scholarly journals Preparation and Characterization of a Novel Activated Carbon@Polyindole Composite for the Effective Removal of Ionic Dye from Water

Polymers ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 3
Author(s):  
Bushra Begum ◽  
Saba Ijaz ◽  
Rozina Khattak ◽  
Raina Aman Qazi ◽  
Muhammad Sufaid Khan ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Oxidative Polymerization ◽  
Dye Adsorption ◽  
Kinetic Studies ◽  
Isotherm Model ◽  
Point Of Zero Charge ◽  
Potential Candidate ◽  
Operational Parameters ◽  
X Ray ◽  
Effective Removal

The present study is aimed at the synthesis and exploring the efficiency of a novel activated carbon incorporated polyindole (AC@PIN) composite for adsorptive removal of Malachite Green (MG) dye from aqueous solution. An AC@PIN hybrid material was prepared by in situ chemical oxidative polymerization. The physico-chemical characteristics of the AC@PIN composite were assessed using Fourier-transform infrared spectrometer, X-ray diffraction, scanning electron microscopy, energy dispersive X-ray spectroscopy, ultraviolet visible spectroscopy, and determination of point of zero charge (pHPZC). A series of adsorption studies was conducted to evaluate the influence of operational parameters such as pH, contact time, initial dye concentration, AC@PIN dosage, and temperature on dye adsorption behavior of developed composite. A maximum dye removal percentage (97.3%) was achieved at the pH = 10, AC@PIN dosage = 6.0 mg, initial dye concentration 150 mg L−1, and temperature = 20 °C. The kinetic studies demonstrated that the adsorption of MG on AC@PIN followed pseudo-second-order model (R2 ≥ 0.99). Meanwhile, Langmuir isotherm model was founded to be the best isotherm model to describe the adsorption process. Finally, the recyclability test revealed that the composite exhibits good recycle efficiency and is stable after 5 cycles. The obtained results suggest that AC@PIN composite could be a potential candidate for the removal of MG from wastewater.

A Novel Hydroxyapatite Carrier for Enrichment of Hydrocarbon Degradation Bacteria

2007 ◽  
Vol 336-338 ◽  
pp. 1914-1917
Author(s):  
Lei Yang ◽  
Zhen Yi Zhang ◽  
Xiao Shan Ning ◽  
Guang He Li
Keyword(s):  
Activated Carbon ◽  
Sol Gel ◽  
Hydrocarbon Degradation ◽  
Potential Candidate ◽  
X Ray Diffraction ◽  
X Ray ◽  
Bacterial Enrichment ◽  
Bet Method ◽  
The One ◽  
Scanning Electron

In this paper, a novel and highly efficient hydroxyapatite (HA) carrier for cultivating hydrocarbon degradation bacteria (HDB) is introduced. The HA particles synthesized through a sol-gel method and different heat treatments were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and BET method. The microbial amount and activities of HDB cultivated on HA carriers were quantitatively investigated in order to assess their enriching capabilities. The results showed that HA synthesized at 550°C and the one without calcination could enrich HDB 3 and 2 magnitude orders more than the activated carbon, respectively. Mechanisms of bacterial enrichment on HA and activated carbon were also studied, and it is believed that the high bioactivity and the surface morphology of HA were responsible for the efficient reproduction of HDB. It is concluded that HA is a potential candidate to replace the conventionally used activated carbon as a novel carrier applied in the filed of bioremediation for oil contaminated soil.

scholarly journals Comparison of Surface and Structural Properties of Carbonaceous Materials Prepared by Chemical Activation of Tomato Paste Waste: The Effects of Activator Type and Impregnation Ratio

2016 ◽  
Vol 2016 ◽  
pp. 1-10 ◽  
Author(s):  
Nurgul Ozbay ◽  
Adife Seyda Yargic
Keyword(s):  
Activated Carbon ◽  
Activated Carbons ◽  
Low Cost ◽  
Chemical Activation ◽  
Nitrogen Adsorption ◽  
Xrd Analysis ◽  
Point Of Zero Charge ◽  
Activation Process ◽  
X Ray ◽  
Tomato Paste

Activated carbons were prepared by carbonization of tomato paste processing industry waste at 500°C followed by chemical activation with KOH, K2CO3, and HCl in N2 atmosphere at low temperature (500°C). The effects of different activating agents and impregnation ratios (25, 50, and 100 wt.%) on the materials’ characteristics were examined. Precursor, carbonized tomato waste (CTW), and activated carbons were characterized by using ultimate and proximate analysis, thermogravimetric analysis (TG/DTG), Fourier transform-infrared (FT-IR) spectroscopy, X-ray fluorescence (XRF) spectroscopy, point of zero charge measurements (pHPZC), particle size analyzer, scanning electron microscopy (SEM), energy dispersive X-ray (EDX) spectroscopy, nitrogen adsorption/desorption isotherms, and X-ray diffraction (XRD) analysis. Activation process improved pore formation and changed activated carbons’ surface characteristics. Activated carbon with the highest surface area (283 m3/g) was prepared by using 50 wt.% KOH as an activator. According to the experimental results, tomato paste waste could be used as an alternative precursor to produce low-cost activated carbon.

scholarly journals Photocatalytic degradation of malachite green dye using zero valent iron doped polypyrrole

2021 ◽  
Vol 27 (2) ◽  
pp. 200638-0
Author(s):  
Bircan HASPULAT TAYMAZ ◽  
Handan KAMIŞ ◽  
Özge YOLDAŞ
Keyword(s):  
Malachite Green ◽  
Uv Light ◽  
Irradiation Time ◽  
Oxidative Polymerization ◽  
Zero Valent Iron ◽  
Point Of Zero Charge ◽  
Light Illumination ◽  
X Ray ◽  
Malachite Green Dye ◽  
Iron Doped

The zero valent iron doped polypyrrole (Ppy/Fe) was synthesized via chemical oxidative polymerization method in diethylene glycol medium for the first time in this study. The characterization of synthesized Ppy and Ppy/Fe composites was realized by using fourier transform infrared spectrometer (FTIR), UV-visible diffuse reflectance spectrometer (DRS), scanning electron microscope (SEM), elemental dispersion X-ray analysis (EDX), four point probe electrical conductivity X-Ray diffraction spectroscopy (XRD) and pH at point of zero charge (pHpzc) methods. These characterizations show that there is an interaction between zero valent iron (Fe0) and Ppy polymer. The photocatalytic activity of synthesized Ppy and Ppy/Fe composite were investigated by degradation of malachite green (MG) dye under UV light irradiation. Ppy/Fe composite was achieved complete degradation within 60 min, which is 5.92 times faster than pure Ppy. The effect of irradiation time, ratio of Ppy and Fe0 in the synthesized composites, photocatalyst amount to photocatalytic efficiency of Ppy/Fe is studied. Also, the photocatalytic stability of Ppy/Fe is investigated under UV light illumination for degradation MG dye.

Adsorption of Pb(ll) on Activated Carbon Treated by Nitric Acid

2012 ◽  
Vol 550-553 ◽  
pp. 2190-2193
Author(s):  
Xiao Yan Tan ◽  
Fang Zhao ◽  
Rui Zhi Wen ◽  
Yu Dai
Keyword(s):  
Activated Carbon ◽  
Nitric Acid ◽  
Photoelectron Spectroscopy ◽  
Adsorption Process ◽  
Point Of Zero Charge ◽  
Acidic Ph ◽  
N2 Adsorption ◽  
X Ray ◽  
Boehm Titration ◽  
Carboxylic Groups

Commercially available coal-based activated carbon was treated with different concentration of nitric acid. The resultant samples were used to adsorb lead from aqueous solution. N2 adsorption, Boehm titration, point of zero charge (pHPZC) and X-ray photoelectron spectroscopy (XPS) were used to characterize the samples. Acidic pH is favorable for Pb(Ⅱ) adsorption. The acidic groups increase significantly with the increment of the concentration of nitric acid during the treatment. The carboxylic groups of surface carbon play an important role in the adsorption process.

Effective removal of tetracycline from water by batch method using activated carbon, magnetic carbon nanocomposite, and membrane hybrid technology

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Muhammad Wahab ◽  
Muhammad Zahoor ◽  
Syed Muhammad Salman ◽  
Sumaira Naz
Keyword(s):  
Activated Carbon ◽  
Entropy Change ◽  
Permeate Flux ◽  
X Ray ◽  
Stirred Reactor ◽  
Effective Removal ◽  
In Series ◽  
Ultra Filtration ◽  
Pseudo Second Order ◽  
Adsorbent Dose

Abstract In this study two adsorbents (activated carbon; AC and magnetic activated carbon; MCN) were prepared from Dalbergia sissoo sawdust and used as potential adsorbents for the removal of tetracycline (TC) from water. Both the adsorbents were characterized by instrumental techniques like energy dispersive x-ray (EDX), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR), x-ray diffraction (XRD), surface area analyzer and thermal gravimetric/Differential thermal analysis (TG/DTA). The effect of antibiotic initial concentration, contact-time, pH, adsorbent-dose, and temperature were evaluated to determine optimum adsorption conditions. The optimum TC concentration for both AC and MCN was 120 mg/L while optimum time of saturation for both adsorbents was 120 min. The optimum pH determined was five while optimum adsorbent dose was 0.1 g. The adsorption isothermal data of both sets of experiments was best explained by Langmuir model. The kinetic data was well explained by pseudo-second order kinetics model. The ΔH° (enthalpy change) and ΔSo (entropy change) were; −14.989 and 25.174 kJ/mol for AC and −11.628 and 51.302 kJ/mol for MCN respectively. The values of Gibbs free energy (ΔG°) calculated for AC were 7.36, −7.99, −7.36, −7.61, and −8.12 kJ/mol while for MCN these were −15.02, −15.53, −16.05, −16.56, and −17.07 kJ/mol corresponding to temperatures; 298, 303, 313, 323, and 333 K. To control fouling in ultra-filtration, nano-filtration, and reverse osmosis membranes caused by TC, and both adsorbents, a continuous stirred reactor was connected in series with membrane pilot plant. The improvement brought about by both adsorbent in parameters like % retention and permeate flux was also evaluated. Comparatively, better improvement was brought about in % retention and permeates flux by MCN.

scholarly journals Viability of Activated Carbon Derived from Polystyrene Sulphonate Beads as Electrical Double Layer Capacitors

2021 ◽  
Vol 7 (4) ◽  
pp. 82
Author(s):  
Gbenro Babajide Folaranmi ◽  
Anthony Ekennia ◽  
Nkiruka Chidiebere Ani ◽  
Richard Chukwuemeka Ehiri
Keyword(s):  
Activated Carbon ◽  
Double Layer ◽  
Electrical Double Layer ◽  
Electrochemical Impedance ◽  
Carbon Sphere ◽  
Potential Candidate ◽  
Carbon Spheres ◽  
Transfer Resistance ◽  
X Ray ◽  
Polystyrene Sulphonate

In this paper, a commercial polymeric resin precursor (polystyrene sulphonate beads) was used as a source of carbon spheres. The resin was pyrolyzed at different temperatures (700, 800, and 900 °C) and the resulting carbons were analyzed by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). From the result of EIS, carbon spheres obtained at 700 °C (CS−700) have the least ohmnic resistance and highest capacitance. In furtherance, the resin was chemically activated with iron (III) chloride FeCl3·6H2O at different concentration (0.1 M, 0.3 M, and 0.5 M) and pyrolyzed at 700 °C to obtain activated carbon sphere namely (ACS 700−0.1, ACS 700−0.3, and ACS 700−0.5) in which the last digit of the samples denotes the concentration of FeCl3. Scanning electron microscope (SEM) showed that the carbon is of spherical shape; X-ray diffraction (XRD), energy dispersive spectroscopy (EDS), and X-ray photon electron spectroscopy (XPS) revealed successful introduction of Fe on the surface of the carbon. Out of all the activated carbon spheres, ACS 700−0.1 exhibited highest double layer capacitance of 9 µF cm−2 and lowest charge transfer resistance of 3.33 KΩ·cm2. This method shows that carbon spheres obtained from a polymeric source can be easily improved by simple resin modification and the carbon could be a potential candidate for an electrical double layer capacitor

scholarly journals Removal of Congo Red Dye using Synthesised Copper(II) Activated Carbon from Date Seeds

2021 ◽  
Vol 14 ◽  
pp. 1-9
Author(s):  
Nur rahimah Said ◽  
Hazirah Syahirah Zakria ◽  
Siti Nor Atika Baharin ◽  
Nurul' Ain Jamion
Keyword(s):  
Activated Carbon ◽  
Surface Area ◽  
Congo Red ◽  
Bet Surface Area ◽  
Activation Process ◽  
X Ray Diffraction ◽  
X Ray ◽  
Effective Removal ◽  
Vis Spectroscopy ◽  
Red Dye

Azo dyes are recognised as contaminants from the textile and printing industries that lead to human toxicity. Copper(II) activated carbon (CuAC) is an effective removal agent of dyes in these industries. The purpose of this study is to synthesise and characterise CuAC from date seeds. In addition, the efficiency of CuAC as a removal of Congo red (CR) in aqueous solution is also studied. Activated carbon (AC) was prepared from date seeds using phosphoric acid as activating agent, followed by activation process in a furnace at 500 ℃ for 2 hours. Copper(II) nitrate was used in the impregnation of AC to produce CuAC. The AC and CuAC were characterised using Attenuated Total Reflectance Fourier-Transform Infrared Spectroscopy (ATR-FTIR), BET surface area (SBET), Scanning Electron Microscope-Energy Dispersive X-Ray Spectroscopy (SEM-EDX), Atomic Absorption Spectroscopy (AAS) and X-Ray Diffraction (XRD). UV-VIS Spectroscopy was used to determine dye concentrations after treatment with removal agent of CuAC. The characterisation data proved that the CuAC has been successfully synthesised with 0.33% Cu(II) loaded onto AC and its surface area increased from 8.37 m2/g to 384.82 m2/g. The dye removal study was conducted at 10 ppm concentration of dye. Result revealed that 0.2 g of CuAC at pH 2 in 90 min removed 100% of CR dye.

scholarly journals Adsorptive removal of malachite green dye from aqueous solution onto activated carbon of Catha edulis stem as a low cost bio-adsorbent

2020 ◽  
Vol 9 (1) ◽  
Author(s):  
Gietu Yirga Abate ◽  
Adugna Nigatu Alene ◽  
Adere Tarekegne Habte ◽  
Desiew Mekuanint Getahun
Keyword(s):  
Aqueous Solution ◽  
Activated Carbon ◽  
Low Cost ◽  
Aqueous System ◽  
Point Of Zero Charge ◽  
Isotherm Models ◽  
Synthetic Dyes ◽  
Order Kinetic ◽  
Operational Parameters ◽  
Catha Edulis

Abstract Background The release of hazardous synthetic dyes into industrial effluents has emerged as an environmental problem requiring remediation. The present study focused on the preparation of a new and environmentally-friendly material (adsorbent) for the remediation of hazardous dyes from aqueous solution. The low cost adsorbent was prepared from locally available khat (Catha edulis) stem which considered as waste and accumulated on waste disposal areas of Woldia town, Ethiopia. Comprehensive characterization studies were carried out on the bio-adsorbent such as proximate analyses, specific surface area, point of zero charge and FT-IR analysis. Results The proximate analysis shows the prepared adsorbent has very high fixed carbon content (83.65%), which refers to high quality of the adsorbent. The adsorption performance of the prepared activated carbon was optimized by varying operational parameters such as initial dye concentration (10 mg/L), pH (10), dosage (0.5 g), and contact time (60 min). The maximum removal efficiency of the prepared adsorbent at those optimum conditions was 98.8%. The experimental data was tested by most common kinetics and isotherm models. It was observed that the pseudo-second-order kinetic model fits better with good correlation coefficient and the equilibrium data fitted well with the Freundlich isotherm model. Conclusion In summery this study demonstrated that the waste bio sorbent could be employed as an effective and eco-friendly alternative for the cleanup of dye-polluted aqueous system.

scholarly journals Defluoridation of groundwater using mixed Mukondeni clay soils

2016 ◽  
Vol 17 (2) ◽  
pp. 480-492 ◽  
Author(s):  
T. Ngulube ◽  
M. W. Gitari ◽  
H. Tutu
Keyword(s):  
Fluoride Concentration ◽  
Freundlich Isotherm ◽  
Kinetic Studies ◽  
Exchange Capacity ◽  
Clay Soils ◽  
Point Of Zero Charge ◽  
X Ray ◽  
Temperature Optimization ◽  
Pseudo Second Order ◽  
Defluoridation Of Water

Excess fluoride in drinking water is harmful to human health and therefore it needs to be removed from water before consumption. The potential of locally available mixed Mukondeni clay soils (MMCS) as a cheap adsorbent for the removal of fluoride from aqueous solution was investigated. Characterization of MMCS was done by X-ray fluorescence, X-ray diffraction, scanning electron microscopy, Fourier transform infrared and Brunauer Emmett Teller. Cation exchange capacity and point of zero charge of the clays were determined using standard methods. Parameters optimized included: contact time, adsorbent dosage, initial fluoride concentration, pH and temperature. Optimization experiments were done in batch procedures. The results showed that the optimum conditions for the defluoridation of water using MMCS are 60 min, 1.5 g, 9 mg/L, 1.5/100 S/L ratios, pH of 2 and a temperature of 25 °C. The equilibrium isotherm regression parameter (R2 = 0.95) showed that the Freundlich isotherm gave a better fit than the Langmuir isotherm (R2 = 0.52) which indicates multilayer adsorption. Kinetic studies revealed that the adsorption followed pseudo second order kinetics. This study indicated that locally available MMCS are good in the defluoridation of groundwater but modification through blending with metal oxide modified clays can enhance their adsorption capacity.

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