, temperature (30 °C), and pH 4. In the ultrasonic cavitation (UC) reactor, COD reduction is 68.7% without TiO2 and with TiO2 it is 71.2%. Also, this HC and UC reactor reduced CFU count to a great extent at the same operating conditions.

scholarly journals Oxidative degradation of gentamicin present in water by an electro-Fenton process and biodegradability improvement

2019 ◽  
Vol 17 (1) ◽  
pp. 1017-1025
Author(s):  
Mohamed Réda Arhoutane ◽  
Muna Shueai Yahya ◽  
Miloud El Karbane ◽  
Kacem El Kacemi
Keyword(s):  
Chemical Oxygen Demand ◽  
Biological Process ◽  
Oxidative Degradation ◽  
Oxygen Demand ◽  
Polluted Water ◽  
Applied Current ◽  
Pseudo First Order Reaction ◽  
First Order ◽  
Appropriate Treatment ◽  
By Products

AbstractIn the context of environmental protection, where there is a need to develop effective operations for carrying out appropriate treatment of polluted water by pharmaceuticals. Therefore, the present study aims at evaluating the degradation for gentamicin through electro-Fenton (EF) operation, through taking into consideration the effect of several parameters of experimental in the process, namely, the concentration of initial gentamicin, the applied current and the Fe+2 (II) quantities. The (EF) operation employed involves a carbon-felt as cathode and platinum as anode at pH 3. Studies for the gentamicin kinetics is monitored by HPLC giving a pseudo-first order reaction following by a chemical oxygen demand, with a reached degree of mineralization 96% after of four hours of treatment through current 100 mA/cm2 with 0.1 mM of Fe+2. We find that the degradation for molecule of gentamicin is accompanied by an augmentation of the biodegradability, assesse through the Biochemical Oxygen Demand (BOD5) on chemical oxygen demand (COD) ratio, that augmentation from 0 to 0.41 before treatment after 30 min for EF treatment, showing that there is potential for conjugation of the EF process and the biological process. Furthermore, the by-products have been identified on the basis of HPLC-MS/MS results.

Treatment of Palm Oil Mill Effluent (POME) Supernatants Using Aerobic Attached–Growth System: Trickling Filter as a Case Study

2012 ◽  
Author(s):  
Ahmad Zuhairi Abdullah ◽  
Mohamad Hakimi Ibrahim ◽  
Mohd. Omar Ab. Kadir
Keyword(s):  
Palm Oil ◽  
Colloidal Particles ◽  
Oxygen Demand ◽  
Cod Removal ◽  
Palm Oil Mill Effluent ◽  
Trickling Filter ◽  
Biomass Hydrolysis ◽  
Removal Efficiencies ◽  
Palm Oil Mill ◽  
Hydrolysis Of

Kertas kerja ini membincangkan tentang kecekapan penuras cucur dalam merawat supernatan kumbahan kilang kelapa sawit (POME). Supernatan POME diperoleh menerusi dua jenis perawatan. Dalam perawatan 1, pengendapan graviti digunakan untuk menyingkir pepejal boleh mendak. Perawatan 2 digunakan untuk menyingkir pepejal boleh mendak dan gumpalan partikal dengan menggunakan 350 ppm alum. Influen dialurkan secara titisan pada biojisim yang terlekat pada penyokong pepejal rawak PVC setinggi 1 m. Penuras cucur berupaya menyingkir lebih daripada 90.0% dari keperluan oksigen biologi (BOD) dan keperluan oksigen kimia (COD) di bawah 1 m3/m2–hari. Pada 2.53 m3/m2–hari, influen dengan Perawatan 1 menghasilkan kecekapan penyingkiran COD sebanyak 40.3%, berbanding 83.1% bila Perawatan 2 digunakan. Perkara ini berlaku berikutan penyingkiran bahan organik tak boleh resap semasa Perawatan 2. Kecekapan penyingkiran menurun dengan meningkatnya bebanan hidraulik kerana wujudnya kelemahan dalam hidrolisis bahan tak boleh resap kepada substratum larut. Dengan edaran semula (α=1), penyingkiran BOD dan COD yang lebih tinggi dicapai di bawah 7 m3/m2–hari. Pencapaian ini disebabkan oleh bebanan organik yang lebih rendah serta pergedaran semula enzim dan biojisim yang aktif kepada sistem. Perawatan 2 menghasilkan enap cemar yang lebih tinggi kerana penukaran substratum boleh larut kepada biojisim tak boleh larut. Hidrolisis bahan organik tak boleh resap didapati berlaku secara aktif pada bahagian atas penuras cucur sementara bahagian bawahnya cenderung mengoksidakan substratum organik. Kata kunci: POME, turas cucur, bahan organik bolehresap, penggumpalan, alir semula This paper discusses the efficiency of a trickling filter to treat Palm Oil Mill Effluent (POME) supernatants. POME supernatants were obtained via two treatments. In Treatment 1, gravity sedimentation was used to remove settleable solids. In Treatment 2, both settleable solids and colloidal particles were removed using 350 ppm of alum. The influents were allowed to trickle over biomass attached to 1 m high random PVC solid support. Below 1 m3/m2–day, the filter demonstrated Biological Oxygen Demand (BOD) and Chemical Oxygen Demand (COD) removal efficiencies of more than 90.0%. At 2.53 m3/m2–day, the influent with Treatment 1 gave a COD removal efficiency of 40.3%, but increased to 83.1% when the influent with Treatment 2 was used. This was ascribed to the removal of non–diffusible organics during Treatment 2. The removal efficiencies decreased with an increase in hydraulic loading due to limitations in the hydrolysis of non–diffusibles into soluble substrates. With recirculation (α=1), higher BOD and COD removals were achieved below 7.0 m3/m2–day, attributed to lower organic loading and the recycling of active enzyme and biomass to the system. The influent with Treatment 2 demonstrated higher sludge production due to higher conversion of soluble substrates into insoluble biomass. Hydrolysis of non–diffusible organics mainly took place at upper reaches of the filter column while lower reaches were involved in oxidizing the organic subtrates. Key words: POME, trickling filter, diffusible organic, coagulation, recirculation

Long-time self-diffusion of charged spherical colloidal particles in parallel planar layers

2014 ◽  
Vol 140 (24) ◽  
pp. 244116 ◽  
Author(s):  
Claudio Contreras-Aburto ◽  
César A. Báez ◽  
José M. Méndez-Alcaraz ◽  
Ramón Castañeda-Priego
Keyword(s):  
Colloidal Particles ◽  
Self Diffusion ◽  
Long Time

Agricultural utilization of lignosulfonates

Holzforschung ◽  
2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Gerhild K. Wurzer ◽  
Hubert Hettegger ◽  
Robert H. Bischof ◽  
Karin Fackler ◽  
Antje Potthast ◽  
...  
Keyword(s):  
Paper Industry ◽  
Pulp And Paper Industry ◽  
Feed Additive ◽  
Complexing Agent ◽  
Fuel Pellets ◽  
Inorganic Substances ◽  
Binding Agents ◽  
Long Time ◽  
Renewable Material ◽  
By Products

Abstract Lignosulfonates (LSs) are by-products of the pulp and paper industry from pulping of lignocellulosic biomass according to the sulfite process. This renewable material already plays a role in low-value applications, such as binding agents for fuel, pellets, as a feed additive, or as a dispersant. Another possible field of application of this technical lignin type is agriculture. It is known that this eco-friendly and cheap material can improve soil quality, fertilizer efficacy and replace or decrease the use of potentially (eco)toxic organic or inorganic substances. The use of LS in agriculture and five main strategies for the implementation of LS in soil are discussed in this review: LS as a complexing agent with micronutrients, co-pelleting of LS with (macro)nutrients, capsule formation with LS for coating of fertilizers or pesticides, LS as a biostimulant, and ammonoxidation of LS. All five ways can be beneficial in fertilizer-related applications, either to slow down the release of nutrients or pesticides, to substitute harmful chemicals, or to inhibit nitrification and modify fertilizer behaviour. Nevertheless, application and long-time studies are often missing, and more research is required for generating products that are economically competitive to commercial bulk products.

Table II : Quantitative determination of carbonyl compounds at different odour sources (concentrations in ppb) Rendering plant Gelatine plant neighbourhood neighbourhood Formaldehyde 40 16 Acetaldehyde 39 24 Acetone 36 73 Prcpanal 10 -Isobutyraldehyde 10 30 Pentanal 15 19 Hexanal 3.52 Heptanal 12.5 Octanal 10.5 Nonanal 1 2 acids (figure 7). However extractions always involve a serious decrease in sensitivity, while evaporation of the extract produces a solution in 0.1-0.5 ml of solvent, and only 1 pi of it can be brought in the gas chromatograph. Therefore work is in progress to enhance sensitivity by converting acids in­ to halogenated derivatives, which can be GC-analysed with the more sensitive electron-capture detector. For thiols a similar procedure is investigated as with aldehydes. One possibility is absorption of thiols in an alkaline solution and reaction with 2,4-dinitrochlorobenzene, yielding 2,4-dinitrofenylsulfides, which are analysed by HPLC (9). Sane improvements on removal of reagents at the one hand and on separation of sane by-products on the other hand have to be achieved in order to in­ crease the sensitivity with another factor of ten. 5. CONCLUSION The actual scope and limitations of chemical analysis of odour show that all problems can be tackled as far as emission is concerned. For iititiission measurements seme progress is necessary, but there is no essential reason why chemical analysis would be unable to attain the desired sensitivity for all types of odorants. There is no doubt that in a few years the last dif­ ficulties will be solved. In order to achieve real control of odour nui­ sance, automatic measurement is necessary on a long time basis. There again seme technical development is to be expected. Does this mean that machines are going to decide if an odour is pre­ sent or not? By no means, while the population will always be the reference, and psychophysical measurements will be necessary to make chemical analysis possible.

1986 ◽  
pp. 171-171
Keyword(s):  
Chemical Analysis ◽  
Quantitative Determination ◽  
Alkaline Solution ◽  
Automatic Measurement ◽  
The Other ◽  
Long Time ◽  
Time Basis ◽  
The One ◽  
By Products

scholarly journals Seasonal changes of biological condition and reproductive cycle of hampback shrimp Pandalus hypsinotus (Caridea, Pandalidae) in the Tatar Strait

2021 ◽  
Vol 201 (3) ◽  
pp. 547-560
Author(s):  
D. N. Yuriev ◽  
G. V. Zhukovskaya
Keyword(s):  
Reproductive Cycle ◽  
Japan Sea ◽  
Biological Condition ◽  
Tatar Strait ◽  
Stage Of Development ◽  
Long Time ◽  
Pass Through ◽  
The Individual ◽  
Almost All ◽  
Trawl Catches

Research and commercial trawl catches of humpback shrimp Pandalus hypsinotus from the Tatar Strait (Japan Sea) in 2004–2020 were investigated, with bioanalysis of about 45 thousand specimens. Average timing of group molting, spawning, and eggs laying are determined, terms of gonads and eggs development are estimated. Prespawning and molting of the females occur between January-April, with the peaks in early February and middle February, respectively. All oviparous females have 30–40 days to lay eggs, and molt during 50–55 days; the peak of the eggs laying occurs in late June. The males molt in July-August, afterwards the largest individuals change gender and new intersexes are formed. The males have the second molting in October-December, with the peak in late November. In January, after finish of the males molting, a new annual reproduction cycle starts from the prespawning molting of females. Both vitellogenesis and embryogenesis are observed through the year, though females with developing gonads prevail from August to January (because of a long time span between winter and summer moltings while the egg carrying continued 15 months) but oviparous females — from February to July. The individual reproductive cycle of Pandalus hypsinotus in the Tatar Strait lasts 24 months, with 9 months of vitellogenesis (quick growth of gonads) and 15 months of embryogenesis. During the 2-year reproductive cycle, most of females pass through the following stages: i) gonads development (just after eggs laying) when almost all oviparous females (up to 95 % in May) have green gonads under carapace that corresponds to the stage of development «eggs laid — gonads weakly developed»; ii) summer molting from August when females lose hairs on pleopods and the gonads growth accelerates; iii) respawning in January-March (together with the firstly spawning intersexes, with slight delay of the latter); iv) initial developing of eggs during summer; v) stage of «eyed eggs» from December to March; and vi) eggs laying and molting from late March to late May; then the 2-year reproductive cycle repeats.

scholarly journals Effect of applied voltage on membrane fouling in the amplifying anaerobic electrochemical membrane bioreactor for long-term operation

RSC Advances ◽  
2021 ◽  
Vol 11 (50) ◽  
pp. 31364-31372
Author(s):  
Mengjing Cao ◽  
Yongxiang Zhang ◽  
Yan Zhang
Keyword(s):  
Chemical Oxygen Demand ◽  
Applied Voltage ◽  
Membrane Fouling ◽  
Membrane Bioreactor ◽  
Glucose Solution ◽  
Oxygen Demand ◽  
Term Operation ◽  
Long Time

A novel and amplifying anaerobic electrochemical membrane bioreactor was constructed and operated for a long time (204 days) with synthetic glucose solution having an average chemical oxygen demand (COD) of 315 mg L−1, at different applied voltages and room temperatures.

scholarly journals An Expedient SERS Strip Tactic for Rapid On-Site Detection with Long-Time Sensitivity and Repeatability

2021 ◽  
Vol 2021 ◽  
pp. 1-8
Author(s):  
Chen Wang ◽  
Yueqian Wan ◽  
Yong Su ◽  
Yafei Cai ◽  
Shengjun Xiong ◽  
...  
Keyword(s):  
Colloidal Particles ◽  
Rhodamine 6G ◽  
Surface Enhanced Raman Spectroscopy ◽  
Dip Coating ◽  
Animal Blood ◽  
Discrimination Capability ◽  
Time Sensitivity ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Long Time

Surface-enhanced Raman spectroscopy (SERS) has attracted lots of interest in academic and industrial fields in recent years. The improvement in long-time sensitivity and repeatability is highly demanded by the on-site applications. Herein, we present an expedient SERS strip tactic with these desired advantages. Specifically, the tactic utilized the outstanding stability of colloidal particles to maintain the SERS materials during the storage. Upon usage, the strip is rapidly prepared on-site, and then the targets were sampled with a dip-coating and heating method, which is designed to standardize the whole detection process with the sensitivity kept. Thanks to the tactic, only one-third of SERS sensitivity decay was observed for rhodamine 6G after half a year. Besides rhodamine 6G, the SERS spectra of different animal blood samples were also investigated with the SERS strip tactic, and a species-based discrimination capability was preliminarily demonstrated.

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