Vertically aligned silicon carbide nanowires/reduced graphene oxide networks for enhancing the thermal conductivity of silicone rubber composites

Author(s):  
Jianan Song ◽  
Yong Zhang
2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Joanna Wilk ◽  
Robert Smusz ◽  
Ryszard Filip ◽  
Grzegorz Chmiel ◽  
Tomasz Bednarczyk

Abstract Graphene oxide/rubber composites were experimentally investigated for obtaining their thermal properties. Three kinds of the composite matrix material have been used: NBR, HNBR and FKM. The reduced graphene oxide in the form of crumped flakes has been applied as the filler influencing on thermal conductivity of the composites. Two values of graphene oxide weight concentration have been taken into account in the investigation. Thermal conductivity of the composites and basic matrix has been measured by the professional apparatus with the use of the guarded heat plate method. Before measurements the preliminary tests using the simplified comparative method have been performed. The results obtained, both from preliminary tests and using the guarded heat plate method, show an increase in thermal conductivity with increasing the reduced graphene oxide content in the composite. The experimental investigation allowed to determine not only the increase in thermal properties of graphene oxide/rubber composites compared to the basic matrix, but also the absolute values of thermal conductivities. Additionally, the SEM analysis showed that the tested composite samples contain agglomerates of the rGO nanoparticles. The occurrence of agglomerates could affect the composite thermal properties. This was noticed in the comparatively measurements of the temperature of different composites during the heating of samples tested. The maximum enhancement of thermal conductivity obtained was about 11% compared to the basis matrix of the composites tested.


Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1254 ◽  
Author(s):  
Weijie Liang ◽  
Xin Ge ◽  
Jianfang Ge ◽  
Tiehu Li ◽  
Tingkai Zhao ◽  
...  

With developments of the electronics industry, more components are being included in electronic devices, which has led to challenges in thermal management. Using reduced graphene oxide embedded with MQ silicone resin (RGO/MQ) nano-aggregates as the composite filler and silicone rubber (SR) as the matrix, a simple approach is designed to prepare RGO/MQ/SR composites. Reduced graphene oxide (RGO) was first used as a substrate for the growth of MQ silicone resin by hybridization, forming sandwich-like micro structured RGO/MQ nano-aggregates successfully. Then, RGO/MQ was integrated into α,ω-dihydroxylpolydimethylsiloxane based on the in situ solvent-free blending method, followed by condensation and vulcanization, fabricating the final RGO/MQ/SR composites. The effective strategy could enhance the adaptability between graphene and silicone matrix under external stimuli at room temperature by embedding nanoscale MQ into the interface of graphene/silicone as the buffer layer. Obvious improvements were found in both thermal conductivity and mechanical properties due to excellent dispersion and interfacial compatibility of RGO/MQ in the host materials. These attractive results suggest that this RGO/MQ/SR composite has potential as a thermal interface material for heat dissipation applications.


2021 ◽  
pp. 151270
Author(s):  
Jiana Hu ◽  
Caiyun Liang ◽  
Jiadong Li ◽  
Yongjiu Liang ◽  
Shangyu Li ◽  
...  

Author(s):  
Kaiming Guo ◽  
Firdoz Shaik ◽  
Jine Yang ◽  
Bin Jiang

Abstract Water splitting is considered as a potential sustainable and green technology for producing mass hydrogen and oxygen. A cost-effective self-supported stable electrocatalyst with excellent electrocatalytic performance in a wide pH range is greatly required for water splitting. This work reports on the synthesis and anchoring of Fe1CoxNiyP nanoparticles on vertically aligned reduced graphene oxide array (VrGO) via electroless plating. The catalytic activity of Fe1CoxNiyP nanoparticles is tuned finely by tailoring the cationic ratio of Co and Ni. Fe1Co2Ni1P/VrGO exhibits the lowest overpotential (58 and 110 mV) at 10 mA cm−2 and lowest tafel slope (31 and 33 mV dec−1) for hydrogen evolution reaction in 1.0 M KOH and 0.5 M H2SO4 respectively. Fe1Co1Ni2P/VrGO exhibits the lowest overpotential (173 mV) at 10 mA cm−2 with lowest tafel slope (47 mV dec-1) for oxygen evolution reaction. The enhanced performance of the electrocatalyst is attributed to improved electrical conductivity, synergistic effects and beneficial electronic states caused by the appropriate atomic ratio of Co and Ni in the bifunctional electrocatalyst. This study helps to explore the effect of variable cationic ratio in the cost-effective ternary iron group metal phosphides electrocatalysts to achieve enhanced electrocatalytic performance for water splitting in a wide pH range.


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