scholarly journals Experimental Investigation of the Biomass Catalytic Pyrolysis Process to Produce the Combustible Gases with the High Calorific Value

Author(s):  
Yury Kosivtsov ◽  
Esther Sulman ◽  
Yury Lugovoy ◽  
Anna Kosivtsova ◽  
Antonina Stepacheva
2021 ◽  
Author(s):  
YiRan Zhang ◽  
Jianfen Li ◽  
Bolin Li ◽  
Zeshan Li ◽  
Yun He ◽  
...  

Abstract The developed Ni-La/Al2O3-CeO2-Bamboo charcoal (ACB) catalyst was applied to the co-pyrolysis of straw and plastic to produce hydrogen in a horizontal quartz tube pyrolysis furnace. In this study, the effects of the mixing ratio of straw and plastic, the presence and stability of the catalyst on the co-pyrolysis hydrogen production were investigated. Experiment showed that the addition of PE can increase the yield of H2 within a certain range, and the best mass ratio of 5:5 was found. In the co-pyrolysis process with the participation of the catalysts, the macromolecular tar can be cracked into combustible gases such as H2, and the H2 yield could be increased to 332.2ml/g (Ni-La/ACB) is much higher than 68.87ml/g without catalyst. Compared with Ni/ACB, Ni-La/ACB had been increased the alkalinity by adding La element and enhanced the carbon deposition resistance of the catalyst, which makes the catalyst maintain higher stability. This was also confirmed in stability test experiments.


2013 ◽  
Vol 787 ◽  
pp. 184-189 ◽  
Author(s):  
Khanh Vi Dang ◽  
Suzana Yusup ◽  
Yoshimitsu Uemura ◽  
Mohd Fadhil Nuruddin

The market demand of bio-fuel is 11,8 billion litters based on recent reported data. Hence, with the high demand of bio-fuel, the bio-fuel production utilizing rice husk can be one of the solutions. Beside, bio-oil can be produced by pyrolysis process utilizing rice husk as the feedstock. In this research, the optimization condition in producing bio-oil from rice husk by catalytic pyrolysis process was studied. The effect of catalyst type (H-β, H-Y, HZSM-5), catalyst loading (1wt%, 5wt%, 12wt%), temperature (400-500°C) and flow rate (60-100ml/min) were investigated through repetitive experiments using L9 Taguchi Orthogonal Array. The highest liquid yield of 38wt% was obtained at the optimum conditions with temperature of 500°C with nitrogen flow rate of 60ml/min and 12wt% of H-ZSM-5.


2015 ◽  
Vol 787 ◽  
pp. 67-71
Author(s):  
R.M. Alagu ◽  
E. Ganapathy Sundaram

Pyrolysis process in a fixed bed reactor was performed to derive pyrolytic oil from groundnut shell. Experiments were conducted with different operating parameters to establish optimum conditions with respect to maximum pyrolytic oil yield. Pyrolysis process was carried out without catalyst (thermal pyrolysis) and with catalyst (catalytic pyrolysis). The Kaolin is used as a catalyst for this study. The maximum pyrolytic oil yield (39%wt) was obtained at 450°C temperature for 1.18- 2.36 mm of particle size and heating rate of 60°C/min. The properties of pyrolytic oil obtained by thermal and catalytic pyrolysis were characterized through Fourier Transform Infrared Spectroscopy (FT-IR) and Gas Chromatography-Mass Spectrometry (GC-MS) techniques to identify the functional groups and chemical components present in the pyrolytic oil. The study found that catalytic pyrolysis produce more pyrolytic oil yield and improve the pH value, viscosity and calorific value of the pyrolytic oil as compared to thermal pyrolysis.


Author(s):  
Amal Bellahcene ◽  
Madjid Hachemi ◽  
Jean-François Largeau ◽  
Lyes Tarabet ◽  
Gaëtan Burnens ◽  
...  

Eksergi ◽  
2021 ◽  
Vol 18 (1) ◽  
pp. 13
Author(s):  
Sri Wahyu Murni ◽  
Tutik Muji Setyoningrum ◽  
Muhamad Maulana Azimatun Nur

Indonesia biomass waste is a potential feedstock as a source of renewable energy since it can be converted into carcoal briquettes. However, the production of the briquettes using pyrolysis process using the agricultural waste was lacking. In this research, briquette was made from palm shells,  corncob and soybean stem wood due to its high availability and have high cellulose content. The purpose of this research was to produce briquettes from three kind of raw materials by employing pyrolysis process and compared the characteristics. The briquette was made from different type of raw materials (palm shells, corncob and soybean stem) and  the concentration of binder : 3-7 %. Pyrolysis was done at  500 °C, and 100 kg / cm2 of pressing pressure. Results showed that, the best charcoal briquette was achieved from palm shells by using 5% binder, which resulted 4,1% moisture content, 3.4% ash content,  15% volatile matter content, 77.5% carbon content,  7075 cal/g calorific value and  1.4 kg/cm2 compresive strength. It is found that the concentration of binder and raw material influenced the quality of the briquettes. In overall, the production of the briquettes by employing pyrolysis method could meet the standard.


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