Atmospheric plasma reaction synthesised PtxFe1−x/graphene and TiO2 nanoparticles/graphene for efficient dye-sensitized solar cells

The DSSCs using a Pt0.7Fe0.3/G CE and TiO2 nanoparticles/G photoanode obtained a PCE of 10.13%.

WASTE CLASSIFICATION ASSESSMENT OF NUCLEAR STEELS FOR FUSION POWER APPLICATIONS

Fusion power is an attractive option for the world’s future energy needs. An important goal for fusion is to avoid the severe radioactive waste issues associated with nuclear fission. However, the neutrons produced in the fusion plasma reaction impinge on the surrounding reactor structure causing nuclear activation. It is hoped that activated material from fusion facilities can be disposed of as low level waste 50-100 years after operation ceases, but recent work suggests this may be difficult to achieve. This work presents inventory simulations for a number of potential fusion steels, for two neutron irradiation conditions typical of the DEMO reactor concept. The results are used to determine if the steels meet low level waste regulations, for a number of different international waste management systems. These results show that steels do not appear able to consistently meet low level waste requirements when exposed to near-plasma neutron fluxes. They have more success when exposed to lower fluxes, but traditional steels will still struggle to meet low level waste requirements in a fusion environment.

AlN PEALD with TMA and forming gas: study of plasma reaction mechanisms

Plasma effect on PEALD AIN growth rate follows a similar trend but shifts to longer plasma dose time when deposition temperature decreases.

Fabrication of Molybdenum Oxide/Activated Carbon Using Liquid Phase Plasma Reaction and Its Electrochemical Performance

In this study, molybdenum oxide/carbon nanocomposites (MOCNCs) were prepared by precipitating molybdenum oxide nanoparticles on activated carbon powder using liquid phase plasma process. The molybdenum oxide nanoparticles were impregnated on the AC surface and the amount impregnated was dependent on the concentration of the molybdenum precursor. MoO3 nanoparticles were predominantly precipitated and their size was about 20–80 nm. The specific capacitance of MOCNCs was increased with increasing the amount of molybdenum nanoparticles. Moreover, the resistances of MOCNCs were reduced than that of bare AC.

Higher Activity of Ni/γ-Al2O3 over Fe/γ-Al2O3 and Ru/γ-Al2O3 for Catalytic Ammonia Synthesis in Nonthermal Atmospheric-Pressure Plasma of N2 and H2

Developing a novel ammonia synthesis process from N2 and H2 is of interest to the catalysis and hydrogen research communities. γ-Alumina-supported nickel was determined capable of serving as an efficient catalyst for ammonia synthesis using nonthermal plasma under atmospheric pressure without heating. The catalytic activity was almost unrelated to the crystal structure and the surface area of the alumina carrier. The activity of Ni/Al2O3 was quantitatively compared with that of Fe/Al2O3 and Ru/Al2O3, which contained active metals for the conventional Haber–Bosch process. The activity sequence was Ni/Al2O3 > Al2O3 > Fe/Al2O3 > no additive > Ru/Al2O3, surprisingly indicating that the loading of Fe and Ru decreased the activity of Al2O3. The catalytic activity of Ni/Al2O3 was dependent on the amount of loaded Ni, the calcination temperature, and the reaction time. XRD, visual, and XPS observations of the catalysts before the plasma reaction indicated the generation of NiO and NiAl2O4 on Al2O3, the latter of which was generated upon high-temperature calcination. The NiO species was readily reduced to Ni metal in the plasma reaction, whereas the NiAl2O4 species was difficult to reduce. The catalytic behavior could be attributed to the production of fine Ni metal particles that served as active sites. The PN2/PH2 ratio dependence and rate constants of formation and decomposition of ammonia were finally determined for 5.0 wt% Ni/Al2O3 calcined at 773 K. The ammonia yield was 6.3% at an applied voltage of 6.0 kV, a residence time of reactant gases of 0.12 min, and PH2/PN2 = 1.

Tar Removal by Nanosecond Pulsed Dielectric Barrier Discharge

Plasma-catalytic reforming of simulated biomass tar composed of naphthalene, toluene, and benzene was carried out in a coaxial plasma reactor supplied with nanosecond high-voltage pulses. The effect of Rh-LaCoO3/Al2O3 and Ni/Al2O3 catalysts covering high-voltage electrode on the tar conversion efficiency was evaluated. Compared to the plasma reaction without a catalyst, the combination of plasma with the catalyst significantly enhanced the conversion of all three tar components, achieving complete conversion when an Rh-based catalyst was used. Apart from gaseous and liquid samples, char samples taken at five locations inside the reactor were also analyzed for their chemical composition. Char was not formed when the Rh-based catalyst was used. Different by-products were detected for the plasma reactor without a catalyst, with the Ni- and Rh-based catalysts. A possible reaction pathway in the plasma-catalytic process for naphthalene, as the most complex compound, was proposed through the combined analysis of liquid and solid products.