Nanofiltration Membrane Fouling and Control Caused by Residual Aluminum in Feed Water

2021 ◽  
Vol 233 (1) ◽  
Author(s):  
Hui-Bo Yu ◽  
Xian-Qiu Zhang ◽  
Xue Han ◽  
Zhen-Zhen Yang ◽  
Ya-Wen Zhou ◽  
...  
2003 ◽  
Vol 3 (5-6) ◽  
pp. 183-190
Author(s):  
R. Liikanen ◽  
H. Kiuru ◽  
T. Tuhkanen ◽  
M. Nyström

Nanofiltration is a very effective technique for improving the removal of trace organics after a conventional chemical water treatment train. However, the fouling of the membranes decreases the applicability of the process, and thus, an understanding and control of membrane fouling are crucial for a more widespread use of nanofiltration in water treatment. The fouling of different nanofiltration membranes by pre-treated surface waters was investigated in a laboratory-scale filtration unit in this study. The results indicate that the traditional chemical treatment does not remove membrane foulants from the surface water. No correlation was found between the feed water constituents and nanofiltration performance, but most feed water components are expected to interact in membrane fouling. Actually, the performance of the nanofiltration process was more related to membrane than to feed water characteristics.


2011 ◽  
Vol 11 (3) ◽  
pp. 324-332 ◽  
Author(s):  
Hongwei Bai ◽  
Darren Delai Sun

Hybrid UV/TiO2 photocatalytic oxidation (PCO) and ultrafiltration (UF) process (PCO-UF) were used to remove humic acid (HA) and control membrane fouling. The PCO-UF process showed advantages in terms of higher removal rate of HA, higher permeate flux and less membrane fouling over UF alone and PCO alone on HA removal and membrane fouling control. Membrane material and pH of feed water were shown to be the influence on the performance of PCO-UF process. It was observed that higher pH of HA feed water and a hydrophobic membrane lead to better removal of HA with relatively higher permeate flux. The experimental results in this study demonstrated that 100 kDa ultraflic UF membrane and pH 9 of HA feed water would be the optimal choice for HA removal in the combined PCO-UF process.


2008 ◽  
Vol 8 (4) ◽  
pp. 449-458 ◽  
Author(s):  
J. S. Vrouwenvelder ◽  
C. Hinrichs ◽  
A. R. Sun ◽  
F. Royer ◽  
J. A. M. van Paassen ◽  
...  

Water quality parameters such as ATP, total direct cell counts, AOC, biofilm formation rate and destructive membrane studies are not suitable for biofouling monitoring and prediction. Therefore, a monitor named membrane fouling simulator was developed. In a comparison study, the same feed channel pressure drop development in time and the same fouling accumulation was observed in spiral wound membrane elements and membrane fouling simulators. Chemical dosing to the membrane fouling simulator feed water showed that a biofouling inhibitor was not inhibiting biofouling, but was even contributing to biofouling. It is shown that other chemicals such as acid and antiscalants may contribute to biofouling as well. It was found that the feed spacer presence strongly influences the feed spacer channel pressure drop increase caused by biofilm accumulation: in nanofiltration and reverse osmosis systems biofouling is a feed spacer problem. A new set of monitors for membrane fouling studies and methods for biofouling monitoring are described. A state of the art on global membrane fouling simulator use is given.


2021 ◽  
Vol 3 ◽  
Author(s):  
Andres Felipe Novoa ◽  
Johannes S. Vrouwenvelder ◽  
Luca Fortunato

The use of algal biotechnologies in the production of biofuels, food, and valuable products has gained momentum in recent years, owing to its distinctive rapid growth and compatibility to be coupled to wastewater treatment in membrane photobioreactors. However, membrane fouling is considered a main drawback that offsets the benefits of algal applications by heavily impacting the operation cost. Several fouling control strategies have been proposed, addressing aspects related to characteristics in the feed water and membranes, operational conditions, and biomass properties. However, the lack of understanding of the mechanisms behind algal biofouling and control challenges the development of cost-effective strategies needed for the long-term operation of membrane photobioreactors. This paper reviews the progress on algal membrane fouling and control strategies. Herein, we summarize information in the composition and characteristics of algal foulants, namely algal organic matter, cells, and transparent exopolymer particles; and review their dynamic responses to modifications in the feedwater, membrane surface, hydrodynamics, and cleaning methods. This review comparatively analyzes (i) efficiency in fouling control or mitigation, (ii) advantages and drawbacks, (iii) technological performance, and (iv) challenges and knowledge gaps. Ultimately, the article provides a primary reference of algal biofouling in membrane-based applications.


Membranes ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 380
Author(s):  
Yan Chen ◽  
Huiping Li ◽  
Weihai Pang ◽  
Baiqin Zhou ◽  
Tian Li ◽  
...  

Nanofiltration (NF) is a promising post-treatment technology for providing high-quality drinking water. However, membrane fouling remains a challenge to long-term NF in providing high-quality drinking water. Herein, we found that coupling pre-treatments (sand filtration (SF) and ozone–biological activated carbon (O3-BAC)) and NF is a potent tactic against membrane fouling while achieving high-quality drinking water. The pilot results showed that using SF+O3-BAC pre-treated water as the feed water resulted in a lower but a slowly rising transmembrane pressure (TMP) in NF post-treatment, whereas an opposite observation was found when using SF pre-treated water as the feed water. High-performance size-exclusion chromatography (HPSEC) and three-dimensional excitation–emission matrix (3D-EEM) fluorescence spectroscopy determined that the O3-BAC process changed the characteristic of dissolved organic matter (DOM), probably by removing the DOM of lower apparent molecular weight (LMW) and decreasing the biodegradability of water. Moreover, amino acids and tyrosine-like substances which were significantly related to medium and small molecule organics were found as the key foulants to membrane fouling. In addition, the accumulation of powdered activated carbon in O3-BAC pre-treated water on the membrane surface could be the key reason protecting the NF membrane from fouling.


Author(s):  
Qisheng Ye ◽  
Rui Wang ◽  
Saitao Yan ◽  
Baoliang Chen ◽  
Xiaoying Zhu

Inspired by the stomatal of plant leaves, a photo-responsive membrane was developed to enhance the removal of irreversible membrane fouling and control molecule release. The photo-responsive polymers were prepared by...


2013 ◽  
Vol 3 (3) ◽  
pp. 260-267
Author(s):  
Ho-Young Jeong ◽  
Yoon-Jin Kim ◽  
Ji-Hee Han ◽  
Dong-Ha Kim ◽  
Jinsik Sohn ◽  
...  

Wastewater reclamation is where wastewater from various sources is purified so the water can be used by human consumption. Among many treatment options, membranes have gained an important place in wastewater reclamation. It allows the production of high quality water from wastewater, with a small footprint and affordable energy consumption. Nevertheless, membrane fouling is regarded as a serious problem due to the high fouling potential of wastewater. In this study, we applied ultraviolet (UV) processes as a pretreatment for membrane systems that are used for wastewater reclamation. Low pressure UV (LUV) and pulsed UV (PUV) were used to decompose or alter the organics in the feed water of the membranes. Effluent organic matter was characterized by total organic carbon (TOC) and UV absorbance (UVA). Also the effect of UV pretreatment on membrane fouling was investigated for microfiltration (MF) and reverse osmosis (RO) processes. The pretreatment of membranes using LUV or PUV was effective to control fouling of hollow fiber MF membranes. This is probably because of the reduction and modification of organics after UV treatments. However, the effect of UV pretreatment on RO flux was less significant, which is attributed to low fouling prophecy after MF treatment.


Membranes ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 922
Author(s):  
Xianghao Meng ◽  
Shujuan Meng ◽  
Yu Liu

Microfiltration and ultrafiltration for water/wastewater treatment have gained global attention due to their high separation efficiency, while membrane fouling still remains one of their bottlenecks. In such a situation, many researchers attempt to obtain a deep understanding of fouling mechanisms and to develop effective fouling controls. Therefore, this article intends to trigger discussions on the appropriate choice of foulant surrogates and the application of mathematic models to analyze fouling mechanisms in these filtration processes. It has been found that the commonly used foulant surrogate (sodium alginate) cannot ideally represent the organic foulants in practical feed water to explore the fouling mechanisms. More surrogate foulants or extracellular polymeric substance (EPS) extracted from practical source water may be more suitable for use in the studies of membrane fouling problems. On the other hand, the support vector machine (SVM) which focuses on the general trends of filtration data may work as a more powerful simulation tool than traditional empirical models to predict complex filtration behaviors. Careful selection of foulant surrogate substances and the application of accurate mathematical modeling for fouling mechanisms would provide deep insights into the fouling problems.


Desalination ◽  
2005 ◽  
Vol 178 (1-3) ◽  
pp. 171-178 ◽  
Author(s):  
Zhi Wang ◽  
Yuanyuan Zhao ◽  
Jixiao Wang ◽  
Shichang Wang

Author(s):  
Haruka Takeuchi ◽  
Naoyuki Yamashita ◽  
Norihide Nakada ◽  
Hiroaki Tanaka

This study investigated the removal characteristics of N-Nitrosamines and their precursors at three pilot-scale water reclamation plants. These plants applies different integrated membrane systems: (1) microfiltration (MF)/nanofiltration (NF)/reverse osmosis (RO) membrane; (2) sand filtration/three-stage RO; and (3) ultrafiltration (UF)/NF and UF/RO. Variable removal of N-Nitrosodimethylamine (NDMA) by the RO processes could be attributed to membrane fouling and the feed water temperature. The effect of membrane fouling on N-Nitrosamine removal was extensively evaluated at one of the plants by conducting one month of operation and chemical cleaning of the RO element. Membrane fouling enhanced N-Nitrosamine removal by the pilot-scale RO process. This finding contributes to better understanding of the variable removal of NDMA by RO processes. This study also investigated the removal characteristics of N-Nitrosamine precursors. The NF and RO processes greatly reduced NDMA formation potential (FP), but the UF process had little effect. The contributions of MF, NF, and RO processes for reducing FPs of NDMA, N-Nitrosopyrrolidine and N-Nitrosodiethylamine were different, suggesting different size distributions of their precursors.


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