PEA Electromagnetic Distortion Reduction by Impedance Grounding and Pulsed Voltage Electrode Configurations

Space charges are one of the main challenges facing the constantly increasing use of extruded high voltage direct current (HVDC) cables. The Pulsed Electro-Acoustic (PEA) method is one of the most common procedures for space charge measurements of insulation. One issue with the PEA method is distortion due to the crosstalk between the applied voltage pulse and the acoustic sensor. This work analyzed two factors involved in the reduction in this distortion: the influence of the exposed semiconductor distance between the injection electrodes and PEA test cell, and the influence of adding a reactance at the grounding circuit of the PEA test cell. The interaction of these two factors with the distortion was analyzed through a series of experimental testing. Moreover, the performance regarding distortion after applying a developed coaxial injection was compared with the standard non-coaxial injection configuration. It was observed that these two factors had a direct impact on distortion and can be utilized for the reduction in distortion arising from the crosstalk of the applied pulsed voltage. The results can be utilized for the consideration of practical aspects during the construction of a PEA test setup for the measurement of full-size HVDC cables.

Functionalized Silicon Electrodes Toward Electrostatic Catalysis

Oriented external electric fields are now emerging as “smart effectors” of chemical changes. The key challenges in experimentally studying electrostatic catalysis are (i) controlling the orientation of fields along the reaction axis and (ii) finely adjusting the magnitudes of electrostatic stimuli. Surface models provide a versatile platform for addressing the direction of electric fields with respect to reactants and balancing the trade-off between the solubility of charged species and the intensity of electric fields. In this mini-review, we present the recent advances that have been investigated of the electrostatic effect on the chemical reaction on the monolayer-functionalized silicon surfaces. We mainly focus on elucidating the mediator/catalysis role of static electric fields induced from either solid/liquid electric double layers at electrode/electrolyte interfaces or space charges in the semiconductors, indicating the electrostatic aspects is of great significance in the semiconductor electrochemistry, redox electroactivity, and chemical bonding. Herein, the functionalization of silicon surfaces allows scientists to explore electrostatic catalysis from nanoscale to mesoscale; most importantly, it provides glimpses of the wide-ranging potentials of oriented electric fields for switching on/off the macroscale synthetic organic electrochemistry and living radical polymerization.

Localized Deep and Shallow Traps of α-Peaks from Thermally Stimulated Current (TSC) Measurement on Thermoplastic Polymers

In this paper, trap levels around the glass transition temperature (Tg) of polymers have been characterized using Thermally Stimulated Current (TSC) technique. Deconvolution on α-peaks of the Tg for PE (-104 °C), plasticized PVC (-35 °C), PMMA (90 °C) and PET (96 °C) were carried out based on the first-order kinetic theory for non-Debye relaxation. Using temperature, T from TSC experimental data, we have successfully separated the α-peaks of the thermoplastic polymers. It is found that the complex curve of α-peaks can composed of four (4) to eight (8) sub peaks. Dominant sub peaks were identified at Tmax = -105 °C, -34 °C, 89 °C and 92 °C for PE, pPVC, PMMA and PET, respectively. These peaks show activation energy, Ea of shallow and deep trap centers ranged from 0.3 eV to 4.6 Ev where they represent the depolarization of localized dipoles and space charges relaxations in the polymers.

Direct observation of nanoscale dynamics of ferroelectric degradation

Failure of polarization reversal, i.e., ferroelectric degradation, induced by cyclic electric loadings in ferroelectric materials, has been a long-standing challenge that negatively impacts the application of ferroelectrics in devices where reliability is critical. It is generally believed that space charges or injected charges dominate the ferroelectric degradation. However, the physics behind the phenomenon remains unclear. Here, using in-situ biasing transmission electron microscopy, we discover change of charge distribution in thin ferroelectrics during cyclic electric loadings. Charge accumulation at domain walls is the main reason of the formation of c domains, which are less responsive to the applied electric field. The rapid growth of the frozen c domains leads to the ferroelectric degradation. This finding gives insights into the nature of ferroelectric degradation in nanodevices, and reveals the role of the injected charges in polarization reversal.

Corona point discharges from grounded rods under high background electric field

<p>During the formation of thunderclouds, simultaneous macrophysical and microphysical processes cause the separation of charges inside the cloud, forming the electrical structure of storm clouds. As a result of that, the electric field at the ground level can change significantly. Irregularities on the surfaces of grounded structures can provide conditions for corona discharges that generate ions and form a space charge layer at ground level.</p><p>In this work, we investigate the features of corona point discharges from grounded conductive rods installed in three different sites. In all of them, we measured current along the grounded rod under high background electric field conditions or during its fast changes caused by lightning strikes. The current signals reveal pulses with a fast rise time (tens of nanoseconds) and slow decay (hundreds of nanoseconds), with polarity compatible with the background electric field. Comparing laboratory experiments with the results in the field, we observed that positive discharges required a lower electric field threshold than negative discharges. Their pulse frequency is also equivalent to one-tenth of the pulse frequency of negative discharges, for a similar electric field level.</p><p>In one of the sites, one current sensor coupled to a grounded rod, 1.5 m above a roof, was installed in a site located at an altitude of 2525 m, near a ski-station. We observed a large number of events, and we were able to correlate the frequency of the pulses with the electric field, as well as evaluate the effect of the wind on the discharges. In the other two sites, the rods were placed near the ground and on the roof of a conventional building. Pulses were registered on some occasions when there was lightning activity nearby, either before or after lightning events. Previous works on this topic correlate the electric field with the average current flow, and on this work, we evaluate the pulse frequency and electric field. This investigation is relevant for understanding the production of corona and space charges from high structures.</p>

SPECTRA OF THERMOSTIMULATED DEPOLARIZATION OF BIOCOMPOSITES WITH FILLERS OF BIOLOGICAL ORIGIN

The paper presents the results of studying the spectra of thermally stimulated depolarization of high-pressure polyethylene modified with fillers of biocomposites with fillers of biological origin - fish bone and fish scales. It was revealed that the stability and surface density of space charges can be controlled by varying the volumetric content of biological fillers. The optimal values of bio-fillers that contribute to the stability of the surface density of the studied biocomposites have been determined.

EFFECT OF TEMPERATURE TREATMENT ON THE ENERGY SPECTRUM OF DEFECTS IN SILICON DOPED WITH MOLYBDENUM

The paper presents the results of studying the spectra of thermally stimulated depolarization of high-pressure polyethylene modified with fillers of biocomposites with fillers of biological origin - fish bone and fish scales. It was found that the stability and surface density of space charges can be controlled by varying the volumetric content of biological fillers. The optimal values of bio-fillers that contribute to the stability of the surface density of the investigated biocomposites have been determined.