high impurity
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2021 ◽  
Author(s):  
Hang Si ◽  
Rui Ding ◽  
Ilya Y Senichenkov ◽  
Vladimir A Rozhansky ◽  
Pavel Molchanov ◽  
...  

Abstract One of the major challenges for the GW-class Chinese Fusion Engineering Testing Reactor (CFETR) is to efficiently handle huge power fluxes on plasma-facing components (PFCs), especially the divertor targets. This work investigates the effects of two candidate radiation impurity species, argon (Ar) and neon (Ne), with two different divertor geometries (baseline and long leg divertor geometry) on the reduction of steady-state power load to divertor targets in CFETR by using the SOLPS-ITER code package with full drifts and kinetic description of neutrals. The modeling results show clearly that increasing the seeding rate of Ar or Ne with fixed fueling gas D2 injection rate reduces the target electron temperature and heat flux density for the baseline divertor geometry, which can be reduced further by higher D2 injection rate. With a high impurity seeding rate, partial detachment with steady-state power load at the divertor target below the engineering limit of 10 MWm-2 is demonstrated. In addition, the radiation efficiency for Ar is better than that for Ne. Increasing the divertor leg length reduces the electron temperature and heat load at the targets. This modeling, therefore, suggests that a long leg divertor design with Ar seeding impurity is appropriate to meet the CFETR divertor requirements.



PLoS ONE ◽  
2021 ◽  
Vol 16 (6) ◽  
pp. e0252376
Author(s):  
Heide W. Nørgaard ◽  
Ernst Pernicka ◽  
Helle Vandkilde

Based on 550 metal analyses, this study sheds decisive light on how the Nordic Bronze Age was founded on metal imports from shifting ore sources associated with altered trade routes. On-and-off presence of copper characterised the Neolithic. At 2100–2000 BC, a continuous rise in the flow of metals to southern Scandinavia begins. First to arrive via the central German Únětician hubs was high-impurity metal from the Austrian Inn Valley and Slovakia; this was complemented by high-tin British metal, enabling early local production of tin bronzes. Increased metal use locally fuelled the leadership competitions visible in the metal-led material culture. The Únětice downfall c.1600 BC resulted for a short period in a raw materials shortage, visible in the reuse of existing stocks, but stimulated direct Nordic access to the Carpathian basin. This new access expedited innovations in metalwork with reliance on chalcopyrite from Slovakia, as well as opening new sources in the eastern Alps, along an eastern route that also conveyed Baltic amber as far as the Aegean. British metal plays a central role during this period. Finally, from c.1500 BC, when British copper imports ceased, the predominance of novel northern Italian copper coincides with the full establishment of the NBA and highlights a western route, connecting the NBA with the southern German Tumulus culture and the first transalpine amber traffic.



2021 ◽  
Author(s):  
Mangmang Gao ◽  
Xu Zhao ◽  
Ang Gao ◽  
Rui Li ◽  
Wenyu Chen ◽  
...  

Abstract Solvent refining with Al-Si alloy is a promising purification method for production of solar-grade silicon (SoG-Si) feedstock owing to the advantages of low production cost and high impurity removal efficiency. In this process, larger refined Si primary dendrites are easily collected after acid leaching, which is favorable to recovery, thereby to reduce the production cost. Hence, the growth behavior of the precipitated Si crystal must be investigated systematically. In present work, the morphology evolution of solidified Al-Si alloys with a wide range of Si content (30~70 wt.%) was analyzed. The typical plate-like Si primary dendrites grown following the twin plane re-entrance edge (TPRE) mechanism formed in all alloy compositions. As increasing the Si content from 30 wt.% to 50 wt.%, the Si primary dendrites underwent a coarsening process attributed to the preferred growth along <211> and <111> directions, leading to an increase in the experimental recovery rate. However, the preferred growth along <211> direction was inhibited when the Si content is higher than 55 wt.%. Moreover, the broken effect originating from grain collision and thermal stress on the Si primary dendrites was enhanced as further increasing the Si content, resulting in a decrease in the experimental recovery rate. Therefore, the optimum composition is determined as Al-50~55 wt.% Si for solvent refining solution, based on the cost reduction consideration.



2021 ◽  
Vol 289 ◽  
pp. 07020
Author(s):  
Zlixa Saparniyazova ◽  
Temur Ismaylov ◽  
Gulnaza Abdireymova ◽  
Gulnaz Turmanova ◽  
T Kh Hakimov

In works [1-4], it was shown that a number of new physical phenomena are observed in silicon with nanoclusters, such as high-temperature negative magnetoresistance (NMR), anomalously high impurity photoconductivity, giant residual photoconductivity, etc. All these phenomena are directly related to the presence of multiply charged, magnetic clusters of manganese atoms in the silicon lattice. It is shown that, on the basis of such materials, it is possible to create fundamentally new, highly sensitive magnetosensors, photodetectors of infrared radiation operating in the μm region and photomagnetic devices.



Author(s):  
Ganesan Dharmalingam ◽  
Murali Arun Prasad ◽  
Sachin Salunkhe

The oxide dispersion strengthened (ODS) ferritic steels are one of the most important in fuel cladding materials for 4th Generation nuclear reactors because of their excellent mechanical properties such as irradiation resistance, swelling resistance, and elevated temperature tensile/compressive strength. Mechanical alloying (MA) is one of the most promising routes for developing nanocrystalline ferritic ODS steel materials. For the production of nanocrystalline ferritic ODS steel powders, the most influencing factor is the milling speed and milling time during the mechanical alloying process. With the improper selection of milling time and speed, the final milled powders become an amorphous structure consisting of high impurity inclusions in the microstructure, and strength was also affected. In order to overcome these drawbacks, the present investigation was taken into account for the selection of appropriate mechanical milling speed and time, which was optimized through Taguchi analysis followed by the MA process. The optimized mechanical milling speed and time of milled powders were characterized through X-Ray Diffraction Analysis (XRD) and Scanning Electron Microscope (SEM).



Solar Energy ◽  
2021 ◽  
Vol 214 ◽  
pp. 86-92
Author(s):  
Chung-Yu Li ◽  
Yin-Song Liao ◽  
Diksha Thakur ◽  
Anjali Chandel ◽  
Shou-En Chiang ◽  
...  


2021 ◽  
Vol 288 ◽  
pp. 01013
Author(s):  
Yokub Ergashov ◽  
Boltaxodja Umirzakov ◽  
Nebodir Nurmatov ◽  
Golib Otamurodov

The paper studies the effect of disordering of the surface layers on the electronic and optical properties of single-crystal silicon.An analysis of the photoelectron spectra shows that with complete amorphization of the surface density, the condition of Si valence electrons of changes significantly. In particular, the positions of the main maximum of the electrons of the valence band of Si (111) shift by ~ 0.4 eV towards higher binding energies and the band gap Eg increases by 0.1-0.15 eV. The energy of a valence electron in amorphized silicon, which at low impurity concentrations, i.e. at low bombardment doses (D <1015 cm–2), the potential Mkk and, therefore, the shift of the maximum of the density of states vary linearly with respect to concentration. At high impurity concentrations (at doses D> 1015 cm–2), corresponding to the transition to amorphous silicon, the concentration dependence of Mkk is very weak. Therefore, upon amorphization, the peak A of the density of states of the silicon valence band under consideration is shifted to the region of lower electron binding energies. The theoretical substantiation of the obtained experimental results is given.



2020 ◽  
Vol 1004 ◽  
pp. 265-271 ◽  
Author(s):  
Daiki Tanaka ◽  
Wei Fang Lu ◽  
Satoshi Kamiyama ◽  
Motoaki Iwaya ◽  
Tetsuya Takeuchi ◽  
...  

The dependence of optical properties on impurity concentrations and excitation power was explored. In particular, it was found that the peak shift of photoluminescence (PL) is proportional to the boron concentration. This might be due to donor–acceptor pair (DAP) recombination via double deep acceptor levels (D-centers), where the occupancy of the D*-center increased with the B concentration, and the recombination via the D*-center for longer wavelengths became dominant. Moreover, the relative constants B and C were calculated by BC model fitting from the internal quantum efficiency (IQE) curve as a function of excitation power. The theoretical extrapolation based on BC model predicted that high impurity concentrations are sufficient to suppress the droop phenomenon of efficiency induced by the increased excitation power.



2018 ◽  
Vol 58 (1) ◽  
Author(s):  
Adam Wincukiewicz ◽  
Wojciech Mech ◽  
Sylwia Grankowska ◽  
Agnieszka Wolos ◽  
Aneta Drabinska ◽  
...  

We present selected semiconductor (inorganic and organic) structures for which non-radiative recombination of excess charge carriers is very high, luminescence suppressed and its lifetime substantially shortened. Processes competitive with radiative energy emission are discussed. The importance of Shockley–Read–Hall recombination in materials with high impurity or defect concentration, applied in ultrafast devices, is shown. Also, charge transfer process in solar cells is discussed in the context of luminescence quenching of individual components of an active layer. A part of the shown research was a subject of our common work with Prof. Arūnas Krotkus during the period from 1994 till 2006.



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