Preparation of thiol-functionalized activated carbon from sewage sludge with coal blending for heavy metal removal from contaminated water

2018 ◽  
Vol 234 ◽  
pp. 677-683 ◽  
Author(s):  
Juan Li ◽  
Xing Xing ◽  
Jiao Li ◽  
Mei Shi ◽  
Aijun Lin ◽  
...  
Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1907
Author(s):  
Fatma Hussain Emamy ◽  
Ali Bumajdad ◽  
Jerzy P. Lukaszewicz

Optimizing the physicochemical properties of the chitosan-based activated carbon (Ch-ACs) can greatly enhance its performance toward heavy metal removal from contaminated water. Herein, Ch was converted into a high surface area (1556 m2/g) and porous (0.69 cm3/g) ACs with large content of nitrogen (~16 wt%) using K2CO3 activator and urea as nitrogen-enrichment agents. The prepared Ch-ACs were tested for the removal of Cr(VI) and Pb(II) at different pH, initial metal ions concentration, time, activated carbon dosage, and temperature. For Cr(VI), the best removal was at pH = 2, while for Pb(II) the best pH for its removal was in the range of 4–6. At 25 °C, the Temkin model gives the best fit for the adsorption of Cr(VI), while the Langmuir model was found to be better for Pb(II) ions. The kinetics of adsorption of both heavy metal ions were found to be well-fitted by a pseudo-second-order model. The findings show that the efficiency and the green properties (availability, recyclability, and cost effectiveness) of the developed adsorbent made it a good candidate for wastewaters treatment. As preliminary work, the prepared sorbent was also tested regarding the removal of heavy metals and other contaminations from real wastewater and the obtained results were found to be promising.


2021 ◽  
Vol 897 ◽  
pp. 109-115
Author(s):  
Sri Martini ◽  
Kiagus Ahmad Roni ◽  
Dian Kharismadewi ◽  
Erna Yuliwaty

This review article presents the usage of various animal bones such as chicken bone, fish bone, pig bone, camel bone, and cow bone as reliable biosorbent materials to remove heavy metals contained in contaminated water and wastewater. The sources and toxicity effects of heavy metal ions are also discussed properly. Then specific insights related to adsorption process and its influential factors along with the proven potentiality of selected biosorbents especially derived from animal bone are also explained. As the biosorbents are rich in particular organic and inorganic compounds and functional groups in nature, they play an important role in heavy metal removal from contaminated solutions. Overall, after conducting study reports on the literature, a brief conclusion can be drawn that animal bone waste has satisfactory efficacy as effective, efficient, and environmentally friendly sorbent material.


2020 ◽  
Vol 242 ◽  
pp. 116822 ◽  
Author(s):  
Degang Ma ◽  
Meizhong Su ◽  
Jingjing Qian ◽  
Qian Wang ◽  
Fanyi Meng ◽  
...  

2002 ◽  
Vol 45 (10) ◽  
pp. 287-292 ◽  
Author(s):  
D. Lowrie ◽  
J. Hobson ◽  
D.C. Stuckey

A new, closed loop process for the disinfection, stabilisation and removal of heavy metal from sewage sludge (consisting of a sludge/sulfuric acid reactor, hybrid H2S generator and H2S bioscrubber) is described. Preliminary results for total solids (TS), volatile suspended solids (VSS), chemical oxygen demand (COD), acetate and propionate destruction in the hybrid H2S generator have shown that digestion efficiency is not compromised in a hybrid reactor generating H2S compared to a methanogenic reactor. 70% of the electron flow in the hybrid H2S generator was diverted to methane at a COD:SO4 ratio of 5.45:1. Enough H2SO4 could be generated from the H2S emitted at this ratio to effect sufficient metal solubilisation and pathogen removal from primary sludge.


2008 ◽  
Vol 28 (12) ◽  
pp. 2709-2722 ◽  
Author(s):  
H. Mattenberger ◽  
G. Fraissler ◽  
T. Brunner ◽  
P. Herk ◽  
L. Hermann ◽  
...  

2021 ◽  
Author(s):  
Jun Nie

Removal of heavy metal contaminants from sewage sludge is a necessity before it is used as an agricultural fertilizer (biosolid), due to environmental concerns and municipal, provincial and federal regulations. The bioleaching method is recommended as an economical and effective process for the removal of heavy metals from the Ashbridges Bay Treatment Plant (ABTP) sludge, some of them with concentrations exceeding the recommended level by the Ontario Ministry of Agriculture, Food, and Rural Affairs guidelines. The Gram-negative thiobacilli is a group of organisms with physiological and morphological similarity and grows by oxidizing ferrous ion and reduced sulphur compounds. One species of thiobacillus, T. ferrooxidan , was recommended as an effective bacterium for the heavy metal removal from sewage sludge. This research involved the incubation of adapted sludge using fresh raw digested sludge and activated sludge of ABTP. Using adapted sludge for the bioleaching process, the method was tested in a continuously stirred tank reactor (CSTR) in combination with a series of jar tests. Results showed that the metal removal efficiency increases with decreasing pH, and the solids content does not affect the removal efficiency of cupper and zinc very much during short term jar test. The results from the long-term (20-day) CSTR test demonstrated that the high T ferrooxians-contained adapted sludge could remove copper from the sewage sludge of ABTP very effectively, by as much as 79.2%. In comparison, the simultaneous removal efficiency of zinc and cadmium were also studied for the same process and, they are 82.0% and 83.9% respectively. The TSS degradation constant rate during the 20 days' bioleaching was found to be 0.0522 day -1. It is concluded that Ontario should continue to apply sludge to agricultural land, as sludge is an economic alternative, promotes recycling of resources, and is a valuable fertilizer. However, the toxic metals in sludge should be removed from sewage sludge using the bioleaching process to recommended level before it is disposed as a fertilizer for land application.


2015 ◽  
Vol 18 (1) ◽  
pp. 88-99 ◽  
Author(s):  
Thouraya Bohli ◽  
Abdelmottaleb Ouederni ◽  
Nuria Fiol ◽  
Isabel Villaescusa

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