Insight into high areal capacitances of low apparent surface area carbons derived from nitrogen-rich polymers

Carbon ◽  
2015 ◽  
Vol 94 ◽  
pp. 560-567 ◽  
Author(s):  
Xiaozhong Wu ◽  
Jin Zhou ◽  
Wei Xing ◽  
Yu Zhang ◽  
Peng Bai ◽  
...  
Keyword(s):  
2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Handuo Shi ◽  
Yan Hu ◽  
Pascal D. Odermatt ◽  
Carlos G. Gonzalez ◽  
Lichao Zhang ◽  
...  

AbstractThe steady-state size of bacterial cells correlates with nutrient-determined growth rate. Here, we explore how rod-shaped bacterial cells regulate their morphology during rapid environmental changes. We quantify cellular dimensions throughout passage cycles of stationary-phase cells diluted into fresh medium and grown back to saturation. We find that cells exhibit characteristic dynamics in surface area to volume ratio (SA/V), which are conserved across genetic and chemical perturbations as well as across species and growth temperatures. A mathematical model with a single fitting parameter (the time delay between surface and volume synthesis) is quantitatively consistent with our SA/V experimental observations. The model supports that this time delay is due to differential expression of volume and surface-related genes, and that the first division after dilution occurs at a tightly controlled SA/V. Our minimal model thus provides insight into the connections between bacterial growth rate and cell shape in dynamic environments.


2019 ◽  
Vol 43 (3) ◽  
pp. 1230-1237 ◽  
Author(s):  
Mingcai Yin ◽  
Wenli Zhang ◽  
Hui Li ◽  
Chaojun Wu ◽  
Fangfang Jia ◽  
...  

The specific surface area and composition are found to be the key factors influencing the photocatalytic performance of MoS2+x.


1973 ◽  
Vol 95 (4) ◽  
pp. 521-527 ◽  
Author(s):  
L. C. Witte ◽  
T. J. Vyas ◽  
A. A. Gelabert

Molten metals, (mercury, lead, zinc, bismuth, tin, and aluminum) were quenched in water and liquid nitrogen. High-speed photographs provide insight into the fragmentation phenomenon. The key to the vapor explosion is the very rapid transfer of heat which requires substantial surface area: fragmentation provides this necessary surface area. Prior fragmentation theories are examined in light of these experiments and are found to be inadequate. This study indicates strongly that fragmentation occurs when a sample is molten and fragmentation is a response to an external stimulus. Alternate causes of fragmentation are proposed and are predicated upon the initial collapse of a vapor film around the molten metal. The data also show that energy required to form new surface area and to displace water during the fragmentation phenomenon is not significant when compared to the energy available in a molten sample.


2002 ◽  
Vol 80 (2) ◽  
pp. 286-295 ◽  
Author(s):  
Eileen A Hebets

While the unique sensory system and neuroanatomy of amblypygids suggest that olfaction is important in their lives, to date no behavioral data exist to support this suggestion. To gain insight into amblypygid ecology and behavior, an individual mark–recapture study was conducted on the Costa Rican amblypygid Phrynus parvulus. Within two 50 by 25 m plots, the distribution and movement patterns of individual amblypygids were recorded for over 2 months. A total of 88 adult individuals (60 males and 28 females) were marked, with an average 51% resighted. Females were resighted more frequently than males (75% females, 40% males). The sexes did not differ in their frequency or movement distance, but females were more likely to be seen on the same tree over time. While both sexes potentially wander in search of mates, females may also be searching for a good crevice, or diurnal hideout. Once a female has mated and laid eggs, she likely remains stationary. Movement patterns and tree choice seem to be dictated by both the presence of conspecifics and environmental factors such as tree surface area, moss cover, and the presence of buttressing. Cumulative observational data collected over 3 years suggest that the main breeding season for this species is October-January. Both mate attraction and navigation may be facilitated by the olfactory capabilities of amblypygids, while their giant interneurons may be involved in their foraging behavior.


Author(s):  
Mark D. Haynes ◽  
Chih-Hang John Wu ◽  
Matthew Arnold ◽  
Naga Narendra B. Bodapati ◽  
B. Terry Beck ◽  
...  

The purpose of this research is to establish mathematical models that predicts the bond strength of a reinforcement wire in prestressed concrete members, given the known geometrical features of the wire. A total of nineteen geometrical features of the reinforcement wire were measured and extracted by a precision non-contact profilometer. With these mathematical models, prestressing reinforcement wires can now be analyzed for their bond strength without destructive testing. These mathematical models, based upon a large collection of empirical data via prestressing reinforcement wires from various wire manufacturers in US and Europe, have the potential to serve as quality assessment tools in reinforcement wire and prestressed concrete member production. Most of these models are very simple and easy to implement in practice, which could provide insight into which reinforcement wires provide the greatest bond strength and which combinations of geometrical features of the reinforcement wire are responsible for providing the bond strength. Our various empirical models have shown that the indent side-wall angle, which is suggested by the ASTM-A881/A881M, may not be the only significant geometrical feature correlated to the transfer length and bond strengths. On the contrary, features such as the indent surface area, indent width, indent edge surface area, indent volume, and release strengths do have significant correlations with the ultimate transfer lengths of the prestressed concrete members. Extensive experiments and testing performed at the Structures Laboratory in Kansas State University, as well as field tests at Transportation Technology Center, Inc. (TTCI) and one Prestressed Concrete Railroad Tie manufacturing facility, have been used to confirm the model predictions. In addition, our experimental results suggest that the maximum pull out force in the un-tensioned pullout testing has significant correlation with the ultimate transfer length. This finding could provide reinforcement wire manufactures with a quality assurance tool for testing their wires prior to the production. The resultant mathematical model relating the wire geometrical features to transfer length is referred to as the Bond Index Number (BIN). The BIN is shown to provide a numerical measure of the bond strength of prestressing steel reinforcement wire, without the need for performing destructive tests with the reinforcement wire. We believe that with the BIN and the maximal pull-out forces from the un-tensioned pull-out tests, one can have better insight into the optimal reinforcement wire design by testing the performance of wires before they are put into production lines.


Catalysts ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1160
Author(s):  
Safia Syazana Mohtar ◽  
Farhana Aziz ◽  
Ahmad Fauzi Ismail ◽  
Nonni Soraya Sambudi ◽  
Hamidah Abdullah ◽  
...  

The effect of ion doping and the incorporation of additives on photocatalysts’ textural properties have been reviewed. Generally, it can be summarised that ion doping and additives have beneficial effects on photocatalytic efficiency and not all have an increase in the surface area. The excessive amount of dopants and additives will produce larger aggregated particles and also cover the mesoporous structures, thereby increasing the pore size (Pd) and pore volume (Pv). An excessive amount of dopants also leads to visible light shielding effects, thus influence photocatalytic performance. Ion doping also shows some increment in the surface areas, but it has been identified that synergistic effects of the surface area, porosity, and dopant amount contribute to the photocatalytic performance. It is therefore important to understand the effect of doping and the application of additives on the textural properties of photocatalysts, thus, their performance. This review will provide an insight into the development of photocatalyst with better performance for wastewater treatment applications.


2014 ◽  
Vol 172 ◽  
pp. 473-496 ◽  
Author(s):  
Jonathan Quinson ◽  
Ricardo Hidalgo ◽  
Philip A. Ash ◽  
Frank Dillon ◽  
Nicole Grobert ◽  
...  

We present a study of electrocatalysis by an enzyme adsorbed on a range of carbon materials, with different size, surface area, morphology and graphitic structure, which are either commercially available or prepared via simple, established protocols. We choose as our model enzyme the hydrogenase I from E. coli (Hyd-1), which is an active catalyst for H2 oxidation, is relatively robust and has been demonstrated in H2 fuel cells and H2-driven chemical synthesis. The carbon materials were characterised according to their surface area, surface morphology and graphitic character, and we use the electrocatalytic H2 oxidation current for Hyd-1 adsorbed on these materials to evaluate their effectiveness as enzyme electrodes. Here, we show that a variety of carbon materials are suitable for adsorbing hydrogenases in an electroactive configuration. This unified study provides insight into selection and design of carbon materials for study of redox enzymes and different applications of enzyme electrocatalysis.


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