A new phosphorus flame‐retard curing agent for epoxy resin/anhydride system

2021 ◽  
Author(s):  
Yichen Han ◽  
Hui Zhao ◽  
Jichuan Chen ◽  
Xinlong Wang ◽  
Lixin Chen ◽  
...  
Keyword(s):  
Epoxy Resin ◽  
Curing Agent

Preparation and analysis of a flexible curing agent for epoxy resin

2009 ◽  
Vol 114 (5) ◽  
pp. 2706-2710 ◽  
Author(s):  
Y. Yang ◽  
Gong Chen ◽  
K. M. Liew
Keyword(s):  
Epoxy Resin ◽  
Curing Agent

scholarly journals Synthesis of antibacterial polyether biguanide curing agent and its cured antibacterial epoxy resin

2021 ◽  
Vol 24 (1) ◽  
pp. 63-72
Author(s):  
Rui Li ◽  
Guoxing Yang ◽  
Yudan Wang ◽  
Lijia Liu ◽  
Qiang Wang ◽  
...  
Keyword(s):  
Epoxy Resin ◽  
Curing Agent

scholarly journals A Study on the Synthesis, Curing Behavior and Flame Retardance of a Novel Flame Retardant Curing Agent for Epoxy Resin

Polymers ◽  
2022 ◽  
Vol 14 (2) ◽  
pp. 245
Author(s):  
Yong Sun ◽  
Yongli Peng ◽  
Yajiao Zhang
Keyword(s):  
Flame Retardant ◽  
Epoxy Resin ◽  
Decomposition Temperature ◽  
Isothermal Kinetics ◽  
Flame Retardance ◽  
Curing Agent ◽  
Initial Decomposition Temperature ◽  
Limiting Oxygen Index ◽  
Epoxy Resin System ◽  
Dsc Method

In this work, a flame retardant curing agent (DOPO-MAC) composed of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide DOPO and methyl acrylamide (MAC) was synthesized successfully, and the structure of the compound was characterized by FT-IR and 1H-NMR. The non-isothermal kinetics of the epoxy resin/DOPO-MAC system with 1% phosphorus was studied by non-isothermal DSC method. The activation energy of the reaction (Ea), about 46 kJ/mol, was calculated by Kissinger and Ozawa method, indicating that the curing reaction was easy to carry out. The flame retardancy of the epoxy resin system was analyzed by vertical combustion test (UL94) and limiting oxygen index (LOI) test. The results showed that epoxy resin (EP) with 1% phosphorus successfully passed a UL-94 V-0 rating, and the LOI value increased along with the increasing of phosphorus content. It confirmed that DOPO-MAC possessed excellent flame retardance and higher curing reactivity. Moreover, the thermal stability of EP materials was also investigated by TGA. With the DOPO-MAC added, the residual mass of EP materials increased remarkably although the initial decomposition temperature decreased slightly.

Phosphorus- and silicon-containing amino curing agent for epoxy resin

2020 ◽  
Vol 29 (5) ◽  
pp. 433-443 ◽  
Author(s):  
Ajinkya Satdive ◽  
Siddhesh Mestry ◽  
Pavan Borse ◽  
Shashank Mhaske
Keyword(s):  
Epoxy Resin ◽  
Curing Agent

scholarly journals The application of a phosphorus nitrogen flame retardant curing agent in epoxy resin

e-Polymers ◽  
2019 ◽  
Vol 19 (1) ◽  
pp. 545-554 ◽  
Author(s):  
Anxin Li ◽  
Pingli Mao ◽  
Bing Liang
Keyword(s):  
Flame Retardant ◽  
Epoxy Resin ◽  
Adhesive Strength ◽  
Chemical Structure ◽  
Phosphorus Content ◽  
Raw Material ◽  
Curing Agent ◽  
Thermal Degradation Behavior ◽  
Overall Performance ◽  
The Impact

AbstractIn order to improve the compatibility of flame retardant and epoxy resin, a phosphorus nitrogen flame retardant curing agent poly(p-xylylenediamine spirocyclic pentaerythritol bisphosphonate) (PPXSPB) was synthesized. FTIR, 1HNMR, and mass spectroscopy were used to identify the chemical structure of PPXSPB. Epoxy resin (E-44) and PPXSPB as the raw material, a series of thermosetting systems were prepared. The effects of PPXSPB on flame retardancy, water resistance, thermal degradation behavior, mechanical properties and the adhesive strength of EP/PPXSPB thermosets were investigated. The results show that with the increase of phosphorus content, the oxygen index and carbon residue of the system both increased significantly, and the heat release rate gradually decreased, which is of great significance in delaying the occurrence of fire. When the phosphorus content is 3.24% in EP/PPXSPB thermosets, EP-2 can successfully pass the UL94 V-0 flammability rating, the LOI value of EP-2 can reach 31.4%, the impact strength and tensile strength was 6.58 kJ/m2 and 47.10 MPa respectively, and the adhesive strength was 13.79 MPa, the system presents a good overall performance.

HIGH TECHNIQUE FOR T-PEEL STRENGTH ENHANCEMENT OF Al/AFRP HYBRID COMPOSITE

2006 ◽  
Vol 20 (25n27) ◽  
pp. 4273-4278
Author(s):  
CHEOL-WOONG KIM ◽  
DONG-JOON OH
Keyword(s):  
Tensile Strength ◽  
Epoxy Resin ◽  
Hybrid Composite ◽  
Equivalence Ratio ◽  
Peel Strength ◽  
Aramid Fiber ◽  
Curing Agent ◽  
Mixture Ratio ◽  
Resin Mixture ◽  
Resin Curing

The interlaminar peel strength of Al / AFRP (Aluminum alloy/Aramid Fiber Reinforced Plastic) hybrid composite is affected by the adhesive strength between the Al alloy layer and the aramid fiber layer. The study of the tensile strength and the T-peel strength of the Al / AFRP should be accomplished first. Therefore, this study focused on the effect of the resin mixture ratio as the Al / AFRP on the tensile strength and T-peel strength. In conclusions, the resin mixture ratio by equivalence ratio of 〈epoxy resin : curing agent〉 equal to 〈1:1〉 of Al / AFRP -I and the resin mixture ratio by equivalence ratio of 〈epoxy resin : curing agent : accelerator〉 equal to 〈1:1:0.2〉 of Al / AFRP -II showed the highest ultimate tensile strength. After the T-peel test, it is found that the T-peel strength of Al / AFRP -II is approximately 1.5 times higher than that of Al / AFRP -I. Reviewing the characteristics of the tensile and T-peel strengths, the resin mixture ratio 〈1:1:0.2〉 of Al / AFRP -II showed the highest tensile strength and T-peel strength.

Studies on Mechanical and Thermal Properties of Epoxy Resin Modified by Fluorine-Containing Silicone

2013 ◽  
Vol 401-403 ◽  
pp. 713-716
Author(s):  
Cheng Fang ◽  
Dong Bo Guan ◽  
Wei Guo Yao ◽  
Shou Jun Wang ◽  
Hui An
Keyword(s):  
Glass Transition ◽  
Thermal Properties ◽  
Epoxy Resin ◽  
Bending Strength ◽  
Mechanical And Thermal Properties ◽  
Curing Agent ◽  
Epoxy System ◽  
Resin Curing ◽  
The Impact ◽  
Modified Epoxy

The epoxy resin was modified with the mixture of α,ω-dihydroxy poly-(3,3,3-trifluoropropyl) siloxane (PTFPMS), KH560 and stannous octoate. KH560 can react with PTFPMS and also epoxy resin curing agent. The two reactions were characterized by FI-IR. The modified epoxy resin was characterized by FI-IR. The result showed that fluorine-containing silicone had been successfully introduced into the epoxy system. The mechanical and thermal properties of the modified epoxy resin were analyzed. The results showed that with the increase of PTFPMS the impact strength of epoxy resin increased, hardness and bending strength correspondingly reduced, slight decrease in the glass transition temperature.

Curing study and evaluation of epoxy resin with amine functional chloroaniline acetaldehyde condensate

2015 ◽  
Vol 44 (1) ◽  
pp. 19-25
Author(s):  
T. Maity ◽  
B.C. Samanta
Keyword(s):  
Mechanical Properties ◽  
Molecular Weight ◽  
Epoxy Resin ◽  
Ph Value ◽  
Kinetic Studies ◽  
Diglycidyl Ether ◽  
Curing Agent ◽  
Scanning Calorimetry ◽  
Content Type ◽  
Curing Reaction

Purpose – The purpose of this paper was to check effectiveness of amine functional chloroaniline acetaldehyde condensate (AFCAC) as a new curing agent for diglycidyl ether of bisphenol A (DGEBA) resin. For this purpose, first AFCAC was synthesised, characterised and then curing reaction was carried out. Design/methodology/approach – Equimolecular mixture of AFCAC and DGEBA was subjected to curing reaction, and the reaction was followed by differential scanning calorimetry (DSC) analysis. The kinetic studies of this curing reaction were also carried out from those DSC exotherms. The mechanical properties, dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA) of cured epoxy were also reported. Findings – DSC results reflected the effective first order curing reaction of AFCAC with epoxy resin. Mechanical properties reflected appreciable rigidity of AFCAC cured epoxy matrix and TGA showed that the cured epoxy networks were thermally stable up to around 297°C. Research limitations/implications – The curing agent AFCAC was synthesised by using chloroaniline and acetaldehyde in acid medium. There are some limitations for this procedure. The synthetic procedure is pH dependent. So reaction cannot be done at any pH value. The reaction must also be carried out at room temperature without any heating. To obtain low molecular weight curing agent, chloroaniline and acetaldehyde cannot be taken in equimolecular ratio because the equimolecular mixture of them produces high molecular weight condensate. This was shown in our previous publication. Some implications are also there. By changing amine and aldehyde other curing agents could be synthesised and the curing efficiency of those for epoxy resin could also be studied. Originality/value – Experimental results revealed the greater suitability of AFCAC as curing agent for DGEBA resin and novelty of AFCAC cured matrix in the field of protective coating, casting, adhesives, etc.

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