Effect of MWCNT content and thickness of photoanode on microcracks in QDSCs

2021 ◽  
Vol 123 ◽  
pp. 108341
Author(s):  
Wei Zheng ◽  
Hongquan Sun
Keyword(s):  
2018 ◽  
Vol 915 ◽  
pp. 104-109
Author(s):  
Barış Demirbay ◽  
Şaziye Uğur

Electrical characteristics and morphology of nanocomposite films composed of two different polystyrene (PS) latexes impregnated with multi-walled carbon nanotubes (MWCNT) in the range between 0 wt% and 20 wt% were assessed by considering photon transmission (UV-Vis) technique and electrical conductivity measurements. Emulsion polymerization technique was employed both to synthesize very fine PS particles dispersed in water and to tailor the sizes of the PS particles as 382 nm and 560 nm, respectively. PS/MWCNT nanocomposite films were obtained from the liquid form on glass substrates via drop-casting method and all they dried at 40 QUOTE C. Each dried sample was then annealed at varying temperatures between 100 QUOTE C and 250 QUOTE C for 10 min. The surface conductivity QUOTE of each annealed film at 250 QUOTE C was measured and was found to increase dramatically above a certain mass fraction of MWCNT content, QUOTE . Each set of PS/MWCNT nanocomposite film had a similar electrical percolation threshold of QUOTE =1.5 wt% as the MWCNT content and critical exponents of QUOTE were found to be 2.64 and 1.19 for 382 nm and 560 nm PS latex systems, respectively.


Author(s):  
Pardis Ghahramani ◽  
Kamran Behdinan ◽  
Hani E. Naguib

Polymer foam nanocomposites attract great interest in many wide ranges of biomedical and healthcare monitoring applications. In this study, we investigated the effect of porosity and multi-walled carbon nanotube (MWCNT) content on the piezoresistivity, sensitivity, and mechanical properties of Polydimethylsiloxane (PDMS)/MWCNT foam nanocomposite. The foam nanocomposites were fabricated by particulate leaching method and their electrical and mechanical characteristics were investigated using the different porosity levels (60% and 70%) and different conductive nanofiller contents (0.5 wt.% and 1 wt.%). The foam nanocomposites with 0.5 wt.% MWCNT content and 60% porosity possessed higher pressure sensitivity, higher gage factor, and lower electrical hysteresis along with higher mechanical properties. Moreover, fabricated PDMS/MWCNT foam nanocomposite demonstrated high flexibility, high compressibility, and high recoverability in addition to limited mechanical hysteresis (less than 3%) with a large dynamic sensing range. Contrary to the existing foam nanocomposite samples in the literature, PDMS/MWCNT foam nanocomposites withstood higher pressure ranges (3.5–5 MPa) at limited thickness (average 2.3 mm) without experiencing noticeable macroscopic damage.


2019 ◽  
Vol 168 ◽  
pp. 572-580 ◽  
Author(s):  
Pei Wang ◽  
Guanyu Deng ◽  
Hongtao Zhu ◽  
Hongbo Zhang ◽  
Jian Yin ◽  
...  

2011 ◽  
Vol 694 ◽  
pp. 713-717
Author(s):  
Z. F. Fan ◽  
X.H. Chen ◽  
L.S. Xu ◽  
Y. Q. Liu ◽  
W. B. Zhong ◽  
...  

A unique method for preparation of multi-walled carbon nanotube (MWCNT)- reinforced copper composite is reported. It involves solution phase systhesis MWCNT-implanted cuprous oxide composite spheres, formation of MWCNT/ copper composite spheres after reduction in H2 atmosphere and preparation of the MWCNT/copper bulk with vacuum hot pressing. Scanning Eelectron Microscope image (SEM) of the fracture surfaces indicate MWCNTs are homogeneously dispersed in the composite and bonded to the matrix. In addition, the thermal expansion of the composites at various MWCNTs (0wt%, 1wt%, 5wt%) were investigated. The coefficient of the thermal expansion (CTE) was decreased with increase of the MWCNT content, which are all much lower than that of pure copper.


2020 ◽  
Vol 9 (2) ◽  
pp. 51-62
Author(s):  
Mohd Moonis Zaheer

This paper presents the investigation on the behaviour of a prism reinforced with multi walled carbon nanotubes (MWCNTs) to study mainly the strength and durability aspects for structural applications. Prisms were made by varying the MWCNT content from 0.1 to 0.5% by weight of cement. Ultrasonic energy was employed to disperse carbon nano tubes (CNTs) in water. For evaluating mechanical property such as load-deflection, tests were performed on CNT admixed prisms under flexure. The outcomes were then compared with plain mortar prisms. An attempt has also been made to explore the optimum concentration of MWCNT additions that will give ideal performance with respect to mechanical and durability properties. Flexural and compressive strength is enhanced by 25% and 19%, respectively compared to control prisms at 28 days when CNT was used in the cementitious matrix. Both porosity and water absorption are reduced by about 25% at 28 days. Based on the parametric study, a tentative optimum CNT concentration (0.3% by weight of cement) has been proposed. SEM images shows perfect crack bridging mechanism; several of the CNTs were shown as crack arrestor across the fine cracks along with some CNTs breakage.


2021 ◽  
Vol 1057 (1) ◽  
pp. 012004
Author(s):  
Sarat Chandra Mohanty ◽  
Anup Kumar Jana ◽  
Ranjith Kumar Rachakonda ◽  
Gummadi Manoj Kumar ◽  
A S N S R Teja

2021 ◽  
Vol 2021 ◽  
pp. 1-15 ◽  
Author(s):  
B. Stalin ◽  
M. Ravichandran ◽  
Alagar Karthick ◽  
M. Meignanamoorthy ◽  
G. T. Sudha ◽  
...  

Copper (Cu) metal matrix composite (MMC) was developed with multiwall carbon nanotubes (MWCNT) as reinforcement by using powder metallurgy (PM) technique. The composition of the composites is Cu, Cu-4 wt% MWCNT, Cu-8 wt% MWCNT, and Cu-12 wt% MWCNT. The Cu and MWCNTs were blended for 6 hours in a ball mill and compacted at a 6 ton pressure to form green compacts using a 10 ton hydraulic press. Using a tubular furnace, the heat was applied at 900°C for 1.5 hours to impart strength and integrity to the green compacts. Milled composite blends were studied to analyze its characterization through SEM and EDAX analysis. Characterization studies such as SEM and EDAX confirm the presence and even dispersion of Cu and MWCNT constituents. The relative density, hardness, and ultimate compressive strength have been studied, and a remarkable improvement in properties has been obtained by the inclusion of MWCNTs. The composites reinforced by 8 and 12 wt% MWCNT were recorded with low thermal conductivity than the Cu composite reinforced by 4 wt% MWCNT. A wear study was analyzed using Taguchi technique for determining the effect caused by the wear test parameters and MWCNT content on wear rate. The optimized parameter that contributes minimum wear rate was identified as 12 wt% MWCNT content, 10 N applied load, 2 m/s sliding velocity, and 500 m sliding distance. Based on the obtained results, it could be understood that the produced composites can be utilized for various applications like relay contact springs and switchgear, rotor bars, and bus bars.


Fluids ◽  
2020 ◽  
Vol 5 (4) ◽  
pp. 241
Author(s):  
Karolina Brzóska ◽  
Bertrand Jóźwiak ◽  
Adrian Golba ◽  
Marzena Dzida ◽  
Sławomir Boncel

In this work, thermal conductivity, viscosity, isobaric heat capacity, and density of stable carbon-based nanofluids are presented. The nanofluids under study are composed of 1,2-ethanediol (ethylene glycol, EG) and long multi-walled carbon nanotubes (MWCNTs), so-called ‘in-house 16h’ (synthesized in our laboratory via catalytic chemical vapor deposition during 16 h with a diameter of 60–80 nm and length of 770 μm). Poly(N-vinylpyrrolidone) (PVP) was used to increase the stability of nanofluids. The nanofluids were prepared via an ultrasonication-assisted, three-step method while their key thermophysical characteristics were obtained using the hot-wire technique and rotary viscometer. As a result, the addition of MWCNTs significantly improved the thermal conductivity of nanofluids by 31.5% for the highest 1.0 wt% (0.498 vol%) long MWCNT content, leaving the Newtonian character of the nanofluids practically intact.


Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 181 ◽  
Author(s):  
Jake Thibodeau ◽  
Anna Ignaszak

A polyacrylamide-alginate hydrogel electrolyte, blended with Multi-Walled Carbon Nanotubes (MWCNT) as an electronically conductive fraction, allows for the creation of a flexible, durable, and resilient electrode. The MWCNT content is correlated with mechanical characteristics such as stretch modulus, tensile resistance, and electrical conductivity. The mechanical analysis demonstrates tensile strength that is comparable to similar hydrogels reported in the literature, with increasing strength for MWCNT-embedded hydrogels. The impedance spectroscopy reveals that the total resistance of electrodes decreases with increasing MWCNT content upon elongation and that bending and twisting do not obstruct their conductivity. The MWCNT-inserted hydrogels show mixed ionic and electronic conductivities, both within a range of 1–4 × 10−2 S cm−1 in a steady state. In addition, the thermal stability of these materials increases with incrementing MWCNT content. This observation agrees with long-term charge-discharge cycling that shows enhanced electrochemical durability of the MWCNT-hydrogel hybrid when compared to pure hydrogel electrolyte. The hydrogel-carbon films demonstrate an increased interfacial double-layer current at a high MWCNT content (giving an area-specific capacitance of ~30 mF cm−2 at 2.79 wt.% of MWCNT), which makes them promising candidates as printable and flexible electrodes for lightweight energy storage applications. The maximum content of MWCNT within the polymer electrolyte was estimated at 2.79 wt.%, giving a very elastic polymer electrode with good electrical characteristics.


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