Evaluation of mercury, lead, and cadmium in the waste material of crevalle jack fish from the Gulf of Urabá, Colombian Caribbean, as a possible raw material in the production of sub-products

Author(s):  
Sara Elisa Gallego Ríos ◽  
Claudia María Ramírez Botero ◽  
Beatriz Estella López Marín ◽  
Claudia M. Velásquez Rodríguez
2019 ◽  
Vol 16 (32) ◽  
pp. 34-41
Author(s):  
Guilherme Rufatto SCHMIDT

Herb-mate is a raw material of great importance to Southern Brazil, considering its annual production of approximately 650,000 tons of leaves. The hot mate, known as chimarrão, is the most appreciated beverage and its consumption is linked to the traditions and cultural habits predominantly in the south of the country. Considering its huge importance, the objective of the work was to evaluate the production of laboratory herbmate for chimarrão in order to establish a comparison with the products available on the market. Therefore, it was considered the current legislation and the analysis of its organoleptic and granulometric properties, humidity level and concentration of some toxic metals quantified by inductively coupled plasma optical emission spectrometry. The manufacturing of the final product was made in three steps: first of all, the leaves were submitted to direct fire, then they were dried at a temperature of 40 Cº for 24 hours and, finally, they were ground in a knife mill for 10 minutes. The obtained results showed, in most of the analyzed characteristics, a great similarity between the laboratorial and commercial herb, obtaining approval from 90% of chimarrão consumers who participated in the organoleptic tests. However, the coloration was considered darker and can be explained by logistic problems between the plantation and the laboratory. There was also a divergence in the metals analysis, which showed a higher lead and cadmium concentration when compared to the herbs found on the supermarket shelves. Alarming numbers for consumers were found, since the commercial herbs pointed levels above the recommended for all analyzed metals, which indicate the urgent need for better inspection, as well as improved manufacturing practices of the final product and a better raw material cultivation.


2015 ◽  
Vol 659 ◽  
pp. 237-241 ◽  
Author(s):  
Achanai Buasri ◽  
Teera Sriboonraung ◽  
Kittika Ruangnam ◽  
Pattarapon Imsombati ◽  
Vorrada Loryuenyong

Calcium oxide (CaO) is one of the most promising heterogeneous alkali catalysts since it is cheap, abundantly available in nature, and some of the sources of this compound are renewable (waste material consisting of calcium carbonate (CaCO3)). In this study, the waste enamel venus shell was used as the raw material for CaO catalyst. The calcination of bio-waste was conducted at 900 °C for 2 h. The raw material and the resulting CaO catalyst were characterized using X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy (SEM) and the Brunauer-Emmett-Teller (BET) method. The effects of reaction variables such as reaction time, microwave power, methanol/oil molar ratio, and catalyst loading on the yield of biodiesel were investigated by gas chromatograph-mass spectrometry (GC-MS). From the experimental results, it was found that the CaO catalysts derived from waste material showed good catalytic activity (the conversion of oil of nearly 93%, a very similar catalytic activity with laboratory CaO) and had high potential to be used as biodiesel production catalysts in transesterification of Jatropha Curcas oil with methanol.


Author(s):  
Fatih Kürşat Fırat ◽  
Fahri Akbaş

The growth in world population, global climate change, consumption habits of people, and the excessive use of prime materials, causes natural resources to decline rapidly. We waste more energy during the process of production, operation and transportation of materials than ever. Perhaps one of the most important challenges that our generation faces is to create an economy that prevents waste. Considering limited resources, countries are searching for new methods of recycling and reusing waste material. Recycling is one primary way to reduce the consumption of natural resources. Waste material can go through a reproduction process with various physical and chemical transformation methods. The recycling of petrochemicals used in the automotive industry, electrical appliances, steel and cement industries, and the improvement of the transportation sector can reduce energy consumption and raw material significantly. Investment in recycling facilities can maximize profits by turning waste back into the economy. In Turkey, the improvements on the subject of recycling of materials such as plastics and paper are observed. However, we almost see no recycling in the construction industry, except iron and steel sector. Demolition materials in other countries are included in the reproduction processes through recycling. Thus both the benefits of reducing energy consumption and carbon emissions are at a minimum. Therefore, this study focuses on the recycling in the Turkey construction industry. The research also investigates the impact of recycling of construction materials to the economy and the environment based on the data and knowledge obtained from some European countries.


2014 ◽  
Vol 680 ◽  
pp. 135-139
Author(s):  
Mohd Syahrul Hisyam Mohd Sani ◽  
Fadhluhartini Muftah ◽  
Muhammad Isha Ismail ◽  
Marzuki Ab. Rahman

The paper deals with the properties of a special mortar using a Waste Paper Sludge Ash (WPSA) from Waste Paper Recycling Industry and Bottom Ash (BA) from Coal Electric Power Stations. Special mortar with some advantages is proposed to give a significant impact for replacing of normal cement mortar. The advantages are approached due to the problem that occurred from collecting raw material such as pollution problems and environmental impact issues. Besides, the raw material sources of cement and sand is limited and this issue engages with the ideas to produce new material in mortar and masonry engineering. A total 72 cubes mortar is cast and determined their properties of chemical and mechanical. The properties of special mortar are compared with other special mortar made of other waste material. The compression strength of special mortar is conducted at the age 3, 7, 28 and 40 days of curing. From the result of chemical properties, it showed that the special mortar created the high compression strength value for all mixes. The compression strength of special mortar is increased by increasing the percentage sand replacement by BA. But, the compression strength is decreased when WPSA is increased. Finally, the special mortar with 100 % BA and 10 % WPSA showed the appropriate proportion for producing special mortar.


Catalysts ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 894 ◽  
Author(s):  
Pavol Steltenpohl ◽  
Jakub Husár ◽  
Patrik Šuhaj ◽  
Juma Haydary

Municipal solid waste constitutes one of the major challenges and concerns of our society. Disposal of waste material is potentially dangerous, harming both environment and mankind. In order to diminish negative effects of municipal solid waste, its thermal decomposition to valuable chemicals has been studied. The principal draw-back of thermal processes used for solid waste utilization as raw material is tar formation. In this study, low-cost catalysts of different origin were tested in the decomposition of a model component of tar originating from waste material pyrolysis/gasification. p-Xylene was selected as the model compound found in biomass decomposition products. Its decomposition was carried out in the presence of either tire pyrolysis char- or clay minerals-based catalysts. Tar-cracking activities of both catalyst types at varying experimental conditions were compared and related to the catalysts physical-chemical properties. In experiments, either empty reactor or reactor filled with 10 g of the catalyst was used; p-xylene mass flow was set to 2.58 g h−1 (50 μL min−1, room temperature), and decomposition temperature ranging from 750 °C to 850 °C was applied. Moreover, evolution of the output variables, p-xylene conversion and hydrogen content in the gas phase, with the reaction time was investigated. Catalysts’ properties were assessed based on nitrogen adsorption isotherms, thermogravimetric and elemental composition analyses. Amounts and composition of p-xylene catalytic decomposition products were evaluated using GC analysis of both gaseous phase and condensable products. Results showed the superiority of tire pyrolysis char catalyst over that based on clay minerals.


One of the major fillers used in HMA is cement. With the extensive use of cement in mortars/concrete, there have been some environmental concerns in terms of damage caused by the extraction of raw material and Carbon dioxide (CO2) emission during cement manufacture. This has brought pressures to reduce the cement consumption in the industry. This journal outlines the ongoing research on different waste materials partial replacement of cement as filler used in hot mix asphalt mixes. Many studies regarding their effects on bituminous mixes were also analysed in combination with cement filler mastic. This project summarizes the interaction of Waste materials partial replacement of cement with different percentages 0%, 25%, 50%, 75%, 100% and finding out the optimun percenetage of waste material i.e: GGBS, Flyash, Concrete dust, Metakaolin and Marble powder as partial replacment of cement in bituminous mixes. Marshall properties such as stability, flow value, unit weight, air voids, are used to determine optimum waste material content for the used grade of bitumen (100/120).


2011 ◽  
Vol 1 (4) ◽  
pp. 87-92 ◽  
Author(s):  
A. I KhLYSTOV ◽  
M. V KONNOV ◽  
A. V VLASOV ◽  
E. A ChERNOVA

The question of usage of high-heat inorganic waste material of industry in the structure of heat-resistant binding agents, fillers and concretes is considered. It was established that physical and thermal properties of heat- resistant composites depend on the type of concrete used for chemical binding of anthropogenic raw material. The ways of an efficient choice of raw components and heat- resistant binding agents are suggested for optimization of the structures of refractory lining materials.


2014 ◽  
Vol 798-799 ◽  
pp. 599-604
Author(s):  
Nancy E. Quaranta ◽  
Marta G. Caligaris ◽  
Miguel A. Unsen ◽  
Hugo A. López ◽  
Gisela G. Pelozo

The objective of this work is to analyze ashes from a thermal power plant with the aim of determining its environmental aptitude for reutilization as aggregates in clay mixtures for ceramics production. To achieve this objective the waste material was characterized by different techniques: optical microscopy, scanning electronic microscopy, conductivity, pH, among others. Clay samples with bottom ash addition, up to 50%, were prepared. These samples were thermally treated at 950oC and then characterized with diverse techniques in order to determine their behaviour in service. The obtained results show the high feasibility of reutilization of the studied waste as raw material in the production of ceramic products.


Author(s):  
L. L. Sutter ◽  
G. R. Dewey ◽  
J. F. Sandell

Municipal waste combustion typically involves both energy recovery as well as volume reduction of municipal solid waste prior to landfilling. However, due to environmental concerns, municipal waste combustion (MWC) has not been a widely accepted practice. A primary concern is the leaching behavior of MWC ash when it is stored in a landfill. The ash consists of a finely divided fly ash fraction (10% by volume) and a coarser bottom ash (90% by volume). Typically, MWC fly ash fails tests used to evaluate leaching behavior due to high amounts of soluble lead and cadmium species. The focus of this study was to identify specific lead bearing phases in MWC fly ash. Detailed information regarding lead speciation is necessary to completely understand the leaching behavior of MWC ash.


2001 ◽  
Vol 60 (1) ◽  
pp. 11-14 ◽  
Author(s):  
Lucia Savadori ◽  
Eraldo Nicotra ◽  
Rino Rumiati ◽  
Roberto Tamborini

The content and structure of mental representation of economic crises were studied and the flexibility of the structure in different social contexts was tested. Italian and Swiss samples (Total N = 98) were compared with respect to their judgments as to how a series of concrete examples of events representing abstract indicators were relevant symptoms of economic crisis. Mental representations were derived using a cluster procedure. Results showed that the relevance of the indicators varied as a function of national context. The growth of unemployment was judged to be by far the most important symptom of an economic crisis but the Swiss sample judged bankruptcies as more symptomatic than Italians who considered inflation, raw material prices and external accounts to be more relevant. A different clustering structure was found for the two samples: the locations of unemployment and gross domestic production indicators were the main differences in representations.


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