scholarly journals Assessment of Uncertainty in Long-Term Mass Balances for Acidification Assessments: A MAGIC Model Exercise

AMBIO ◽  
2011 ◽  
Vol 40 (8) ◽  
pp. 891-905 ◽  
Author(s):  
S. J. Köhler ◽  
T. Zetterberg ◽  
M. N. Futter ◽  
J. Fölster ◽  
S. Löfgren
Keyword(s):  
1988 ◽  
Vol 19 (2) ◽  
pp. 99-120 ◽  
Author(s):  
A. Lepistö ◽  
P. G. Whitehead ◽  
C. Neal ◽  
B. J. Cosby

A modelling study has been undertaken to investigate long-term changes in surface water quality in two contrasting forested catchments; Yli-Knuutila, with high concentrations of base cations and sulphate, in southern Finland; and organically rich, acid Liuhapuro in eastern Finland. The MAGIC model is based on the assumption that certain chemical processes (anion retention, cation exchange, primary mineral weathering, aluminium dissolution and CO2 solubility) in catchment soils are likely keys to the responses of surface water quality to acidic deposition. The model was applied for the first time to an organically rich catchment with high quantities of humic substances. The historical reconstruction of water quality at Yli-Knuutila indicates that the catchment surface waters have lost about 90 μeq l−1 of alkalinity in 140 years, which is about 60% of their preacidification alkalinity. The model reproduces the declining pH levels of recent decades as indicated by paleoecological analysis. Stream acidity trends are investigated assuming two scenarios for future deposition. Assuming deposition rates are maintained in the future at 1984 levels, the model indicates that stream pH is likely to continue to decline below presently measured levels. A 50% reduction in deposition rates would likely result in an increase in pH and alkalinity of the stream, although not to estimated preacidification levels. Because of the high load of organic acids to the Liuhapuro stream it has been acid before atmospheric pollution; a decline of 0.2 pH-units was estimated with increasing leaching of base cations from the soil despite the partial pH buffering of the system by organic compounds.


1998 ◽  
Vol 44 (147) ◽  
pp. 333-351 ◽  
Author(s):  
B.T. Rabus ◽  
K. A. Echelmeyer

AbstractMcCall Glacier has the only long-term mass-balance record in Arctic-Alaska. Average annual balances over the periods 1958–72 and 1972–93 were –15 and –33cm, respectively; recent annual balances (1993–96) are about –60 cm, and the mass-balance gradient has increased. For an Arctic glacier, with its low mass-exchange rate, this marks a significant negative trend.Recently acquired elevation profiles of McCall Glacier and ten other glaciers within a 30 km radius were compared with topographic maps made in 1956 or 1973. Most of these glaciers had average annual mass balances between –25 and –33 cm, while McCall Glacier averaged –28 cm for 1956–93, indicating that it is representative of the region. In contrast, changes in terminus position for the different glaciers vary markedly. Thus, mass-balance trends in this region cannot be estimated from fractional length changes at time-scales of a few decades.We developed a simple degree-day/accumulation mass-balance model for McCall Glacier. The model was tested using precipitation and radiosonde temperatures from weather stations at Inuvik, Canada, and Barrow, Kaktovik and Fairbanks, Alaska, and was calibrated with the measured balances. The Inuvik data reproduce all measured mass balances of McCall Glacier well and also reproduce the long-term trend towards more negative balances. Data from the other stations do not produce satisfactory model results. We speculate that the Arctic Front, oriented east–west in this region, causes the differences in model results.


2009 ◽  
Vol 40 (2-3) ◽  
pp. 198-216 ◽  
Author(s):  
Anne Merete S. Sjøeng ◽  
Richard F. Wright ◽  
Øyvind Kaste

MAGIC (the Model of Acidification of Groundwater In Catchments) has been widely applied on catchments all over the world. The model has been used with annual time resolution to simulate the long-term effects of acidic deposition on surface water chemistry. Here MAGIC was applied using a monthly time step. The purpose was to simulate observed seasonal nitrate (NO3) concentrations and fluxes at an upland heathland catchment in southwestern Norway during the period 1993–2004. The rates of the key ecosystem nitrogen (N) processes (mineralization, plant uptake, litterfall and immobilization) were assumed to be governed by temperature. A snow accumulation and melt routine was used. The rates were calibrated to obtain the best match between the observed and simulated NO3 patterns. The best fit was obtained with standard yearly cycles for deposition and N parameters. The results show that MAGIC can explain 68 and 88% of the variation in seasonal NO3 concentrations and fluxes, respectively. The calibrated model provides a tool for exploring the effects of future scenarios of climate change and N deposition on NO3 in streamwater.


2015 ◽  
Vol 9 (1) ◽  
pp. 1133-1175 ◽  
Author(s):  
J. Gabbi ◽  
M. Huss ◽  
A. Bauder ◽  
F. Cao ◽  
M. Schwikowski

Abstract. Light-absorbing impurities in snow and ice control glacier melt as shortwave radiation represents the main component of the surface energy balance. Here, we investigate the long-term effect of snow impurities, i.e. Saharan dust and black carbon (BC), on albedo and glacier mass balance. The analysis was performed over the period 1914–2014 for two sites on Claridenfirn, Swiss Alps, where an outstanding 100 year record of seasonal mass balance measurements is available. Information on atmospheric deposition of mineral dust and BC over the last century was retrieved from two firn/ice cores of high-alpine sites. A combined mass balance and snow/firn layer model was employed to assess the dust/BC-albedo feedback. Compared to pure snow conditions, the presence of Saharan dust and BC lowered the mean annual albedo by 0.04–0.06 and increased melt by 15–19% on average depending on the location on the glacier. BC clearly dominated absorption which is about three times higher than that of mineral dust. The upper site has experienced mainly positive mass balances and impurity layers were continuously buried whereas at the lower site, surface albedo was more strongly influenced by re-exposure of dust-enriched layers due to frequent years with negative mass balances.


2015 ◽  
Vol 98 (10) ◽  
pp. 7052-7070 ◽  
Author(s):  
Sebastian Cela ◽  
Quirine M. Ketterings ◽  
Karl Czymmek ◽  
Melanie Soberon ◽  
Caroline Rasmussen

1994 ◽  
Vol 30 (8) ◽  
pp. 225-234 ◽  
Author(s):  
Robert H. Kadlec

Four Florida wetlands have been studied, by various groups, to provide data on hydrology, biota, and water chemistry. A subset of that data is here further analysed to determine the unifying principles of phosphorus removal. The uptake of this nutrient was found to be first order on an areal basis for long term average performance. Flow-through wetlands exhibit strong gradients in the direction of flow. The first order rate equation was used in conjunction with mass balances on water, soils and biota for water and phosphorus, to determine values of the rate constant ranging from 6.4 to 13 m/yr.


1997 ◽  
Vol 54 (12) ◽  
pp. 2789-2795 ◽  
Author(s):  
Lewis A Molot ◽  
Peter J Dillon

Colour and dissolved organic carbon (DOC) concentrations and mass balances were measured for seven unproductive lakes and 20 tributary streams between June 1980 and May 1992. Individual observations of colour, which measures an unknown DOC fraction assumed to be principally humic, were not good predictors of discrete DOC concentrations for any of the study sites. Long-term mean colour was, however, strongly correlated with long-term mean DOC concentrations in streams and lakes. Colour behaved differently from the total DOC pool in lakes. Lake retention and loss coefficients for colour were always higher than corresponding values for the total DOC pool, and the mean annual colour/DOC ratios in lake outflows were always less than the corresponding ratios in lake inputs, indicating that the coloured fraction was preferentially removed or photooxidized. A steady-state mass balance model was used to estimate the upper bound for the average coloured fraction of DOC in each lake. The upper bound for the seven lakes ranged from 34 to 88%, increasing with increasing colour, DOC, and total phosphorus.


1984 ◽  
Vol 41 (8) ◽  
pp. 1256-1268 ◽  
Author(s):  
Eville Gorham ◽  
Suzanne E. Bayley ◽  
David W. Schindler

Certain types of peatlands are probably highly susceptible to anthropogenic acidification, yet very little research is being done on the vulnerability of bogs and fens to acid deposition. We have documented the need for such research and for studies of the role of acidification — natural and anthropogenic — in determining nutrient availability, metal mobilization, and biogeochemical cycling by fauna and microflora. Possible effects of hydrological changes, and of drainage from acid peatlands to lakes and streams, are noted. We provide an outline of possible responses of plants and animals to acidification; these should be investigated at species, community, and ecosystem levels. Studies of peatlands as possible sources of the gaseous precursors of acid deposition are needed. Different approaches to examining the responses of peatlands to acid deposition include geographical surveys, experimental studies, short-term, long-term, and paleoecological investigations, and analysis of biogeochemical mass-balances. Finally, we emphasize the need for inclusive studies of peatlands in relation to surrounding uplands and to the streams and lakes that receive their drainage.


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