Permeability variation in crystalline rocks due to low-grade solution phenomena

Permeability of crystalline rocks depends on parameters such as density and interconnectivity of fractures and pores. While in pristine crystalline rocks porosity is usually considered to be low, low-grade solution phenomena such as the formation of episyenites occur occasionally and may cause a local dramatic increase in porosity and permeability. These solution phenomena can be effective in otherwise unaltered rocks and may result in the preferential removal of certain mineral phases, especially of quartz so that porosities correspond to the spatial distribution of the previously existing mineral phase if no subsequent mineralization occurs (e.g., Pennacchioni et al., 2016). Using light-optical and scanning electron microscopy, X-ray tomography, micro-XRD, as well as digital image analysis, the differences in connectivity and hence permeability between, for example, quartz-depleted granite, gneiss, and schist can be characterized and quantified. We demonstrate that such porosities do not necessarily result in high permeabilities in an undeformed granodiorite from the Central Gneiss unit of the Tauern Window (Lago di Neves area, Italy), since former quartz aggregates are not interconnected due to their relatively late crystallization age and the preservation of the magmatic fabric; however, in the case of moderate mylonitic deformation, quartz as rheologically weak phase forms interconnected aggregates and layers. Its dissolution results in an extremely increased permeability. Therefore, not only the content and grain size but also the distribution, shape and alignment of minerals are crucial for rock permeability and need to be carefully investigated when searching for a final repository of highly radioactive waste in crystalline rocks. Especially since local shear zones may form in otherwise undeformed intrusive bodies, a detailed structural analysis beyond the exclusion of the presence of fractures is required to mitigate the risk of a long-lasting nuclear waste disposal.

Petrochronology of Monazite-Bearing Garnet Micaschists as a Tool to Decipher the Metamorphic Evolution of the Alpine Basement

Garnet-bearing metapelites in the Helvetic and Austroalpine pre-Mesozoic polymetamorphic basement are characterised by pressure-temperature path segments reconstructed by microstructurally controlled geothermobarometry, and the Th-U-Pb monazite age distribution pattern revealed by the electron probe microanalyser (EPMA). In the Helvetic Aiguilles Rouges Massif and the Austroalpine Oetztal-Stubai basement to the NW an Ordovician-to-Silurian high temperature event preceded a pressure-dominated Carboniferous metamorphism. In the Austroalpine basement units to the south of the Tauern Window, the maximal pressures of the Carboniferous amphibolite-facies metamorphism range from 12 to 6 kbar. The decompressional P-T path segments signal a transition to low pressure conditions. A subsequent high pressure overprint is restricted to the Prijakt Subgroup unit in the Schobergruppe and documented by Cretaceous monazite crystallisation at 88 ± 6 Ma. In the Austroalpine Saualpe basement to the SE, a distinct early Permian metamorphism which started at low pressures of ~4 kbar/500 °C and reached maximal 6 kbar/600–650 °C predated the intrusion of Permian pegmatites. Permian monazite crystallised in line with the intrusion of pegmatites. Corona microstructures around the Permian monazites indicate retrogression previous to a Cretaceous high pressure metamorphism. That way, pressure-temperature-time paths resolve the spatial and temporal evolution in the polymetamorphic Alpine basement prior to the Tertiary collision.

New constraints on the exhumation history of the western Tauern Window (European Alps) from thermochronology, thermokinematic modeling, and topographic analysis

The Brenner normal fault bounds the Tauern Window to the west and accommodated a significant portion of the orogen-parallel extension in the Eastern Alps. Here, we use zircon (U–Th)/He, apatite fission track, and apatite (U–Th)/He dating, thermokinematic modeling, and a topographic analysis to constrain the exhumation history of the western Tauern Window in the footwall of the Brenner fault. ZHe ages from an E–W profile (parallel to the slip direction of the fault) decrease westwards from ~ 11 to ~ 8 Ma and suggest a fault-slip rate of 3.9 ± 0.9 km/Myr, whereas AFT and AHe ages show no spatial trends. ZHe and AFT ages from an elevation profile indicate apparent exhumation rates of 1.1 ± 0.7 and 1.0 ± 1.3 km/Myr, respectively, whereas the AHe ages are again spatially invariant. Most of the thermochronological ages are well predicted by a thermokinematic model with a normal fault that slips at a rate of 4.2 km/Myr between ~ 19 and ~ 9 Ma and produces 35 ± 10 km of extension. The modeling reveals that the spatially invariant AHe ages are caused by heat advection due to faulting and posttectonic thermal relaxation. The enigmatic increase of K–Ar phengite and biotite ages towards the Brenner fault is caused by heat conduction from the hot footwall to the cooler hanging wall. Topographic profiles across an N–S valley in the fault footwall indicate 1000 ± 300 m of erosion after faulting ceased, which agrees with the results of our thermokinematic model. Valley incision explains why the Brenner fault is located on the western valley shoulder and not at the valley bottom. We conclude that the ability of thermokinematic models to quantify heat transfer by rock advection and conduction is crucial for interpreting cooling ages from extensional fault systems.

Re-Evaluation of the First Metamorphic P-T Path Using QuiG Barometry and Equilibrium Thermodynamics

Quartz in garnet (“QuiG”) barometry is a relatively new technique that uses physical properties of minerals to estimate the pressure of garnet nucleation and growth history independent of chemical equilibrium. QuiG barometry was used to determine pressures of garnet growth and compared to thermodynamically calculated P-T conditions for two samples (FH-1M and Z3H) from the Lower Shieferhülle (Formation), Tauern Window, Austria. FH-1M was the first sample for which a P-T path was calculated through inversion of chemical zoning in garnet (Selverstone et al., 1984). Mineral Assemblage Diagrams (MADs) and geothermobarometric techniques were used to determine P-T conditions for garnet nucleation and peak metamorphism. No MAD reproduced either the results of Selvserstone et al. (1984) or petrologic observations such as mineral assemblages and likely P-T conditions as determined using independent thermobarometers. Thermobarometrically calculated rim conditions were consistent between our study and previous work in the Lower Schieferhülle. However, without appropriate inclusion assemblages and compositions, the accuracy of calculated core P-T conditions could not be independently assessed using thermobarometry for either rock. QuiG isomekes from both samples are broadly consistent with growth of garnet during exhumation with heating as originally proposed by Selverstone et al. (1984). However, the QuiG isomekes for Z3H suggest that 90% or more of the Z3H garnet grew over small changes in pressure and temperature or along a QuiG isomeke (heating with a slight increase in pressure). These results support the accuracy of prior P-T paths and their tectonic interpretations. However, inconsistencies between QuiG barometry vs. thermodynamic calculations remain unresolved.

Geochemistry and paleogeographic implications of Permo-Triassic metasedimentary cover from the Tauern Window (Eastern Alps)

The chemical composition of metasediments is a valuable source of paleogeographic information about the protolith's sedimentary environment. Here, we compile major- and trace-element whole-rock data, including B contents, and 10/11B-isotope ratios from the Permo-Triassic metasedimentary cover of the Pfitsch–Mörchner basin, overlying the Variscan basement in the western Tauern Window, Eastern Alps (Austria and Italy). The basement consists of orthogneiss (“Zentralgneis”, metamorphosed Variscan granitoids with intrusion ages between 305 and 280 Ma), and the roof pendant consists of granites (amphibolites, paragneiss, and minor serpentinites). The Zentralgneis is partly hydrothermally altered into pyrite quartzite with high Al–S contents, low Na–Sr–Ca–Mg contents, and very strong depletion of the light rare earth elements. Comparison with published detailed mapping of this and other time-equivalent basins in the western Tauern Window, with radiometric age data in the literature, and with unmetamorphosed basins in the South Alpine realm yields a late Permian to Early Triassic age of sedimentation. Although during Alpine metamorphism all rocks were strongly deformed, the whole-rock chemical compositions of the metasediments were not pervasively changed during deformation. We show that the sediments were deposited in a small, probably lacustrine–fluviatile, intramontane basin, under arid to semi-arid climatic conditions. The sequence starts with metaconglomerates, which can be interpreted as a mixture of the different basement rocks, based on a combination of major-element ratios Na2O / (Na2O + K2O) and MgO / (MgO + Fe2O3) with concentrations of trace elements Cr, V, and Ni. The sequence is overlain by a fining-upwards sequence of clastic sediments, in which the behavior of K, Rb, and Sr allows the reconstruction of intense diagenetic K–B metasomatism, which raised the K2O contents up to ∼ 10 wt %. The average B content of 218 µg g−1 is well above the B content of common sediments, and the B-isotope composition reaches extremely low values of down to −33 ‰ δ11B. The top of the sequence is a lazulite quartzite, interpreted as a former conglomeratic phosphatic sandstone, which marks the transition from a closed Permian basin to an open Triassic basin. Within the clastic sequence, the presence of hydrothermal tourmalinite veins documents a hydrothermal event after deposition but before the onset of Alpine metamorphism. A metamorphosed mafic dike swarm in the orthogneiss indicates a post-Variscan event of basaltic magmatism, and this event is tentatively correlated with increased heat flow in the Triassic basin and hydrothermal activity. A consistent conceptual model of this basin and its diagenetic modifications, based on a combination of geochemical data with petrographical and field information, provides the geodynamic context of the European margin at the onset of the Alpine orogeny.

Contemporaneous opening of the Alpine Tethys in the Eastern and Western Alps: constraints from a Late Jurassic gabbro intrusion age in the Glockner Nappe, Tauern Window, Austria

Metabasic rocks of the ophiolitic sequences of the Glockner Nappe and Eclogite Zone in the south-central Tauern Window, Austria, reveal important insights into rifting and spreading of the Alpine Tethys. U–Pb dating of magmatic zircons yields a concordant 157 ± 2 Ma crystallization age for the precursor of a coarse-grained metagabbro from the Glockner Nappe. The Late Jurassic intrusion age is coeval with mafic plutonic activity in the Western and Central Alps. Although Penninic ophiolitic sequences in tectonic windows of the Eastern Alps are usually disrupted, an ocean–continent transition setting can be reconstructed for the Glockner Nappe, similar to many ophiolites in the Liguria–Piemont domain in the Western and Central Alps. Together, these observations strongly suggest a formation in the Liguria–Piemont branch of the Alpine Tethys and are inconsistent with a formation in the Valais domain. This finding has important implications for paleogeographic reconstructions of the Penninic realm in the Eastern Alps. Whereas the Glockner Nappe metagabbro and metabasalts clearly reveal their depleted mantle origin, the metabasic rocks of the Eclogite Zone record a more complex formation history involving depleted mantle melting and crustal assimilation in a continental margin setting.

Neogene kinematics of the Giudicarie Belt and eastern Southern Alpine orogenic front (northern Italy)

Neogene indentation of the Adriatic plate into Europe led to major modifications of the Alpine orogenic structures and style of deformation in the Eastern and Southern Alps. The Giudicarie Belt is a prime example of this, as it offsets the entire Alpine orogenic edifice; its activity has been kinematically linked to strike-slip faulting and lateral extrusion of the Eastern Alps. Remaining questions on the exact role of this fold-and-thrust belt in the structure of the Alpine orogen at depth necessitate a quantitative analysis of the shortening, kinematics, and depth of decoupling beneath the Giudicarie Belt and adjacent parts of the Southern Alps. Tectonic balancing of a network of seven cross sections through the Giudicarie Belt parallel to the local NNW–SSE shortening direction reveals that this belt comprises two kinematic domains that accommodated different amounts of shortening during overlapping times. These two domains are separated by the NW–SE-oriented strike-slip Trento-Cles–Schio-Vicenza fault system, which offsets the Southern Alpine orogenic front in the south and merges with the Northern Giudicarie Fault in the north. The SW kinematic domain (Val Trompia sector) accommodated at least ∼ 18 km of Late Oligocene to Early Miocene shortening. Since the Middle Miocene, this domain experienced at least ∼ 12–22 km shortening, whereas the NE kinematic domain accommodated at least ∼ 25–35 km shortening. Together, these domains contributed an estimated minimum of ∼ 40–47 km of sinistral strike-slip motion along the Northern Giudicarie Fault, implying that most offset of the Periadriatic Fault is due to Late Oligocene to Neogene indentation of the Adriatic plate into the Eastern Alps. Moreover, the faults linking the Giudicarie Belt with the Northern Giudicarie Fault reach ∼ 15–20 km depth, indicating a thick-skinned tectonic style of deformation. These fault detachments may also connect at depth with a lower crustal Adriatic wedge that protruded north of the Periadriatic Fault and are responsible for N–S shortening and eastward, orogen-parallel escape of deeply exhumed units in the Tauern Window. Finally, the E–W lateral variation of shortening across the Giudicarie Belt indicates internal deformation and lateral variation in strength of the Adriatic indenter related to Permian–Mesozoic tectonic structures and paleogeographic zones.

Moho topography beneath the European Eastern Alps by global-phase seismic interferometry

In this work we present the application of the global-phase seismic interferometry (GloPSI) technique to a dataset recorded across the Eastern Alps with the EASI (Eastern Alpine Seismic Investigation) temporary seismic network. GloPSI aims at rendering an image of the lithosphere from the waves that travel across the core before reaching the seismic stations (i.e. PKP, PKiKP, PKIKP). The technique is based on the principle that a stack of autocorrelations of transmission responses mimics the reflection response of a medium and is used here to retrieve information about the crust–mantle boundary, such as its depth and topography. We produce images of the upper lithosphere using 64 teleseismic events. We notice that with GloPSI, we can well image the topography of the Moho in regions where it shows a nearly planar behaviour and corresponds to a strong velocity contrast (i.e. in the northern part of the profile, from the Bohemian Massif to the Northern Calcareous Alps). Below the higher crests of the Alpine chain, and the Tauern Window in particular, we cannot find evidence of the boundary between crust and mantle. The GloPSI results indicate the absence of an Adriatic crust made of laterally continuous layers smoothly descending southwards and confirm the observations of previous studies suggesting a structurally complex and faulted internal Alpine crustal structure.