APLICAÇÕES E IMPLICAÇÕES DO OZÔNIO NA INDÚSTRIA, AMBIENTE E SAÚDE

OZONE APPLICATIONS AND IMPLICATIONS FOR INDUSTRY, ENVIRONMENT, AND HEALTH. Stratospheric ozone is an efficient filter for ultraviolet radiation, which damages organisms’ lives exposed to sunlight. In the troposphere, ozone is essential to oxidate volatile organic compounds, but its effects are harmful to animals and plants, particularly humans. The high reactivity of ozone with some organic compounds makes it a promising agent for several applications, such as microbiological control and the medical field. However, their contact with surfaces containing unsaturated substances and other compounds can result in the formation of products that are harmful to human health or distort the organoleptic and structural properties of food. The results available in the literature are often divergent as to their safety and economic viability. Despite this, there are many cases of dermatological applications, and as sanitizing agents in several environments. Antiviral and bactericide properties were that guided the expansion of ozone application in the current coronavirus pandemic (COVID-19). However, more studies should be carried out to comprove its effectiveness, considering possible damages resulting from these applications.

Stratosphere–Troposphere Exchange and O3 Variability in the Lower Stratosphere and Upper Troposphere over the Irene SHADOZ Site, South Africa

This study aims to investigate the Stratosphere-Troposphere Exchange (STE) events and ozone changes over Irene (25.5° S, 28.1° E). Twelve years of ozonesondes data (2000–2007, 2012–2015) from Irene station operating in the framework of the Southern Hemisphere Additional Ozonesodes (SHADOZ) was used to study the troposphere (0–16 km) and stratosphere (17–28 km) ozone (O3) vertical profiles. Ozone profiles were grouped into three categories (2000–2003, 2004–2007 and 2012–2015) and average composites were calculated for each category. Fifteen O3 enhancement events were identified over the study period. These events were observed in all seasons (one event in summer, four events in autumn, five events in winter and five events in spring); however, they predominantly occur in winter and spring. The STE events presented here are observed to be influenced by the Southern Hemisphere polar vortex. To strengthen the investigation into STE events, advected potential vorticity maps were used, which were assimilated using Modélisation Isentrope du transport Méso–échelle de l’Ozone Stratosphérique par Advection (MIMOSA) model for the 350 K (~12–13 km) isentropic level. These maps indicated transport of high latitude air masses responsible for the reduction of the O3 mole fractions at the lower stratosphere over Irene which coincides with the enhancement of ozone in the upper troposphere. In general, the stratosphere is dominated by higher Modern Retrospective Analysis for Research Application (MERRA-2) potential vorticity (PV) values compared to the troposphere. However, during the STE events, higher PV values from the stratosphere were observed to intrude the troposphere. Ozone decline was observed from 12 km to 24 km with the highest decline occurring from 14 km to 18 km. An average decrease of 6.0% and 9.1% was calculated from 12 to 24 km in 2004–2007 and 2012–2015 respectively, when compared with 2000–2003 average composite. The observed decline occurred in the upper troposphere and lower stratosphere with winter and spring showing more decline compared with summer and autumn.

Stratosphere–Troposphere Exchange and O3 Decline in the Lower Stratosphere over Irene SHADOZ Site, South Africa

This study aims to investigate the Stratosphere-Troposphere Exchange (STE) events and ozone trends over Irene (25.5°S, 28.1°E). Twelve years of ozonesondes data (2000–2007, 2012–2015) from Irene station operating in the framework of the Southern Hemisphere Additional Ozonesodes (SHADOZ) was used to study the troposphere (0–16 km) and stratosphere (17– 28 km) ozone (O3) vertical profiles. Ozone profiles were grouped into three categories (2000–2003, 2004–2007 and 2012–2015) and average composites were calculated for each category. Fifteen O3 enhancement events were identified over the study period. These events were observed in all seasons (one event in summer, four events in autumn, five events in winter and five events in spring), however, they predominantly occur in winter and spring. The STE events presented here are observed to be influenced by the Southern Hemisphere polar vortex. During the STE events, the advected potential vorticity maps assimilated using Modélisation Isentrope du transport Méso–échelle de l’Ozone Stratosphérique par Advection (MIMOSA) model for the 350 K (~12–13 km) isentropic level indicated a transport of high latitude air masses which seems to be responsible for the reduction of the O3 mole fractions at the lower stratosphere over Irene which takes place at the same time with the enhancement of ozone in the upper troposphere. In general, the stratosphere is dominated by higher Modern Retrospective Analysis for Research Application (MERRA-2) potential vorticity (PV) values compared to the troposphere. However, during the STE events, higher PV values from the stratosphere were observed to intrude the troposphere. Ozone decline was observed from 12 km to 24 km with highest decline occurring from 14 km to 18 km. An average decrease of 6.0 and 9.1% was calculated from 12 to 24 km in 2004–2007 and 2012–2015 respectively. The observed decline occurred in the upper troposphere and lower stratosphere with winter and spring showing more decline compared with summer and autumn.

Investigate Wildfire Impacts on Ozone Production by Vertical Observations and Photochemical Modeling

In troposphere, ozone is a toxic secondary pollutant produced when its precursors react in sunlight. An important source of ozone precursors is biomass burning. Here we investigate the impacts of 2016 Southeast U.S. Wildfires on ozone production by integrating vertical resolved ozone profiles and photochemical modeling. The results show that wildfires contributed to ozone lamina at the top of boundary layer and enhanced surface ozone up to about 10ppbv in Southeast U.S.. Ozone lidar observed a lower ozone change with respect to a fast growth of aerosol plume, of which the reason is also investigated. Current results indicate an effective integration of vertical observations and modeling for us to understand the ozone production from fires in troposphere.

Future changes in the stratosphere-to-troposphere ozone mass flux and the contribution from climate change and ozone recovery

Model simulations consistently project an increase in the stratosphere-troposphere exchange (STE) of ozone in the future. Both, a strengthened circulation and ozone recovery in the stratosphere contribute to the increased mass flux. In our study, we investigate with a state-of-the-art chemistry-climate model the drivers of future STE change as well as the change in the distribution of stratospheric ozone in the troposphere. Our focus is on the investigation of the changes on the monthly scale. The global mean influx of stratospheric ozone into the troposphere is projected to increase between the years 2000 and 2100 by 53 % under the RCP8.5 greenhouse gas scenario. We find the largest increase of STE in the NH in June due to increasing greenhouse gas (GHG) concentrations. In the SH the GHG effect is dominating in the winter months, while decreasing levels of ozone depleting substances (ODS) and increasing GHG concentrations contribute nearly equally to the increase in SH summer. A large ODS-related ozone increase in the southern hemisphere (SH) stratosphere leads to a change in the seasonal breathing term which results in a future decrease of the ozone mass flux into the troposphere in the SH in September and October. We find that the GHG effect on the STE change is due to circulation and stratospheric ozone changes, whereas the ODS effect is dominated by the increased ozone abundance in the stratosphere. The resulting distributions of stratospheric ozone in the troposphere for the GHG and ODS changes differ because of the different regions of ozone input (GHG: midlatitudes; ODS: high latitudes) and the larger increase of tropospheric ozone loss rates due to GHG increase. Thus, the model simulations indicate that stratospheric ozone is more efficiently mixed to lower levels if only ODS levels are changed. The increase of the stratospheric ozone column in the troposphere explains more than 80 % of the tropospheric ozone trend in NH spring and in the SH except for the summer months. The importance of the future stratospheric ozone contribution to tropospheric ozone burdens therefore depends on the season.

Impact of nitrate ammonium and calcium (CAN27%) on the environment.

In this research, a detailed study for energy consumption levels evaluation and environmental impacts assessment in the fertilizers production sector in Algeria was achieved. An analysis of the various inputs and outputs to the process to identify different sources of pollution throughout the life cycle of fertilizer was used. One product is making the subject in this study; CAN 27% N. The flows of material and energy for each phase of the life cycle were counted and the associated environmental problems were identified. The analysis was conducted according to the LCA standards ISO (International Standard Organization) 14040 series and the impacts categories studied are Global Warming Potential, Acidification Potential, Troposphere Ozone Precursor Potential, and Resources use. The results show that Cumulative Energies Requirement and GHG emission in Algerian fertilizers production process are significant. Ammonia plant use 82% of total natural gas that is consumed by fertilizer manufactory. Production of ammonia per year requires 4,506.107MJ of electricity and 2,059.108of natural gas and generates 1.82 T CO2 eq. (equivalent).