Heterogeneous esterification of ricinoleic acid with polyol for the synthesis of polyol ricinoleates as biomass‐based lubricant base oil

2021 ◽  
Author(s):  
Song Gao ◽  
Fang‐Yu Ren ◽  
Wei‐Hang Xie ◽  
Liang‐Nian He ◽  
Hong‐Ru Li
Keyword(s):  
Ricinoleic Acid ◽  
Base Oil ◽  
Heterogeneous Esterification

Evaluation of castorbean samples by economically - valuable traits

2018 ◽  
pp. 39-48
Keyword(s):  
Ricinoleic Acid ◽  
Castor Bean ◽  
Castor Oil ◽  
Oil Content ◽  
Climatic Conditions ◽  
Second Order ◽  
Yield Potential ◽  
Technological Parameters ◽  
Potential Yield ◽  
Ricinolic Acid

Castor oil (Ricinus communus L.) is an important commercial product. The climatic conditions of Ukraine determine the possibility of growing the castor as an annual crop. At the Institute of Oilseeds NAAS studied castor collection. The aim of the work was the selection of the most promising samples of castor oil, combining a large yield potential in a narrow range of vertical distribution for optimal technological parameters of mechanical harvesting with a high content of oil in seeds and ricinolic acid in oil. In the experience of 2015-2016, the manifestation of morphological features of 17 castor bean samples was studied. The height of plants, individual samples among themselves differed more than twice. Long-brush samples of ЕР118, К374, М203, К159 are distinguished on the basis of the length of the brush. The shortest brush was observed in sample K1008. The length of the productive brush in the studied samples is from 10.7 to 32.9 cm. Most castor bean samples under favorable conditions form brushes of the second and higher orders. According to this parameter, samples of Ep118 and selection No. 38 with four inflorescences of the second order are of the greatest interest. The largest brushes of the second order are similar in size to the brushes of the first order were observed in the samples: К1127, К810, К153. The adaptability of harvesting castor beads requires that the brushes of the first and second order coincide in height with each other, since the harvester can take a maximum of 60 cm. For the sum of the productive brushes of the first and second orders, the greatest potential yield will be provided by samples K159 and K1127. Among the studied collection stands out the small seed sample K159 and the large seed samples - PRL41 and K80. The average oil content in the seeds of the collection was from 52 to 61.4%. Sample38 had the highest oil content. The content of ricinolic acid in the collection was from 70.9 to 82.9%. Samples were isolated: К134, К1008, PRL41, К430 with the content of ricinoleic acid more than 80%. The results of the study of all parameters make it possible to isolate valuable technological samples. Sample K1064 with a high technological potential of productivity, with a seed oil content of 57.2%, has a not very high content of ricinoleic acid of 74.3%. Sample K1127 with an oil content of 58.6%, a mass of 1000 seeds of 265 g, a high potential of productive brushes has a wide variation in the arrangement of brushes. Sample K134 with a oil content of 57.1%, ricinoleic acid content of 80.7% has small second-order brushes and can be used as a single-cysts in a thicker seeding.

Chemical composition of Azadirachta indica A. Juss and Ricinus communis Linn. seed oils growing in Marigat, Baringo County, Kenya

2020 ◽  
Vol 1 (2) ◽  
Author(s):  
Ann Kiplagat Jepkorir ◽  
Charles Maina Irungu ◽  
Philip Bett Kendagor
Keyword(s):  
Chemical Composition ◽  
Ricinoleic Acid ◽  
Unsaturated Fatty Acids ◽  
Ricinus Communis ◽  
Methyl Esters ◽  
Octadecenoic Acid ◽  
Seed Oils ◽  
Octadecanoic Acid ◽  
Alkyd Resins ◽  
Natural Remedies

All parts of A. indica (neem) and R. communis (castor) plants have mostly been used as natural remedies in the control and treatment of several ailments, control of pests and insects, animal feeds and production of industrial products globally. The seed oils of A. indica and R. communis are known to have antidiabetic, anti-helminthic, antifertility, antioxidant, antibacterial, anti-inflammatory, anti-cancer, insecticidal and mosquitocidal activity. This study reports for the first time the chemical composition of A. indica and R. communis seed oils from Marigat, Baringo County, Kenya. Seed oils of A. indica and R. communis were   extracted from mature dried seeds through cold pressing and boiling respectively and chemical composition determined using Gas Chromatography (GC)-Mass Spectrometry (MS).  The constituents of both seed oils were dominated by saturated and unsaturated fatty acids, cyclic esters and methyl esters. The predominant constituents of R. communis were (Z)-6-Octadecenoic acid (37.33%), Ricinoleic acid (30.22%) and 13-Hexyloxacyclotridec-10-en-2-one (26.67%) while those of A. indica were 2-hexyl-1-decanol (30.97%), Octadecanoic acid (29.69%) and Oxalic acid, 6-ethyloct-3-yl ethyl ester (15.55%). Oils contained Hexadecanoic acid and Octadecanoic acid which are used in the manufacture of several products such as candles, soaps, lotions, perfumes and cosmetics. Octadecenoic acid is important in control of human diseases and Ricinoleic acid in production of alkyd resins for surface coating and biofuel.  From the results, A. indica and R. communis seed oils constituents have potential in the agricultural, industrial, comestics and pharmaceutical sectors but require further fractionation to isolate the bioactive compounds.

Basal diets with different starch contents do not modify the metabolism of ricinoleic acid in dairy goats

2021 ◽  
pp. 114900
Author(s):  
J.S.R. Barbosa ◽  
J.G. Souza ◽  
C.J. L. Herbster ◽  
L.P. Silva ◽  
J.D.G. Carvalho ◽  
...  
Keyword(s):  
Ricinoleic Acid ◽  
Dairy Goats

scholarly journals Tribological properties of hexagonal boron nitride nanoparticles or graphene nanoplatelets blended with an ionic liquid as additives of an ester base oil

2021 ◽  
Author(s):  
José M. Liñeira del Río ◽  
Enriqueta R. López ◽  
David E. P. Gonçalves ◽  
Jorge H. O. Seabra ◽  
Josefa Fernández
Keyword(s):  
Ionic Liquid ◽  
Boron Nitride ◽  
Tribological Properties ◽  
Hexagonal Boron Nitride ◽  
Graphene Nanoplatelets ◽  
Base Oil ◽  
Boron Nitride Nanoparticles ◽  
Ester Base

scholarly journals Boundary Friction of ZDDP Tribofilms

2020 ◽  
Vol 69 (1) ◽  
Author(s):  
Jie Zhang ◽  
Mao Ueda ◽  
Sophie Campen ◽  
Hugh Spikes
Keyword(s):  
Friction Coefficient ◽  
Group Structure ◽  
Boundary Friction ◽  
Considerable Proportion ◽  
Base Oil ◽  
Characteristic Boundary ◽  
Long Duration ◽  
Structure Boundary ◽  
Alkoxy Groups ◽  
20 Nm

AbstractThe frictional properties of ZDDP tribofilms at low entrainment speeds in boundary lubrication conditions have been studied in both rolling/sliding and pure sliding contacts. It has been found that the boundary friction coefficients of these tribofilms depend on the alkyl structure of the ZDDPs. For primary ZDDPs, those with linear alkyl chains give lower friction those with branched alkyl chain ZDDPs, and a cyclohexylmethyl-based ZDDP gives markedly higher friction than non-cyclic ones. Depending on alkyl structure, boundary friction coefficient in rolling-sliding conditions can range from 0.09 to 0.14. These differences persist over long duration tests lasting up to 120 h. For secondary ZDDPs, boundary friction appears to depend less strongly on alkyl structure and in rolling-sliding conditions stabilises at ca 0.115 for the three ZDDPs studied. Experiments in which the ZDDP-containing lubricant is changed after tribofilm formation by a different ZDDP solution or a base oil indicate that the characteristic friction of the initial ZDDP tribofilm is lost almost as soon as rubbing commences in the new lubricant. The boundary friction rapidly stabilises at the characteristic boundary friction of the replacement ZDDP, or in the case of base oil, a value of ca 0.115 which is believed to represent the shear strength of the bare polyphosphate surface. The single exception is when a solution containing a cyclohexylethyl-based ZDDP is replaced by base oil, where the boundary friction coefficient remains at the high value characteristic of this ZDDP despite the fact that rubbing in base oil removes about 20 nm of the tribofilm. XPS analysis of the residual tribofilm reveals that this originates from presence of a considerable proportion of C-O bonds at the exposed tribofilm surface, indicating that not all of the alkoxy groups are lost from the polyphosphate during tribofilm formation. Very slow speed rubbing tests at low temperature show that the ZDDP solutions give boundary friction values that vary with alkyl group structure in a similar fashion to rolling-sliding MTM tests. These variations in friction occur immediately on rubbing, before any measurable tribofilm can develop. This study suggest that ZDDPs control boundary friction by adsorbing on rubbing steel or tribofilm surfaces in a fashion similar to organic friction modifiers. However it is believed that, for primary ZDDPs, residual alkoxy groups still chemically bonded to the phosphorus atoms of newly-formed polyphosphate/phosphate tribofilm may also contribute to boundary friction. This understanding will contribute to the design of low friction, fuel efficient crankcase engine oils. Graphical Abstract

scholarly journals Tribological Behavior of a Novel Organic Molybdenum Containing Dimercaptothiadiazole as a Multifunctional Additive in Biodegradable Base Oil

2021 ◽  
pp. 109823
Author(s):  
Jiao Wang ◽  
Xuefei Huang ◽  
Zhipeng Li ◽  
Chao Fu ◽  
Chenchen Wang ◽  
...  
Keyword(s):  
Tribological Behavior ◽  
Multifunctional Additive ◽  
Base Oil

Boundary Friction for a Line Contact Model: An Empirical Approach

2015 ◽  
Vol 642 ◽  
pp. 8-12
Author(s):  
William W.F. Chong ◽  
Miguel de La Cruz
Keyword(s):  
Steel Plate ◽  
Friction Model ◽  
Boundary Friction ◽  
Slider Bearing ◽  
Base Oil ◽  
Atomic Force ◽  
Alternative Approach ◽  
Nanoscale Friction ◽  
Friction Measurements ◽  
Good Agreement

The paper introduces an alternative approach to predict boundary friction for rough surfaces at micros-scale through the empirical integration of asperity-like nanoscale friction measurements. The nanoscale friction is measured using an atomic force microscope (AFM) tip sliding on a steel plate, confining the test lubricant, i.e. base oil for the fully formulated SAE grade 10w40. The approach, based on the Greenwood and Tripp’s friction model, is combined with the modified Elrod’s cavitation algorithm in order to predict the friction generated by a slider-bearing test rig. The numerical simulation results, using an improved boundary friction model, showed good agreement with the measured friction data.

CdSe quantum dots capped with naturally occurring biobased oils

2015 ◽  
Vol 39 (9) ◽  
pp. 7251-7259 ◽  
Author(s):  
Joseph W. Kyobe ◽  
Egid B. Mubofu ◽  
Yahya M. M. Makame ◽  
Sixberth Mlowe ◽  
Neerish Revaprasadu
Keyword(s):  
Quantum Dots ◽  
Ricinoleic Acid ◽  
Castor Oil ◽  
Cdse Quantum Dots ◽  
Capping Agents ◽  
Naturally Occurring

Ultra-small CdSe quantum dots were thermally synthesized using castor oil and ricinoleic acid both as capping agents and dispersing solvents.

Bridging high pressure rheology and film-forming capacity of polymer-base oil solutions in EHL

2016 ◽  
Vol 93 ◽  
pp. 502-510 ◽  
Author(s):  
C. Mary ◽  
D. Philippon ◽  
N. Devaux ◽  
N. Fillot ◽  
D. Laurent ◽  
...  
Keyword(s):  
High Pressure ◽  
Base Oil ◽  
Film Forming
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