scholarly journals Hydrocracking diversity in n-dodecane isomerization on Pt/ZSM-22 and Pt/ZSM-23 catalysts and their catalytic performance for hydrodewaxing of lube base oil

2020 ◽  
Vol 17 (6) ◽  
pp. 1752-1763
Author(s):  
Shan-Bin Gao ◽  
Zhen Zhao ◽  
Xue-Feng Lu ◽  
Ke-Bin Chi ◽  
Ai-Jun Duan ◽  
...  
Keyword(s):  
Pour Point ◽  
Viscosity Index ◽  
Carbon Chain ◽  
Catalytic Performance ◽  
High Viscosity ◽  
Vacuum Distillate ◽  
Base Oil

AbstractNobel metallic Pt/ZSM-22 and Pt/ZSM-23 catalysts were prepared for hydroisomerization of normal dodecane and hydrodewaxing of heavy waxy lube base oil. The hydroisomerization performance of n-dodecane indicated that the Pt/ZSM-23 catalyst preferred to crack the C–C bond near the middle of n-dodecane chain, while the Pt/ZSM-22 catalyst was favorable for breaking the carbon chain near the end of n-dodecane. As a result, more than 2% of light products (gas plus naphtha) and 3% more of heavy lube base oil with low-pour point and high viscosity index were produced on Pt/ZSM-22 than those on Pt/ZSM-23 while using the heavy waxy vacuum distillate oil as feedstock.

scholarly journals Synthesis and Characterization of CuO-ZnO Nano Additive for Lubricant

2020 ◽  
Vol 13 (13) ◽  
pp. 33-36
Author(s):  
Buddha Kumar Shrestha ◽  
Hira Mani Trital ◽  
Armila Rajbhandari
Keyword(s):  
Metal Oxide ◽  
Pour Point ◽  
Viscosity Index ◽  
Flash Point ◽  
Nano Particles ◽  
Mixed Metal Oxide ◽  
Lauryl Sulfate ◽  
Copper Strip ◽  
Base Oil ◽  
Mixed Metal

A mixed metal oxide (CuO-ZnO) additives has been successfully synthesized in laboratory by co-precipitation technique. The optimum ratio of CuO and ZnO in mixed metal oxide was found to be 1:1. The sodium lauryl sulfate (SLS) has been used as surfactant. The obtained material was found to be crystalline having crystalline size of 18 nm. The stretching band in FTIR spectra at around 1072 cm-1 to 750 cm-1 and around 600 cm-1 indicates the presence of Zn-O and Cu-O bonds. As prepared nano-particles have been used as nano additive in base oil to improve physio-chemical parameters of lubricants. The results revealed that the additive blended base oil (lubricant) has shown excellent lubrication properties. The higher kinematic viscosity of 33.0504 and 6.0158 at 40°C and 100°C respectively showed that as prepared additive blended lubricant is of ISO-32 category according to ISO grading system for lubricants. Similarly, viscosity index was found to be improved from 101 to 129. The pour point was found to be significantly decreased from -6°C to -24°C. So it can be used as good pour point depressant and could be used even in the extreme cold environment condition. The flash point was found to be increased from 215°C to 220°C indicating that the prepared mixed metal oxide (CuO-ZnO) acts as flash point enhancer. The copper strip corrosion rating was found to be 1b for additive indicating the non corrosive nature. The absence of moisture and pH around the neutral range 6.18 showed the additive blended lubricant is not harmful for machinery devices.

The study of the qualities of light and oil fractions of Azeri oil

2021 ◽  
Vol 02 ◽  
pp. 28-31
Author(s):  
G.S. Mukhtrova ◽  
◽  
Yu.A. Abdullayeva ◽  
R.Z. Hasanova ◽  
S.B. Logmanova ◽  
...  
Keyword(s):  
Sulfur Content ◽  
Pour Point ◽  
Viscosity Index ◽  
Antioxidant Properties ◽  
Hydrocarbon Composition ◽  
Base Oil ◽  
Base Oils ◽  
Oil Fraction ◽  
Oil Fractions ◽  
Light Oil

The article provides research on the qualities of Azeri oil and its light and oil fractions. A characteristic feature of Azeri oil is its high content of light fractions. This oil is light, low-sulfur, and paraffinic. Azeri oil in terms of density, sulfur content, content of light (light) fractions corresponds to marketing grades of oils and is called Azeri Light. Along with light fractions, Azeri Light oil contains up to 30-32% of oil fractions boiling above 350°C. Studies of 50°C oil fractions 350-500°C showed that the viscosity of the fractions at 100°C is in the range of 2.5-10.2 mm2/s, the viscosity index is 72-79.3, and the pour point is 12-36°С, potential content of base oils - 25.73%, their hydrocarbon composition, %: n-paraffinic oils - 50.7; isoparaffinic + naphthenic - 10.67; aromatic - 8.94%. Using traditional methods of purification using a selective solvent, followed by dewaxing and hydrotreating, from 50°C oil fractions of Azeri oil, base oils with a viscosity of 4.2-9.0 mm2/s at 100°C and a viscosity index of 91.0 can be obtained - 95.8, pour point minus 15°С / minus 20°С. By cleaning a wide oil fraction of 350-500°C, it is possible to obtain a base oil with a viscosity at 100 C of 6.5 mm2/s (SAE 20), a viscosity index of 95, a pour point of minus 15°C, an oil yield (350-500°C) is 20.3% for distillate (12.4% for oil). In terms of saturated hydrocarbons content (≥90%, sulfur content less than 0.03%), viscosity index > 90, the oil has good antioxidant properties and can be assigned to API group II.

scholarly journals Lubrication properties of dodecanedioate esters-based bio-lubricant

2020 ◽  
Vol 9 (2) ◽  
pp. 1117-1125
Keyword(s):  
Friction Coefficient ◽  
Oxidative Stability ◽  
Pour Point ◽  
Viscosity Index ◽  
Carbon Chain ◽  
Flash Point ◽  
Carbon Chain Length ◽  
Low Friction ◽  
Chemical Structures ◽  
Lubrication Properties

Interest in the synthesis of new bio-lubricants with improved lubricity properties and higher quality is increasing. This study aimed to evaluate the bio-lubrication properties of synthesized dodecanedioate esters-based bio-lubricant. Thirteen samples of dodecanedioate esters with different chemical structures were synthesized. The results showed that di-2-methylbutyl dodecanedioate (D2MBD), di-2-ethylbutyl dodecanedioate (D2EBD), and di-2-ethylhexyl dodecanedioate (D2EHD) showed good low-temperature properties with very low pour point (PP) values of -45 oC, -35 oC, and -55 oC, respectively. Di-oleyl dodecanedioate (DOlD) showed a remarkable flash point (FP) value of 300 oC; however, it showed poor oxidative stability (OXS) at 177 oC. The results showed increases in flash point (FP), viscosity index (VI), and oxidative stability (OXT) with increasing carbon chain length and branching in the employed alcohol. Furthermore, friction coefficient, Newtonian and non-Newtonian properties were tested. The results showed that the tested dodecanedioate esters, which have high molecular weight had a low friction coefficient, and they were classified as non-Newtonian fluids except DOLD was classified as a Newtonian fluid. In general, based on the results, the branched dodecanedioate esters can be used as lubricant without additives.

Oligomerization of 1-Butylene to Lubricant Catalyzed by Bis(tetramethyl cyclopentadienyl) Zirconium Dichloride/MAO

2013 ◽  
Vol 634-638 ◽  
pp. 659-663
Author(s):  
Mei Chao Chen ◽  
Huai Qi Shao ◽  
Tao Jiang
Keyword(s):  
Pour Point ◽  
Average Molecular Weight ◽  
Viscosity Index ◽  
Catalyst System ◽  
Reaction Conditions ◽  
Base Oil ◽  
Molar Ratios ◽  
Co Catalysts ◽  
H Nmr ◽  
Optimal Reaction

Oligomerization of 1-butylene catalyzed by Bis(tetramethylcyclopentadienyl) Zirconium dichloride/MAO was investigated in detail under different conditions including reaction temperature, Al/Zr molar ratios, co-catalysts, concentration of catalyst to determine the optimal reaction conditions. The work shown that oligomer of 1-butylene in this catalyst system featured a kind of base oil of lubricant with pour point of -22 °C, kinematic viscosity of 2999 mm2/s at 40 °C and 2530 mm2/s at 100 °C, viscosity index of 258 and a moderate average molecular weight. In addition, the oligomer obtained was characterized by 1H-NMR and IR.

scholarly journals Advanced Study of Promoted Pt /SAPO-11 Catalyst for Hydroisomerization of the n-Decane Model and Lube Oil

2021 ◽  
Vol 22 (2) ◽  
pp. 17-26
Author(s):  
Haider Aljendeel ◽  
Hussein Qasim Hussein
Keyword(s):  
Pour Point ◽  
Flow Reactor ◽  
Viscosity Index ◽  
Plug Flow ◽  
Fixed Bed ◽  
Space Velocity ◽  
Lubricating Oil ◽  
Bet Surface Area ◽  
Isomerization Reaction ◽  
Base Oil

   SAPO-11 is synthesized from silicoaluminophosphate in the presence of di-n-propylamine as a template. The results show that the sample obtained has good crystallinity, 396m2/g BET surface area, and 0.35 cm3/g pore volume. The hydroisomerization activity of (0.25)Pt (1)Zr (0.5)W/SAPO-11 catalyst was determined using n-decane and base oil. All hydroisomerization experiments of n-decane were achieved at a fixed bed plug flow reactor at a temperature range of 200-275°C and  LHSV 0.5-2h-1.  The results show that the n-decane conversion increases with increasing temperature and decreasing LHSV, the maximum conversion of 66.7 % was achieved at temperature 275°C and LHSV of 0.5 h-1. Meanwhile, the same catalyst was used to improve base oil specification by increasing viscosity index and decreasing pour point. The isomerization reaction conditions, employed are temperature (200-300)ºC, the liquid hourly space velocity of 0.5-2h-1, and the pressure kept atmospheric. The present study shows that Pt Zr W/SAPO-11 minimizes the pour point of lubricating oil to -16°C at isomerization temperature of  300°C and LHSV of 0.5 h-1 and viscosity index 134.8.

Development of a Proximate IR Spectrometric Method for the Determination of Base Oil Viscosity, Viscosity Index, and Pour Point

2016 ◽  
Vol 52 (1) ◽  
pp. 76-84
Author(s):  
B. P. Tonkonogov ◽  
V. A. Dorogochinskaya ◽  
L. N. Bagdasarov ◽  
E. V. Mozhaiskaya
Keyword(s):  
Pour Point ◽  
Viscosity Index ◽  
Spectrometric Method ◽  
Oil Viscosity ◽  
Base Oil

Rheometric Studies of New Class Ionic Liquid Nanolubricants

2017 ◽  
Author(s):  
Sayavur I. Bakhtiyarov ◽  
Dennis A. Siginer
Keyword(s):  
Ionic Liquid ◽  
Vapor Pressure ◽  
Viscosity Index ◽  
High Viscosity ◽  
Parallel Plates ◽  
Space Applications ◽  
Base Oil ◽  
Mineral Oils ◽  
New Class ◽  
Materials Used

The traditional lubricating materials used in space, such as mineral oils, polyol ester, PFPE, Pennzane, etc. have limited lifetimes in vacuum due to the catalytic degradation on metal surfaces, high vaporization at high temperatures, dewetting, and other disadvantages. The lubricants for the space applications must have vacuum stability (i.e. low vapor pressure), high viscosity index (wide liquid range), low creep tendency, good elastohydrodynamic and boundary lubrication properties, radiation atomic oxygen resistance, optical or infrared transparency. Thermophysical and chemical analyses are another important required set of tests for the newly developed space lubricants. Some of these properties for liquid lubricants are base oil and additive volatility, creep, surface tension, viscosity, chemical composition, weight loss, density, vapor pressure, etc. Unfortunately, the properties such as non-linearity in the rheological behavior of the lubricants were not studied well for newly developed systems. The rheological properties are crucial to analyzing thermodynamic and energy dissipative aspects of the lubrication process. The rheological measurements for the newly developed ionic liquid nanolubricant were conducted using rotational rheometer AES G-2 of “parallel-plates” mode.

scholarly journals Pengaruh Penambahan Minyak Kelapa dan Sawit Terhadap Sifat Fisik dan Tribologi Pelumas SAE 40

Jurnal METTEK ◽  
2019 ◽  
Vol 5 (1) ◽  
pp. 1
Author(s):  
Dedison Gasni ◽  
KM Abdul Razak ◽  
Ahmad Ridwan ◽  
Muhammad Arif
Keyword(s):  
Fatty Acids ◽  
Coefficient Of Friction ◽  
Tribological Properties ◽  
Palm Oil ◽  
Boundary Lubrication ◽  
Viscosity Index ◽  
Coconut Oil ◽  
High Viscosity ◽  
Mineral Oil ◽  
Lubricating Oil

Penelitian ini bertujuan untuk mengetahui efek dari penambahan minyak kelapa dan sawit terhadap sifat fisik dan tribologi pelumas SAE 40. Vegetabel oil, seperti; minyak kelapa dan sawit, memiliki nilai viskositas indek yang tinggi dan sifat pelumasan yang baik terutama didaerah boundary lubrication jika dibandingkan dengan mineral oil (SAE 40). Hal ini disebabkan karena vegetabel oil memiliki kandungan fatty acids yang tidak dimiliki oleh mineral oil. Keunggulan lain dari minyak kelapa dan sawit adanya sifat yang ramah lingkungan karena mudah terurai di alam dan dapat diperbaharui. Pada penelitian ini sifat yang baik dari minyak kelapa dan sawit ini akan dimanfaatkan sebagai zat aditif pada minyak pelumas SAE 40. Pengujian dilakukan terhadap sifat fisik dan tribology dengan penambahan 5%, 10%, 15%, dan 20% berat dari minyak kelapa dan sawit ke dalam minyak pelumas SAE 40. Pengujian sifat fisik terdiri dari pengukuran viskositas pada temperatur 400C dan 1000C dan viskositas index. Pengujian sifat tribologi untuk menentukan keausan dan koefisien gesek berdasarkan ASTM G99 dengan menggunakan alat uji pin on disk. Dari hasil pengujian diperoleh bahwa dengan penambahan minyak kelapa dan sawit kedalam minyak pelumas SAE 40 terjadi peningkatan viskositas indeks. Peningkatan viskositas indeks sebanyak  17% dengan penambahan 20% minyak sawit. Terjadi perubahan sifat tribologi dengan penambahan minyak sawit, berupa penurunan keausan dan nilai koefisien gesek dibandingkan dengan penambahan minyak kelapa. This study aims to determine the effect of coconut and palm oils as additives to physical and tribological properties of SAE 40 lubricating oil . Vegetable oils, such as; coconut oil and palm oil, have high viscosity index and good lubrication properties, especially in boundary lubrication compared to mineral oil. This is due to vegetable oil having fatty acids that are not owned by mineral oil. The advantages of coconut oil and palm oil are environmentally friendly properties because they are biodegradable and renewable. In this study, the good properties of coconut and palm oils will be used as additives in SAE 40 lubricating oil. Tests are carried out on the physical and tribological properties with the addition of 5%, 10%, 15%, and 20% by weight of coconut and palm oils into SAE 40 lubricating oil. Physical properties testing consists of measuring viscosity at temperatures of 400C and 1000C and viscosity index. The tribological test is to determine wear and coefficient of friction based on ASTM G99 using a pin on disc test equipment. From the test results,  it was found that coconut and palm oils as additives into SAE 40 lubricating oil could increase in viscosity index. The increase of  the viscosity index was 17% by adding 20% of palm oil. There was a change of tribological properties in the form of decreasing on the wear and the coefficient of friction with the addition of palm oil compare to addition of coconut oil.

Synthesis and Evaluation of Some Polymeric Compounds as Pour Point Depressants and Viscosity Index Improvers for Lube Oil

2008 ◽  
Vol 26 (12) ◽  
pp. 1390-1402 ◽  
Author(s):  
N. S. Ahmed ◽  
A. M. Nassar ◽  
R. M. Nasser ◽  
A. F. Khattab ◽  
A.-A. A. Abdel-Azim
Keyword(s):  
Pour Point ◽  
Viscosity Index ◽  
Polymeric Compounds ◽  
Pour Point Depressants ◽  
Viscosity Index Improvers
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