Investigating the Effects of Particle Size on the Growth of Silkworm and Fiber Properties with Feeding TiO2 NPs

The production method of functional silk by feeding the various nanoparticles is simple, it has attracted the attention of many researchers. However, many researchers have studied the concentrate of nanoparticles (NPs), there are few studies on the particle size. This study is aimed to confirm the effects in silkworm growth, cocoon quality, and mechanical properties of silk with feeding TiO2 NPs of the various particle size. TiO2 10nm, 50nm, 100nm powers individually are fed to silkworm, investigated the mortality and proliferation rate, cocoon mass and cocoon shell mass, mechanical characteristic of silk fiber. The experiments demonstrated that the larger the particle size of TiO2 NPs, the greater the adverse impact on the growth and livability of silkworms. The stress of 523.35±42 MPa and strain of 19.73±1.8% of the TiO2-10nm added silk were increased 35.9% and 19.5% on average, respectively. By the analysis of the Fourier transform infrared (FTIR) spectra, it was confirmed that this resulted in a more random coil/?-helix structure. The nanoparticles are acted as knots, forming the cross-linked network, resulting in lower crystallinity and higher strain, but the larger the particle, the fewer the number of knots, at the same time, it has a great impact on protein synthesis, and then the strength may be decreased. The effect in the silkworm body of TiO2 NPs particle size has to be deeply studied, but this study has important significance to study in the production of the functional silk by feed additives.

Pollen limitation and xenia effects in a cultivated mass-flowering tree, Macadamia integrifolia (Proteaceae)

Background and Aims Pollen limitation is most prevalent among bee-pollinated plants, self-incompatible plants, and tropical plants. However, we have very little understanding of the extent to which pollen limitation affects fruit set in mass-flowering trees despite tree crops accounting for at least 600 million tons of the 9,200 million tons of annual global food production. Methods We determined the extent of pollen limitation in a bee-pollinated, partially self-incompatible, subtropical tree by hand cross-pollinating the majority of flowers on mass-flowering macadamia (Macadamia integrifolia) trees that produce about 200,000–400,000 flowers. We measured tree yield and kernel quality and estimated final fruit set. We genotyped individual kernels by MassARRAY to determine levels of outcrossing in orchards and assess paternity effects on nut quality. Key Results Macadamia trees were pollen limited. Supplementary cross-pollination increased nut-in-shell yield, kernel yield and fruit set by as much as 97%, 109% and 92%, respectively. The extent of pollen limitation depended upon the proximity of experimental trees to trees of another cultivar because macadamia trees were highly outcrossing. Between 84% and 100% of fruit arose from cross-pollination, even at 200 m (25 rows) from orchard blocks of another cultivar. Large variations in nut-in-shell mass, kernel mass, kernel recovery and kernel oil concentration were related to differences in fruit paternity, including between self-pollinated and cross-pollinated fruit, thus demonstrating pollen-parent effects on fruit quality, i.e. xenia. Conclusions This study is the first to demonstrate pollen limitation in a mass-flowering tree. Improved pollination led to increased kernel yield of 0.31–0.59 tons per hectare, which equates currently to higher farm-gate income of approximately US3,720–US7,080 per hectare. The heavy reliance of macadamia flowers on cross-pollination and the strong xenia effects on kernel mass demonstrate the high value that pollination services can provide to food production.

Preparation of Polyurea Microcapsules by Interfacial Polymerization of Isocyanate and Chitosan Oligosaccharide

(2-((1-(4-chlorophenyl)-1H-pyrazol-3-yl)oxy)-N-(3,4-dichlorophenyl)-propanamide) is a new oil-soluble compound with good fungicidal activity against Rhizoctonia solani. Chitosan oligosaccharide (COS) is the depolymerization product of chitosan and can be developed into biological pesticides, growth regulators, and fertilizers due to its various bioactivities. COS is an oligomer of β- (1 → 4)-linked d –glucosamine and can be taken as a polyamine. In this study, microcapsules were prepared by interfacial polymerization of oil-soluble methylene diphenyl diisocyanate and water-soluble COS. The effects of several key preparation parameters, e.g., emulsifier dosage, agitation rate during emulsification, and core/shell ratio, on properties of the microcapsules such as the encapsulation efficiency, particle size, and size distribution were investigated. The microcapsules were characterized by infrared spectroscopy, thermogravimetric analysis, and scanning electron microscopy, etc., and the encapsulation efficiency and release behaviors were investigated. The results show that the microcapsules have a smooth surface and 93.3% of encapsulation efficiency. The microcapsules showed slow-release behavior following a first-order kinetic equation, and the accumulative release rates of the microcapsules with core/shell mass ratios of 8.0/4.0, 8.0/5.0, and 8.0/6.0, were 95.5%, 91.4%, and 90.1%, respectively, on day 30. Due to many high biological activities, biodegradability, and the pure nature of COS, microcapsules formed from COS are promising for applications in controlled release of pesticides, growth regulators, and fertilizer.

Metamaterials Demonstrating Negative Thermal Capacity

One-dimensional chain of core-shell pairs connected by ideal springs enables design of the metamaterial demonstrating the negative effective density and negative specific thermal capacity. We assume that the molar thermal capacity of the reported metamaterial is governed by the Dulong-Petit law in its high temperature limit. The specific thermal capacity depends of the density of the metamaterial; thus, it is expected to be negative, when the effective density of the chain is negative. The range of the frequencies enabling the effect of the negative thermal capacity is established. Dependence of the effective thermal capacity on the exciting frequency for various core/shell mass ratios is elucidated. The effective thermal capacity becomes negative in the vicinity of the local resonance frequency ω0 in the situation when the frequency ω approaches ω0 from above. The effect of the negative effective thermal capacity is expected in metals in the vicinity of the plasma frequency.

Metamaterials Demonstrating Negative Thermal Capacity

: One-dimensional chain of core-shell pairs connected by ideal springs enables design of the metamaterial demonstrating the negative effective density and negative specific thermal capacity. We assume that the molar thermal capacity of the reported metamaterial is governed by the Dulong-Petit law in its high temperature limit. The specific thermal capacity depends of the density of the metamaterial; thus, it is expected to be negative, when the effective density of the chain is negative. The range of the frequencies enabling the effect of the negative thermal capacity is established. Dependence of the effective thermal capacity on the exciting frequency for various core/shell mass ratios is elucidated. The effective thermal capacity becomes negative in the vicinity of the local resonance frequency ω0 in the situation when the frequency ω approaches ω0 from above. The effect of the negative effective thermal capacity is expected in metals in the vicinity of the plasma frequency.

Optimal design of buckling resistance for a large deepwater functional tank (DFT)

Buckling resistance is a major challenge in the design of a large deepwater functional tank (DFT), and internal stiffeners are commonly used to strengthen its shell. In the present paper, the influence of various stiffener parameters on the stability of the DFT was studied via the finite element method. The strengthening scheme of the DFT was optimised by the orthogonal test method, by which the influence of various parameters on the shell mass, internal volume and stability of the structure was evaluated. The optimal buckling resistance scheme can be obtained using the comprehensive balance method based on the orthogonal assessment results.

Exact results for $$ {Z}_m^{\mathrm{OS}} $$ and $$ {Z}_2^{\mathrm{OS}} $$ with two mass scales and up to three loops

We consider the on-shell mass and wave function renormalization constants $$ {Z}_m^{\mathrm{OS}} $$ Z m OS and $$ {Z}_2^{\mathrm{OS}} $$ Z 2 OS up to three-loop order allowing for a second non-zero quark mass. We obtain analytic results in terms of harmonic polylogarithms and iterated integrals with the additional letters $$ \sqrt{1-{\tau}^2} $$ 1 − τ 2 and $$ \sqrt{1-{\tau}^2}/\tau $$ 1 − τ 2 / τ which extends the findings from ref. [1] where only numerical expressions are presented. Furthermore, we provide terms of order $$ \mathcal{O} $$ O (ϵ2) and $$ \mathcal{O} $$ O (ϵ) at two- and three-loop order which are crucial ingredients for a future four-loop calculation. Compact results for the expansions around the zero-mass, equal-mass and large-mass cases allow for a fast high-precision numerical evaluation.

The globular cluster M10: reassessment of stellar membership, distance, and age using its variable and HB stars

ABSTRACT Time-series VI CCD photometry of the globular cluster M10 (NGC 6254) is employed to perform a detailed identification, inspection of their light curves, their classification, and their cluster membership, of all the known variables reported up to 2018. The membership analysis is based on the $Gaia$-DR2 positions and proper motions. The metallicity of the cluster is estimated based on the sole RRc star known in the cluster. The Fourier decomposition of its light curve leads to [Fe/H]$_{\rm ZW}$ = $-1.59 \pm 0.23$ dex. The mean cluster distance, estimated by several independent methods, is $5.0 \pm 0.3$ kpc. A multiapproach search in a region of about 10$\times$10 arcmin$^2$ around the cluster revealed three new variables, one SX Phe (V35) and two sinusoidal variables on the red giant branch (RGB) of unclear classification (V36 and V37). Modelling the HB stars is very sensitive to the stellar hydrogen shell mass, which surrounds the 0.50 $\mathrm{ M}_{\odot }$ helium core. To match the full stretch of the HB population, a range of total mass of 0.56–0.62 $\mathrm{ M}_{\odot }$ is required. These models support a distance of 5.35 kpc and an age of about 13 Gyr, and hint to some individual variation of the mass-loss on the upper RGB, perhaps caused by the presence of closed magnetic field in red giants.

X-ray tomographic data of planktonic foraminifera species Globigerina bulloides from the Eastern Tropical Atlantic across Termination II

Increased planktonic foraminifera shell weights were recorded during the course of Termination II at a tropical site off the shore of the Mauritanian coast. In order to investigate these increased shell mass values, a series of physicochemical analyses were performed, including X-ray computed tomography (CT). The data are given here. Furthermore, the relevant CT setup, scanning, reconstruction, and visualization methods are explained and the acquired datasets are given, together with 3D volumes and models of the scanned specimens.