Construction of Three-Dimensional Using Layer-by-Layer Method

This work addresses the formation and the internal morphology of polyelectrolyte layers obtained by the layer-by-layer method. A multimodal characterization showed the absence of stratification of the films formed by the alternate deposition of poly(diallyldimethylammonium chloride) and poly(sodium 4-styrenesulfonate). Indeed the final organization might be regarded as three-dimensional solid-supported inter-polyelectrolyte films. The growth mechanism of the multilayers, followed using a quartz crystal microbalance, evidences two different growth trends, which show a dependency on the ionic strength due to its influence onto the polymer conformation. The hydration state does not modify the multilayer growth, but it contributes to the total adsorbed mass of the film. The water associated with the polyelectrolyte films leads to their swelling and plastification. The use of X-ray photoelectron spectroscopy has allowed for deeper insights on the internal structure and composition of the polyelectrolyte multilayers.

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Three-Dimensional Nanodot-Type Floating Gate Memory Fabricated by Bio-Layer-by-Layer Method

Applied Physics Express ◽

10.1143/apex.4.085004 ◽

2011 ◽

Vol 4 (8) ◽

pp. 085004 ◽

Cited By ~ 8

Author(s):

Kosuke Ohara ◽

Bin Zheng ◽

Mutsunori Uenuma ◽

Yasuaki Ishikawa ◽

Kiyotaka Shiba ◽

...

Keyword(s):

Three Dimensional ◽

Floating Gate ◽

Layer By Layer ◽

Layer Method ◽

Floating Gate Memory

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Layer-by-Layer Method to Prepare Three-Dimensional Reduced Graphene Materials with Controlled Architectures Using SiO2 as a Sacrificial Template

Industrial & Engineering Chemistry Research ◽

10.1021/acs.iecr.1c00885 ◽

2021 ◽

Author(s):

Alma D. Salazar-Aguilar ◽

José Iván Rodriguez-Rodriguez ◽

Alexis Piñeiro-García ◽

Ferdinando Tristan ◽

Gladis Judith Labrada-Delgado ◽

...

Keyword(s):

Three Dimensional ◽

Layer By Layer ◽

Sacrificial Template ◽

Layer Method ◽

Reduced Graphene

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Angular Calibration of Ribosomal Subuntts in Factor Space

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100181063 ◽

1990 ◽

Vol 48 (1) ◽

pp. 462-463

Author(s):

Minakhi Pujari ◽

Joachim Frank

Keyword(s):

Three Dimensional ◽

Carbon Layer ◽

Uranyl Acetate ◽

Particle Analysis ◽

Factor Space ◽

Multivariate Statistical ◽

Ribosomal Subunits ◽

Layer Method ◽

Dimensional Reconstruction ◽

Number Of Particles

In single-particle analysis of macromolecule images with the electron microscope, variations of projections are often observed that can be attributed to the changes of the particle’s orientation on the specimen grid (“rocking”). In the multivariate statistical analysis (MSA) of such projections, a single factor is often found that expresses a large portion of these variations. Successful angle calibration of this “rocking factor” would mean that correct angles can be assigned to a large number of particles, thus facilitating three-dimensional reconstruction.In a study to explore angle calibration in factor space, we used 40S ribosomal subunits, which are known to rock around an axis approximately coincident with their long axis. We analyzed micrographs of a field of these particles, taken with 20° tilt and without tilt, using the standard methods of alignment and MSA. The specimen was prepared with the double carbon-layer method, using uranyl acetate for negative staining. In the MSA analysis, the untilted-particle projections were used as active, the tilted-particle projections as inactive objects. Upon tilting, those particles whose rocking axes are parallel to the tilt axis will change their appearance in the same way as under the influence of rocking. Therefore, each vector, in factor space, joining a tilted and untilted projection of the same particle can be regarded as a local 20-degree calibration bar.

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3D Printing of High Viscosity Reinforced Silicone Elastomers

Polymers ◽

10.3390/polym13142239 ◽

2021 ◽

Vol 13 (14) ◽

pp. 2239

Author(s):

Nicholas Rodriguez ◽

Samantha Ruelas ◽

Jean-Baptiste Forien ◽

Nikola Dudukovic ◽

Josh DeOtte ◽

...

Keyword(s):

Mechanical Properties ◽

High Performance ◽

New Technologies ◽

Three Dimensional ◽

High Viscosity ◽

Layer By Layer ◽

Silicone Elastomers ◽

Uv Curable ◽

Octet Truss ◽

Tunable Mechanical Properties

Recent advances in additive manufacturing, specifically direct ink writing (DIW) and ink-jetting, have enabled the production of elastomeric silicone parts with deterministic control over the structure, shape, and mechanical properties. These new technologies offer rapid prototyping advantages and find applications in various fields, including biomedical devices, prosthetics, metamaterials, and soft robotics. Stereolithography (SLA) is a complementary approach with the ability to print with finer features and potentially higher throughput. However, all high-performance silicone elastomers are composites of polysiloxane networks reinforced with particulate filler, and consequently, silicone resins tend to have high viscosities (gel- or paste-like), which complicates or completely inhibits the layer-by-layer recoating process central to most SLA technologies. Herein, the design and build of a digital light projection SLA printer suitable for handling high-viscosity resins is demonstrated. Further, a series of UV-curable silicone resins with thiol-ene crosslinking and reinforced by a combination of fumed silica and MQ resins are also described. The resulting silicone elastomers are shown to have tunable mechanical properties, with 100–350% elongation and ultimate tensile strength from 1 to 2.5 MPa. Three-dimensional printed features of 0.4 mm were achieved, and complexity is demonstrated by octet-truss lattices that display negative stiffness.

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A guideline for 3D printing terminology in biomedical research utilizing ISO/ASTM standards

3D Printing in Medicine ◽

10.1186/s41205-021-00098-5 ◽

2021 ◽

Vol 7 (1) ◽

Author(s):

Amy E. Alexander ◽

Nicole Wake ◽

Leonid Chepelev ◽

Philipp Brantner ◽

Justin Ryan ◽

...

Keyword(s):

3D Printing ◽

Medical Literature ◽

Three Dimensional ◽

Physical Object ◽

Medical Community ◽

Layer By Layer ◽

Digital File ◽

Standardized Terminology ◽

Standard Terms ◽

The Impact

AbstractFirst patented in 1986, three-dimensional (3D) printing, also known as additive manufacturing or rapid prototyping, now encompasses a variety of distinct technology types where material is deposited, joined, or solidified layer by layer to create a physical object from a digital file. As 3D printing technologies continue to evolve, and as more manuscripts describing these technologies are published in the medical literature, it is imperative that standardized terminology for 3D printing is utilized. The purpose of this manuscript is to provide recommendations for standardized lexicons for 3D printing technologies described in the medical literature. For all 3D printing methods, standard general ISO/ASTM terms for 3D printing should be utilized. Additional, non-standard terms should be included to facilitate communication and reproducibility when the ISO/ASTM terms are insufficient in describing expository details. By aligning to these guidelines, the use of uniform terms for 3D printing and the associated technologies will lead to improved clarity and reproducibility of published work which will ultimately increase the impact of publications, facilitate quality improvement, and promote the dissemination and adoption of 3D printing in the medical community.

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Three-dimensionally printed polycaprolactone/multicomponent bioactive glass scaffolds for potential application in bone tissue engineering

Biomedical glasses ◽

10.1515/bglass-2020-0006 ◽

2020 ◽

Vol 6 (1) ◽

pp. 57-69

Author(s):

Amirhosein Fathi ◽

Farzad Kermani ◽

Aliasghar Behnamghader ◽

Sara Banijamali ◽

Masoud Mozafari ◽

...

Keyword(s):

Tissue Engineering ◽

3D Printing ◽

Bone Tissue Engineering ◽

Bone Tissue ◽

Three Dimensional ◽

Layer By Layer ◽

Composite Scaffolds ◽

3D Printed ◽

Co Doped

AbstractOver the last years, three-dimensional (3D) printing has been successfully applied to produce suitable substitutes for treating bone defects. In this work, 3D printed composite scaffolds of polycaprolactone (PCL) and strontium (Sr)- and cobalt (Co)-doped multi-component melt-derived bioactive glasses (BGs) were prepared for bone tissue engineering strategies. For this purpose, 30% of as-prepared BG particles (size <38 μm) were incorporated into PCL, and then the obtained composite mix was introduced into a 3D printing machine to fabricate layer-by-layer porous structures with the size of 12 × 12 × 2 mm3.The scaffolds were fully characterized through a series of physico-chemical and biological assays. Adding the BGs to PCL led to an improvement in the compressive strength of the fabricated scaffolds and increased their hydrophilicity. Furthermore, the PCL/BG scaffolds showed apatite-forming ability (i.e., bioactivity behavior) after being immersed in simulated body fluid (SBF). The in vitro cellular examinations revealed the cytocompatibility of the scaffolds and confirmed them as suitable substrates for the adhesion and proliferation of MG-63 osteosarcoma cells. In conclusion, 3D printed composite scaffolds made of PCL and Sr- and Co-doped BGs might be potentially-beneficial bone replacements, and the achieved results motivate further research on these materials.

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Direct Patterning and Spontaneous Self-Assembly of Graphene Oxide via Electrohydrodynamic Jet Printing for Energy Storage and Sensing

Micromachines ◽

10.3390/mi11010013 ◽

2019 ◽

Vol 11 (1) ◽

pp. 13 ◽

Cited By ~ 2

Author(s):

Bin Zhang ◽

Jaehyun Lee ◽

Mincheol Kim ◽

Naeeung Lee ◽

Hyungdong Lee ◽

...

Keyword(s):

Graphene Oxide ◽

Energy Storage ◽

Self Assembly ◽

High Performance ◽

Three Dimensional ◽

Chemical Properties ◽

Layer By Layer ◽

Energy Storage Devices ◽

Laminar Structure ◽

Jet Printing

The macroscopic assembly of two-dimensional materials into a laminar structure has received considerable attention because it improves both the mechanical and chemical properties of the original materials. However, conventional manufacturing methods have certain limitations in that they require a high temperature process, use toxic solvents, and are considerably time consuming. Here, we present a new system for the self-assembly of layer-by-layer (LBL) graphene oxide (GO) via an electrohydrodynamic (EHD) jet printing technique. During printing, the orientation of GO flakes can be controlled by the velocity distribution of liquid jet and electric field-induced alignment spontaneously. Closely-packed GO patterns with an ordered laminar structure can be rapidly realized using an interfacial assembly process on the substrates. The surface roughness and electrical conductivity of the LBL structure were significantly improved compared with conventional dispensing methods. We further applied this technique to fabricate a reduced graphene oxide (r-GO)-based supercapacitor and a three-dimensional (3D) metallic grid hybrid ammonia sensor. We present the EHD-assisted assembly of laminar r-GO structures as a new platform for preparing high-performance energy storage devices and sensors.

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Evaluation of Parts Produced by a Novel Additive Manufacturing Process

Applied Mechanics and Materials ◽

10.4028/www.scientific.net/amm.315.63 ◽

2013 ◽

Vol 315 ◽

pp. 63-67 ◽

Cited By ~ 1

Author(s):

Muhammad Fahad ◽

Neil Hopkinson

Keyword(s):

Additive Manufacturing ◽

Rapid Prototyping ◽

Manufacturing Process ◽

High Speed ◽

Three Dimensional ◽

Coordinate Measuring Machine ◽

Layer By Layer ◽

Nylon 12 ◽

Measuring Machine ◽

End Use

Rapid prototyping refers to building three dimensional parts in a tool-less, layer by layer manner using the CAD geometry of the part. Additive Manufacturing (AM) is the name given to the application of rapid prototyping technologies to produce functional, end use items. Since AM is relatively new area of manufacturing processes, various processes are being developed and analyzed for their performance (mainly speed and accuracy). This paper deals with the design of a new benchmark part to analyze the flatness of parts produced on High Speed Sintering (HSS) which is a novel Additive Manufacturing process and is currently being developed at Loughborough University. The designed benchmark part comprised of various features such as cubes, holes, cylinders, spheres and cones on a flat base and the build material used for these parts was nylon 12 powder. Flatness and curvature of the base of these parts were measured using a coordinate measuring machine (CMM) and the results are discussed in relation to the operating parameters of the process.The result show changes in the flatness of part with the depth of part in the bed which is attributed to the thermal gradient within the build envelope during build.

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