scholarly journals The Thermal Diffusivity of Glass Sieves: II. Gas-saturated Frits

2021 ◽  
Vol 42 (6) ◽  
Author(s):  
Ulf Hammerschmidt ◽  
Muhammad Abid
Keyword(s):  
Thermal Diffusivity ◽  
Borosilicate Glass ◽  
Room Temperature ◽  
Ambient Pressure ◽  
Expanded Uncertainty ◽  
The Matrix ◽  
Thermal Diffusivities ◽  
Transient Hot Bridge

AbstractThe thermal diffusivity of gas-saturated glass sieves (frits) of porosities between 20 % and 48 % is presented as measured at room temperature and ambient pressure. The saturants cover a range in thermal diffusivity from 20.63 × 10–6 m2⋅s−1 to 172 × 10–6 m2⋅s−1. The experiments were carried out using a transient hot-bridge instrument of an expanded uncertainty of 5 % to 10 %. It turned out that all measured thermal diffusivities of the gas-saturated frits (1) are smaller than that of the borosilicate glass the frits are made from and (2) are completely different from the thermal diffusivities of the liquid-saturated frits. Both these discrepancies can be attributed to characteristic properties of the matrix and not directly to the saturants. The first divergence results from thermal tortuosity that lengthens the pathway of heat through the matrix, whereas the second arises from dissolved He that enhances the transport of heat through the matrix.

Thermal Conductivities of Cs-M-O (M= Mo or U) Ternary Compounds

2009 ◽  
Vol 1215 ◽  
Author(s):  
Kazuyuki Tokushima ◽  
Kosuke Tanaka ◽  
Ken Kurosaki ◽  
Hiromichi Gima ◽  
Hiroaki Muta ◽  
...  
Keyword(s):  
Heat Capacity ◽  
Thermal Diffusivity ◽  
Room Temperature ◽  
Laser Flash ◽  
Flash Method ◽  
Ternary Compounds ◽  
Plasma Sintering ◽  
Spark Plasma ◽  
Thermal Diffusivities ◽  
Thermal Conductivities

AbstractThermal conductivities of Cs-M-O (M= Mo or U) ternary compounds, observed in the pellet-cladding gap region and in the pellet periphery in irradiated oxide fuels with high oxygen potentials, were investigated. Bulk samples of Cs2MoO4and Cs2UO4were prepared by hot pressing or spark plasma sintering, and their thermal diffusivities were measured by the laser flash method from room temperature to 823 K for Cs2MoO4and to 900 K for Cs2UO4. The thermal conductivities were evaluated from the thermal diffusivity and bulk density, and the specific heat capacity values available in the literature. The thermal conductivities of Cs2MoO4and Cs2UO4were quite low compared with UO2(e.g. 0.5 Wm−1K−1at 800 K for Cs2MoO4).

Development of iron-base composite materials with high thermal conductivity for DEMO

2014 ◽  
Vol 1645 ◽  
Author(s):  
H. Homma ◽  
N. Hashimoto ◽  
S. Ohnuki
Keyword(s):  
Composite Materials ◽  
Thermal Diffusivity ◽  
High Heat ◽  
High Heat Flux ◽  
Plasma Sintering ◽  
The Matrix ◽  
Critical Issues ◽  
High Thermal Diffusivity ◽  
Copper Composite ◽  
Thermal Diffusivities

ABSTRACTOne of the critical issues for development of the nuclear fusion demonstration reactor (DEMO) is the high heat flux on heat-resistant equipments, especially the blanket and divertor. Materials of such equipments require relatively high thermal conductivities. In this study, we developed iron-based composite materials with carbon nanotube (CNT) and copper, which have high thermal diffusivities, by means of Hot Pressing (HP) and Spark Plasma Sintering (SPS).The thermal diffusivity in the iron/CNT composites was not high enough compared with that of pure iron, while iron/copper composite showed a relatively high thermal diffusivity in the joining conditions. One of the reasons not to be improved thermal diffusivity could be non-mono-dispersion of CNT by the formation of carbides in the matrix.

Effects of microstructural evolution on the thermal conductivity of α–Al2O3 prepared from nano-size γ–Al2O3 powder

2000 ◽  
Vol 15 (3) ◽  
pp. 744-750 ◽  
Author(s):  
Eduardo J. Gonzalez ◽  
Grady White ◽  
Lanhua Wei
Keyword(s):  
Thermal Conductivity ◽  
Thermal Diffusivity ◽  
Microstructural Evolution ◽  
Vickers Hardness ◽  
Room Temperature ◽  
Volume Fraction ◽  
Al2o3 Powder ◽  
Α Al2o3 ◽  
Thermal Diffusivities ◽  
Nano Size

The thermal diffusivities (D) of porous α–Al2O3 specimens prepared from nano-size γ–Al2O3 powder and from conventional submicrometer-size alumina powders were measured at room temperature, and the thermal conductivity (κ) was calculated from D. Plots of κ versus the volume fraction of porosity (P) showed that the data from both sets of samples followed similar linear curves. Similarly, data of Vickers hardness versus P obtained from the same specimens also followed a single linear curve. The good correlation of thermal diffusivity with P suggests that grain boundaries have a lesser effect on thermal transport than porosity.

scholarly journals The Thermal Diffusivity of Glass Sieves: I. Liquid Saturated Frits

2021 ◽  
Vol 42 (4) ◽  
Author(s):  
Ulf Hammerschmidt ◽  
Muhammad Abid
Keyword(s):  
Thermal Conductivity ◽  
Thermal Diffusivity ◽  
Thermal Management ◽  
Electronic Devices ◽  
Lithium Ion ◽  
Expanded Uncertainty ◽  
Conduction Model ◽  
Experimental Findings ◽  
Composite Heat ◽  
Transient Hot Bridge

AbstractThe thermal diffusivity of evacuated and liquid-saturated borosilicate glass sieves (frits) of porosities between 20 % and 48 % is presented as measured at room temperature. The saturants cover a range in thermal diffusivity from 0.091 mm2·s−1 to 0.143 mm2·s−1. The runs were carried out using a transient hot bridge (THB) measuring instrument of an expanded uncertainty of 5 % to 10 %. The experimental results are successfully fitted to a novel transient parallel-serial (TPSC) conduction model for the time-dependent composite heat transfer in porous media. The TPSC-model is an extension of the steady-state parallel-serial conduction (PSC) model to predict the thermal conductivity. The TPSC model confirms the so-called thermal porosity of the frits under test, a term that has been introduced in a former report on the thermal conductivity of the matrices (Hammerschmidt and Abid, Int J Thermophys 42:40, 2021). The experimental findings on the conductive transport of heat by glass sieves and their accurate mathematical description in the framework of the PSC and TPSC models might effectively support improving the thermal management of electronic devices and lithium-ion batteries.

Thermal diffusivity of (Ca1–xSrx)3Co4O9 thin films using transient grating configuration

2003 ◽  
Vol 18 (10) ◽  
pp. 2473-2477 ◽  
Author(s):  
Yoshiaki Takata ◽  
Yutaka Adachi ◽  
Hajime Haneda ◽  
Yoshiki Wada ◽  
Takefumi Mitsuhashi ◽  
...  
Keyword(s):  
Thin Films ◽  
Thermal Diffusivity ◽  
Light Pulse ◽  
Measurement Technique ◽  
Room Temperature ◽  
Optical Diffraction ◽  
Transient Grating ◽  
The Past ◽  
Thermal Diffusivities

The past impossibility to create optical diffraction fringe image out of transparent TiO2(100) substrate was overcome by pumping light pulse of 266-nm wavelength. Thermal diffusivities (D) of TiO2(100) substrate and (Ca1–xSrx)3Co4O9 (0 ≤ x ≤ 0.125) thin films can successfully be determined with a newly proposed transient grating configuration method arising from a generic nanoscale measurement technique. The D values obtained at room temperature were 0.04 cm2/s for the former and 0.07–0.12 cm2/s for the latter, respectively.

Dislocation structures around SiO2 Particles in aged Cu-Cr-SiO2

1978 ◽  
Vol 36 (1) ◽  
pp. 594-595
Author(s):  
N.J. Long ◽  
M.H. Loretto ◽  
C.H. Lloyd
Keyword(s):  
Flow Stress ◽  
Single Crystals ◽  
Room Temperature ◽  
Thin Foil ◽  
Age Hardening ◽  
Dispersion Strengthening ◽  
Accurate Picture ◽  
The Matrix ◽  
Very High ◽  
Good Agreement

IntroductionThere have been several t.e.m. studies (1,2,3,4) of the dislocation arrangements in the matrix and around the particles in dispersion strengthened single crystals deformed in single slip. Good agreement has been obtained in general between the observed structures and the various theories for the flow stress and work hardening of this class of alloy. There has been though some difficulty in obtaining an accurate picture of these arrangements in the case when the obstacles are large (of the order of several 1000's Å). This is due to both the physical loss of dislocations from the thin foil in its preparation and to rearrangement of the structure on unloading and standing at room temperature under the influence of the very high localised stresses in the vicinity of the particles (2,3).This contribution presents part of a study of the Cu-Cr-SiO2 system where age hardening from the Cu-Cr and dispersion strengthening from Cu-Sio2 is combined.

ALCHEMI of B2-Ordered Fe50Al45Me5 alloys

1996 ◽  
Vol 54 ◽  
pp. 548-549
Author(s):  
Ian M. Anderson
Keyword(s):  
Room Temperature ◽  
Iron Aluminide ◽  
Low Density ◽  
Intermetallic Alloys ◽  
Practical Applications ◽  
Alloying Additions ◽  
Site Distribution ◽  
Good Corrosion Resistance ◽  
Room Temperature Ductility ◽  
The Matrix

B2-ordered iron aluminide intermetallic alloys exhibit a combination of attractive properties such as low density and good corrosion resistance. However, the practical applications of these alloys are limited by their poor fracture toughness and low room temperature ductility. One current strategy for overcoming these undesirable properties is to attempt to modify the basic chemistry of the materials with alloying additions. These changes in the chemistry of the material cannot be fully understood without a knowledge of the site-distribution of the alloying elements. In this paper, the site-distributions of a series of 3d-transition metal alloying additions in B2-ordered iron aluminides are studied with ALCHEMI.A series of seven alloys of stoichiometry Fe50AL45Me5, with Me = {Ti, V, Cr, Mn, Co, Ni, Cu}, were prepared with identical heating cycles. Microalloying additions of 0.2% B and 0.1% Zr were also incorporated to strengthen the grain boundaries, but these alloying additions have little influence on the matrix chemistry and are incidental to this study.

The butterfly martensite nucleation in an iron and nickel alloy

1990 ◽  
Vol 48 (4) ◽  
pp. 906-907
Author(s):  
Q.Z. Chen ◽  
X.F. Wu ◽  
T. Ko
Keyword(s):  
Nickel Alloy ◽  
Ethyl Alcohol ◽  
Dislocation Structure ◽  
Martensite Transformation ◽  
Room Temperature ◽  
The Matrix

Some butterfly martensite nuclei were observed in an Fe-27.6Ni-0.89V-0.05C alloy. The alloy was austenitized at 1200°C for 1 hour. Some samples were aged at 850° C for 40 minutes and quenched in 10% brine at room temperature. All the samples were cooled in ethyl alcohol for martensite transformation.A nucleus in an unaged specimen is shown in Fig.1. The nucleus has certain contrast different from the matrix and is shaped like one wing of a butter fly martensite. The SADP of the circled region is measured to be: da=dh, and approximate to dγ(111) and dm(110) with ∠AOB = 55° . It is similar to [011]f.c.c and b patterns in the anglez ∠AOB and the ratio ra/rb, respectively. The SADP shows that the structure of the nucleus is between f.c.c and b.c.c. The dislocation structure within the nucleus is shown in Fig.2. Their Burgers vectors and line directions are also given in it. There are many long dislocations near it without dislocations piled up as shown in Fig.3.Long dislocations are closed at one end as an envelope.

Carbon Capture Performance of Amino-Modified MIL-101 at Room Temperature

2013 ◽  
Vol 395-396 ◽  
pp. 637-640
Author(s):  
Yi Yang ◽  
Zheng Ping Wang ◽  
Ling Meng ◽  
Lian Jun Wang
Keyword(s):  
Carbon Dioxide ◽  
Specific Surface ◽  
Pore Structure ◽  
Carbon Capture ◽  
Room Temperature ◽  
Ambient Pressure ◽  
Metal Organic Framework ◽  
Adsorption Properties ◽  
Carbon Dioxide Adsorption ◽  
Before And After

MIL-101, a metal-organic framework material, was synthesized by the high-temperature hydrothermal method. Triethylenetetramine (TETA) modification enabled the effective grafting of an amino group onto the surface of the materials and their pore structure. The crystal structure, micromorphology, specific surface area, and pore structure of the samples before and after modification were analyzed with an X-ray diffractometer, scanning electron microscope, specific surface and aperture tester, and infrared spectrometer. The carbon dioxide adsorption properties of the samples were determined by a thermal analyzer before and after TETA modification. Results show that moderate amino modification can effectively improve the microporous structure of MIL-101 and its carbon dioxide adsorption properties. After modification, the capacity of MIL-101 to adsorb carbon dioxide decreased only by 0.61 wt%, and a high adsorption capacity of 9.45 wt% was maintained after six cycles of adsorption testing at room temperature and ambient pressure.

Lead inclusions in aluminium

1989 ◽  
Vol 157 ◽  
Author(s):  
E. Johnson ◽  
L. Gråbaek ◽  
J. Bohr ◽  
A. Johansen ◽  
L. Sarholt-Kristensen ◽  
...  
Keyword(s):  
Hysteresis Loop ◽  
Room Temperature ◽  
Noble Gas ◽  
Melting Transition ◽  
X Ray Diffraction ◽  
Free Surfaces ◽  
The Matrix ◽  
Mean Size ◽  
The Mean ◽  
Spontaneous Phase

ABSTRACTIon implantation at room temperature of lead into aluminium leads to spontaneous phase separation and formation of lead precipitates growing topotactically with the matrix. Unlike the highly pressurised (∼ 1–5 GPa) solid inclusions formed after noble gas implantations, the pressure in the lead precipitates is found to be less than 0.12 GPa.Recently we have observed the intriguing result that the lead inclusions in aluminium exhibit both superheating and supercooling [1]. In this paper we review and elaborate on these results. Small implantation-induced lead precipitates embedded in an aluminium matrix were studied by X-ray diffraction. The (111) Bragg peak originating from the lead crystals was followed during several temperature cycles, from room temperature to 678 K. The melting temperature for bulk lead is 601 K. In the first heating cycle we found a superheating of the lead precipitates of 67 K before melting occurred. During subsequent cooling a supercooling of 21 K below the solidification point of bulk lead was observed. In the subsequent heating cycles this hysteresis at the melting transition was reproducible. The full width of the hysteresis loop slowly decreased to 62 K, while the mean size of the inclusions gradually increased from 14.5 nm to 27 nm. The phenomena of superheating and supercooling are thus most pronounced for the small crystallites. The persistence of the hysteresis loop over successive heating cycles demonstrate that its cause is intrinsic in nature, and it is believed that the superheating originates from the lack of free surfaces of the lead inclusions.

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