scholarly journals Study on Manufacturing Environmentally Friendly Alkyd Paint

Author(s):  
Nguyen Trung Thanh

The article presents results of studying and manufacturing environmentally friendly alkyd paint. By producing a polysaccharide intermediate emulsion (LPR), about 20% of water to total paint volume was added. Mechanical properties (impact resistance, flexural strength, adhesion) of paint films were studied. In addition, the paper presents results of thermal stability, 10-cycle UV-thermo-humidity complex stability of paint film. Ability of films to withstand 03-cycle heat shocking of films at temperatures of + 50 oC and -50 oC was investigated. The properties of studying paint were compared with those of an alkyd paint of Hanoi Synthetic Paint Company. Results show that the environmentally friendly alkyd paint has less volatile organic compounds (VOC), uses a smaller amount of toxic solvents, while its properties are comparable to common alkyd paint.

Author(s):  
Nguyen Trung Thanh

The article introduces the modification of alkyd resin by epoxy resin to make epoxy alkyd ester. The study investigated the effects of reflux xylene content, the proportion of the constituents participating in the esterification reaction on the reaction processing and acidity index of the product. The infrared (IR) spectroscopy results confirmed the formation of ester bonds after the reaction. The paper also studied the mechanical properties of paint film based on the synthesized ester epoxy alkyd and compared them with the alkyd paint, the results showed that impact resistance and hardness of the study sample were higher than those of the alkyd paint sample. In addition, investigation, comparison of thermal stability of alkyd paint and epoxy alkyd paint film were also mentioned. Keywords: Epoxy alkyd esters, mechanical properties, thermal endurance, drying time.


Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1064
Author(s):  
Mohd Nor Faiz Norrrahim ◽  
Hidayah Ariffin ◽  
Tengku Arisyah Tengku Yasim-Anuar ◽  
Mohd Ali Hassan ◽  
Nor Azowa Ibrahim ◽  
...  

Residual hemicellulose could enhance cellulose nanofiber (CNF) processing as it impedes the agglomeration of the nanocellulose fibrils and contributes to complete nanofibrillation within a shorter period of time. Its effect on CNF performance as a reinforcement material is unclear, and hence this study seeks to evaluate the performance of CNF in the presence of amorphous hemicellulose as a reinforcement material in a polypropylene (PP) nanocomposite. Two types of CNF were prepared: SHS-CNF, which contained about 11% hemicellulose, and KOH-CNF, with complete hemicellulose removal. Mechanical properties of the PP/SHS-CNF and PP/KOH-CNF showed an almost similar increment in tensile strength (31% and 32%) and flexural strength (28% and 29%) when 3 wt.% of CNF was incorporated in PP, indicating that hemicellulose in SHS-CNF did not affect the mechanical properties of the PP nanocomposite. The crystallinity of both PP/SHS-CNF and PP/KOH-CNF nanocomposites showed an almost similar value at 55–56%. A slight decrement in thermal stability was seen, whereby the decomposition temperature at 10% weight loss (Td10%) of PP/SHS-CNF was 6 °C lower at 381 °C compared to 387 °C for PP/KOH-CNF, which can be explained by the degradation of thermally unstable hemicellulose. The results from this study showed that the presence of some portion of hemicellulose in CNF did not affect the CNF properties, suggesting that complete hemicellulose removal may not be necessary for the preparation of CNF to be used as a reinforcement material in nanocomposites. This will lead to less harsh pretreatment for CNF preparation and, hence, a more sustainable nanocomposite can be produced.


2021 ◽  
Vol 20 (1) ◽  
pp. 37-51
Author(s):  
Kubilay Akçaözoğlu ◽  
◽  
Adem Kıllı ◽  

In this study, the effect of curing conditions on the mechanical properties of slurry infiltrated fiber reinforced concrete (SIFCON) was investigated. For this purpose, SIFCON samples containing 4% and 8% steel fiber with two different aspect ratios were produced. The samples were subjected to three different curing types, namely standard, dry and accelerated curing methods. Ultrasonic wave velocity, flexural strength, fracture toughness, compressive strength, impact resistance and capillary water absorption tests were performed on the samples. The highest flexural strength was found to be achieved in the samples with an aspect ratio of 55 and a content of 8% steel fiber. The most suitable curing method was determined as the standard curing method and the best flexural strength was achieved at the rate of 8%. According to the test results, the best strength properties were achieved in the samples exposed to the standard curing method. In addition, the samples exposed to the accelerated curing method showed satisfactory values. The accelerated curing method can be used as an alternative in SIFCON production especially in applications requiring mass production.


2019 ◽  
Vol 22 (3) ◽  
pp. 208-212
Author(s):  
Sheelan M. Hama ◽  
Alhareth M. Abdulghafor ◽  
Mohammed Tarrad Nawar

In this work, waste glass powder from broken windows and plastic fibers from waste polyethylene terephthalate bottles are utilized to produce an economical self-compact concrete. Fresh properties (slump flow diameter, slump Flow T50, V. Funnel, L–Box), mechanical properties (Compressive strength and Flexural strength) and impact resistance of self-compact concrete are investigated. 15% waste glass powder as a partial replacement of cement with five percentages of polyethylene terephthalate plastic waste were adopted: 0% (reference), 0.5%, 0.75%, 1%, 1.25% and 1.5% by volume. It seems that the flow ability of self-compact concrete decreases with the increasing of the amount of plastic fibers. The compressive strength was increased slightly with plastic fiber content up to (0.75%), about 4.6% For more than (0.75%) plastic fiber. The compressive strength began to decrease about 15.2%. The results showed an improvement in flexural strength and an impact on the resistance in all tested specimens’ content of the plastic fibers, especially at (1.5%) fibers.


Holzforschung ◽  
2006 ◽  
Vol 60 (6) ◽  
pp. 698-701 ◽  
Author(s):  
Zehui Jiang ◽  
Yan Yu ◽  
Daochun Qin ◽  
Ge Wang ◽  
Bo Zhang ◽  
...  

Abstract In situ imaging nanoindentation was used to characterize the mechanical properties of pure paint films on eight types of plywood-based flooring with different wear resistance. Correlation between the mechanical properties of paint films and the wear resistance of wood-based floorings was investigated. The average modulus of elasticity (MOE) and hardness of the paint film tested were 3.33–5.77 and 0.19–0.34 GPa, respectively. A strong linear relationship (r2=0.87) between the MOE and hardness of the paint film was found. Neither of these properties was directly correlated to the macro wear resistance of the floorings. Moreover, the composite index H1.5E-1– frequently used as an indicator of wear resistance in materials science – was not useful either in evaluating the wear resistance of wood floorings. However, in situ imaging nanoindentation was suitable for characterization of the mechanical properties of paint films, although this technique was not suited for direct evaluation of the wear resistance of wood floorings.


2020 ◽  
Vol 2020 ◽  
pp. 1-13
Author(s):  
Tuan Anh Nguyen ◽  
Thi Mai Huong Pham ◽  
Thi Huong Dang ◽  
Thi Hanh Do ◽  
Quang Tung Nguyen

The main purpose of this study is to complete the research process of dispersing nanoclay I.30E (montmorillonite) into epoxy Epikote 240 by mechanical method combined with energy-saving ultrasonic method. We investigate appropriate dispersion conditions such as stirring speed, mechanical stirring temperature, ultrasonic stirring time, and ultrasonic stirring capacity, which affect the mechanical properties and fire resistance of nanocomposite materials. The nanoclay contents studied were 1, 2, 3, and 4% by weight, and the methods used in this study are FE-SEM; XRD; and flame-retardant evaluation methods: LOI, UL 94HB. The mechanical properties were studied: tensile strength, flexural strength, compression strength, and impact resistance Izod. The dispersion method was recommended to stir mechanically at a speed of 3000 rpm at 80°C for 8 hours and then conduct ultrasonic vibrations for 6 hours at 65°C. The results showed that epoxy Epikote 240/nanoclay I.30E nanocomposite material had mechanical properties and improved fire retardancy with a small amount of nanoclay I.30E added (2% by weight): tensile strength of 63.5 MPa (increased by 13.59%), flexural strength of 116.80 MPa (increased by 34.63%), compressive strength of 179.67 MPa (increased by 15.11%), impact resistance Izod of 12.81 KJ/m2 (increased by 80.16%), oxygen limit of 23.7%, and combustion rate of 24.5 mm/min; according to UL 94HB, the combustion rate reached 22.59 mm/min.


2011 ◽  
Vol 12 (2) ◽  
pp. 131-144 ◽  
Author(s):  
Yusof Yusliza ◽  
Ahmad Zuraida

ABSTRACT : The effect of fiber content on mechanical properties and thermal stability of the cotton/albumen composites (CAC) were investigated and presented in this paper. The composites having 0%, 3%, 6%, 10%, 13 %, and 16% w/w of cotton fiber were considered.  Hands lay-up technique was used to prepare the CAC specimens and dried for 24 hours before characterised and evaluated for their mechanical performance. The structure and thermal stability of the composites were characterized by using x-ray and thermogravimetry analysis, respectively. The tensile strength and impact resistance of CAC are found maximum with the value of 8.7 MPa and 19.0 kJ/m2, respectively. Analysis on the morphological structure by SEM revealed that the mechanical properties of the composites depend on good wettability and adhesion between fiber/matrix.


2020 ◽  
Vol 12 (11) ◽  
pp. 4411
Author(s):  
Yao-Tang Hsu ◽  
Wen-Hsin Wang ◽  
Wei-Hsi Hung

According to Taiwan’s Ministry of the Interior, from 2017 to 2019, more than 12% of house-purchase disputes were due to water leakage caused by frequent tropical rains, which have long troubled engineers. The thermal stability resistance, water resistance, and ultraviolet resistance of existing polyurethane formulations have been limited by environmental aging. Thus, the lifespan of commercial PU-coated resins (typical PU) for the waterproofing of roof surfaces is merely two to three years. Accordingly, this study proposed the introduction of siloxane and imide groups to produce waterborne poly(urethane-siloxane-imide) (Si-imide-WPU) copolymers to improve the resistance of environmental aging in typical PU. The waterproof coating resin made of Si-imide-WPU copolymers was environmentally friendly, safe to use, and free of organic solvents. The results showed that the optimal Si-imide-WPU-2 sample in the study made improvements on the defects of polyurethane (PU) including its thermal properties, mechanical properties, environmental resistance, and lifespan which could be extended up to 5.4 years. Consequently, the studied Si-imide-WPU copolymers could reduce material waste while enhancing the sustainability and efficiency of the architecture.


2013 ◽  
Vol 315 ◽  
pp. 136-140 ◽  
Author(s):  
A.R. Azrin Hani ◽  
M. Mariatti ◽  
A. Roslan ◽  
Mohd Nazrul Roslan ◽  
A.R. Othman

This research work was concerned with the evaluation of mechanical properties; flexural strength and impact strength of coconut coir textile composites. The coir fabric reinforcement was in a form of woven and cross ply structure. The two types of laminates orientations for cross-ply structures were 0/90 degrees and 45/-45 degrees. Composites with fibre weight fraction of 30% were prepared by hand lay-up and vacuum bagging technique. Mechanisms of composites failure were examined using scanning electron microscopy (SEM). Results have shown that the woven coir reinforced composites exhibited higher impact resistance and flexural strength (warp woven) compare to cross-ply composites. Moreover, 0/90 degrees orientations demonstrated better strength performance compare to 45/-45 degrees. However, damage propagation on woven composites was found to be larger than cross-ply composites. Normality test of data distribution were evaluated using Minitab software and it was proven that all samples were in a very stable behaviour (p > 0.05). Experimental results were also validated using one way analysis of variance technique (one way-ANOVA) and it revealed there was statistically significant difference (p < 0.05) between all different fabric structures of coir fabric as reinforcement in composite.


2020 ◽  
Vol 2020 ◽  
pp. 1-8 ◽  
Author(s):  
Tuan Anh Nguyen

One of the main disadvantages of epoxy resins is brittleness and flammability, which is one of the biggest threats and the reason for limiting advanced applications. In this study, Epikote 240 (EP) epoxy resin was plasticized with epoxidized flaxseed oil (ELO) at different concentrations (EP/ELO ratios 95/5; 90/10; 85/15; 80/20; 75/25). Then, nanoclay additives and MWCNTs are simultaneously dispersed into the EP/ELO blend by using ultrasonic vibration. The dispersion of ELO and nanoclay additives (nanoclay and MWCNTs) in epoxy resin is observed by using the scanning electron microscope in combination with the XRD method. The effect of ELO, nanoadditives on mechanical properties, and flame retardants is assessed by tensile strength, flexural strength, compressive strength, impact resistance, UL 94HB method, and limiting oxygen index. Experimental results have shown that the mixing ratio of 90/10 w/w is the ratio for good compatibility, high mechanical properties, and fire retardation compared with other ratios. When adding MWCNTs as well as nanoclay I.30E to Epikote 240 epoxy, the mechanical strength and fire resistance have changed greatly: tensile strength of 85.45 MPa, flexural strength of 116.32 MPa, compressive strength of 189.25 MPa, impact resistance Izod of 24.37 kJ/m2, and fire resistance reached at V1.


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