Fire behavior of flame-retardant polyurethane semi-rigid foam in presence of nickel (II) oxide and graphene nanoplatelets additives

2021 ◽  
Vol 28 (3) ◽  
Author(s):  
Halima Saadiya Ababsa ◽  
Zitouni Safidine ◽  
Ahmed Mekki ◽  
Yves Grohens ◽  
Amina Ouadah ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Fire Behavior ◽  
Graphene Nanoplatelets ◽  
Rigid Foam

Scalable ultrarobust thermoconductive nonflammable bioinspired papers of graphene nanoplatelet crosslinked aramid nanofibers for thermal management and electromagnetic shielding

2021 ◽  
Author(s):  
Minh Canh Vu ◽  
Pyeong Jun Park ◽  
Sa-Rang Bae ◽  
Soo Young Kim ◽  
Young-Min Kang ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Thermal Management ◽  
Electromagnetic Shielding ◽  
Graphene Nanoplatelets ◽  
Emi Shielding ◽  
Graphene Nanoplatelet

Graphene nanoplatelets are chemically crosslinked to aramid nanofibers through a phosphorus trimer to fabricate ultratough, thermoconductive, flame retardant, and EMI shielding films.

scholarly journals Effects of Graphene Nanoplatelets on Mechanical and Fire Performance of Flax Polypropylene Composites with Intumescent Flame Retardant

Molecules ◽  
2021 ◽  
Vol 26 (13) ◽  
pp. 4094
Author(s):  
Imran Ali ◽  
Nam Kyeun Kim ◽  
Debes Bhattacharyya
Keyword(s):  
Flame Retardant ◽  
Decomposition Rate ◽  
Natural Fiber ◽  
Fire Retardant ◽  
Graphene Nanoplatelets ◽  
Intumescent Flame Retardant ◽  
Fume Hood ◽  
Fire Dynamics ◽  
Polypropylene Composites ◽  
Set Up

The integration of intumescent flame-retardant (IFR) additives in natural fiber-based polymer composites enhances the fire-retardant properties, but it generally has a detrimental effect on the mechanical properties, such as tensile and flexural strengths. In this work, the feasibility of graphene as a reinforcement additive and as an effective synergist for IFR-based flax-polypropylene (PP) composites was investigated. Noticeable improvements in tensile and flexural properties were achieved with the addition of graphene nanoplatelets (GNP) in the composites. Furthermore, better char-forming ability of GNP in combination with IFR was observed, suppressing HRR curves and thus, lowering the total heat release (THR). Thermogravimetric analysis (TGA) detected a reduction in the decomposition rate due to strong interfacial bonding between GNP and PP, whereas the maximum decomposition rate was observed to occur at a higher temperature. The saturation point for the IFR additive along with GNP has also been highlighted in this study. A safe and effective method of graphene encapsulation within PP using the fume-hood set-up was achieved. Finally, the effect of flame retardant on the flax–PP composite has been simulated using Fire Dynamics Simulator.

The Study of Melamine Modified by Imidazolium Based Ionic Liquid [BMIM]PF6 on the Flame Retardancy of Rigid Polyurethane Foam

2014 ◽  
Vol 1030-1032 ◽  
pp. 241-245 ◽  
Author(s):  
Yan Wei Li
Keyword(s):  
Ionic Liquid ◽  
Flame Retardant ◽  
Polyurethane Foam ◽  
Fire Retardant ◽  
Rigid Polyurethane Foam ◽  
Flame Resistance ◽  
Initial Decomposition Temperature ◽  
Noticeable Effect ◽  
Rigid Foam ◽  
Flame Retardant Properties

In this paper, the effect of C3H6N6modified by imidazolium based Ionic Liquid 1-butyl-methylimidazolium hexafluorophosphate ([BMIM]PF6) on polyurethane rigid foam flame retardant properties was conducted.The results show that the flame retardant properties of C3H6N6 modified with Ionic Liquid significantly increased and the LOI increased form 22.3 to 24.5. In the modification process, the ionic liquid mass have a very noticeable effect to the flame retardant property and when [BMIM]PF6 and C3H6N6 in quality was 4:6, Fire-retardant effect was best.Compared with the prior to the modification, C3H6N6 modified can increase effective Flame resistance of materials, horizontal burning speed from 67.6mm/min down to 33.4mm/min.Thermal degradation data show that C3H6N6 modified could improve initial decomposition temperature and reminder yield of rigid polyurethane foam,and then heat release reduced, the decomposition controlled,thermal stability increased.

scholarly journals Effects of a Phosphorus Flame Retardant System on the Mechanical and Fire Behavior of Microcellular ABS

Polymers ◽  
2018 ◽  
Vol 11 (1) ◽  
pp. 30 ◽  
Author(s):  
Vera Realinho ◽  
David Arencón ◽  
Marcelo Antunes ◽  
José Velasco
Keyword(s):  
Flame Retardant ◽  
Impact Energy ◽  
Weight Reduction ◽  
Flame Retardants ◽  
Mechanical Performance ◽  
Fire Behavior ◽  
Acrylonitrile Butadiene Styrene ◽  
Injection Molding Process ◽  
Molding Process ◽  
The Impact

The present work deals with the study of phosphorus flame retardant microcellular acrylonitrile–butadiene–styrene (ABS) parts and the effects of weight reduction on the fire and mechanical performance. Phosphorus-based flame retardant additives (PFR), aluminum diethylphosphinate and ammonium polyphosphate, were used as a more environmentally friendly alternative to halogenated flame retardants. A 25 wt % of such PFR system was added to the polymer using a co-rotating twin-screw extruder. Subsequently, microcellular parts with 10, 15, and 20% of nominal weight reduction were prepared using a MuCell® injection-molding process. The results indicate that the presence of PFR particles increased the storage modulus and decreased the impact energy determined by means of dynamic-mechanical-thermal analysis and falling weight impact tests respectively. Nevertheless, the reduction of impact energy was found to be lower in ABS/PFR samples than in neat ABS with increasing weight reduction. This effect was attributed to the lower cell sizes and higher cell densities of the microcellular core of ABS/PFR parts. All ABS/PFR foams showed a self-extinguishing behavior under UL-94 burning vertical tests, independently of the weight reduction. Gradual decreases of the second peak of heat release rate and time of combustion with similar intumescent effect were observed with increasing weight reduction under cone calorimeter tests.

scholarly journals Synthesis of Novel Polymeric Acrylate-Based Flame Retardants Containing Two Phosphorus Groups in Different Chemical Environments and Their Influence on the Flammability of Poly (Lactic Acid)

Polymers ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 778 ◽  
Author(s):  
Jacob Sag ◽  
Philipp Kukla ◽  
Daniela Goedderz ◽  
Hendrik Roch ◽  
Stephan Kabasci ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Mode Of Action ◽  
Flame Retardants ◽  
Fire Behavior ◽  
Heat Fluxes ◽  
Poly Lactic Acid ◽  
Cone Calorimetry ◽  
Scanning Calorimetry ◽  
Fire Scenarios ◽  
Physical Phenomena

Novel polymeric acrylate-based flame retardants (FR 1–4) containing two phosphorus groups in different chemical environments were synthesized in three steps and characterized via nuclear magnetic resonance (NMR) spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and mass spectrometry (MS). Polylactic acid (PLA) formulations with the synthesized compounds were investigated to evaluate the efficiency of these flame retardants and their mode of action by using TGA, UL94, and cone calorimetry. In order to compare the results a flame retardant polyester containing only one phosphorus group (ItaP) was also investigated in PLA regarding its flame inhibiting effect. Since the fire behavior depends not only on the mode of action of the flame retardants but also strongly on physical phenomena like melt dripping, the flame retardants were also incorporated into PLA with higher viscosity. In the UL94 vertical burning test setup, 10% of the novel flame retardants (FR 1–4) is sufficient to reach a V-0 rating in both PLA types, while a loading of 15% of ItaP is not enough to reach the same classification. Despite their different structure, TGA and cone calorimetry results confirmed a gas phase mechanism mainly responsible for the highly efficient flame retardancy for all compounds. Finally, cone calorimetry tests of the flame retardant PLA with two heat fluxes showed different flame inhibiting efficiencies for different fire scenarios.

Fire Behavior of Natural Rubber Filled with Intumescent Flame Retardant Containing Graphite

2019 ◽  
Vol 26 (2) ◽  
pp. 155-164 ◽  
Author(s):  
Aksam Abdelkhalik ◽  
Ghada Makhlouf ◽  
Ahmed Abdel‐Hakim
Keyword(s):  
Natural Rubber ◽  
Flame Retardant ◽  
Fire Behavior ◽  
Intumescent Flame Retardant

scholarly journals Bio-Based Polyamide 1010 with a Halogen-Free Flame Retardant Based on Melamine–Gallic Acid Complex

Polymers ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1482
Author(s):  
Nicoleta Levinta ◽  
Mihai Cosmin Corobea ◽  
Zina Vuluga ◽  
Cristian-Andi Nicolae ◽  
Augusta Raluca Gabor ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Gallic Acid ◽  
Fire Behavior ◽  
Dynamic Mechanical Properties ◽  
Melt Mixing ◽  
Acid Complex ◽  
Limiting Oxygen Index ◽  
Molar Ratios ◽  
Halogen Free ◽  
Polyamide 1010

This work aims at developing polyamide 1010 (PA1010) composites with improved fire behavior using a halogen-free flame-retardant system based on melamine (Me) and gallic acid (GA) complexes (MA). The MA complexes were formed by hydrogen bonding, starting from 1:2, 1:1, 2:1 Me:GA molar ratios. PA1010 composites were obtained by melt mixing, followed by compression molding. MA provided a plasticizing effect on the PA1010 matrix by decreasing the glass transition temperature. The influence of MA on PA1010 chain packaging was highlighted in the X-ray diffraction patterns, mainly in the amorphous phase, but affected also the α and γ planes. This was reflected in the dynamic mechanical properties by the reduction of the storage modulus. H-bonds occurrence in MA complexes, improved the efficiency in the gaseous form during fire exposure, facilitating the gas formation and finally reflected in thermal stability, thermo-oxidative stability, LOI results, and vertical burning behavior results. PA1010 containing a higher amount of GA in the complex (MA12) displayed a limiting oxygen index (LOI) value of 33.6%, much higher when compared to neat PA1010 (25.8%). Vertical burning tests showed that all the composites can achieve the V-0 rating in contrast with neat PA1010 that has V-2 classification.

Effect of Flame Retardant on Mechanical Properties and Flammability of Sisal/PP Composites

2008 ◽  
Vol 47-50 ◽  
pp. 403-406 ◽  
Author(s):  
Nitinat Suppakarn ◽  
Kasama Jarukumjorn ◽  
Saowapa Tananimit
Keyword(s):  
Mechanical Properties ◽  
Flame Retardant ◽  
Natural Fiber ◽  
Fire Behavior ◽  
Sisal Fiber ◽  
Thermo Gravimetric ◽  
Polypropylene Composites ◽  
Thermo Gravimetric Analyzer ◽  
Automotive Parts ◽  
Housing Materials

Due to environmental reasons and their acceptable mechanical properties, natural fiber based polymer composites have been increasingly used in various applications, e.g. housing materials, automotive parts. However, their low thermal resistance and fire behavior limit the use of these materials. In this work, magnesium hydroxide (Mg(OH)2), as a flame retardant, was incorporated into sisal/polypropylene composites. Ratio of sisal fiber to Mg(OH)2 in each composite sample was varied. Maleic anhydride grafted polypropylene (MAPP) was also used to improve the interface of polypropylene and fillers. Flammability and thermal behavior of the composites were examined using a horizontal burning test and thermo gravimetric analyzer, respectively. Morphology and mechanical properties of the composites were also investigated.

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