Thermal cycling, shear and insulating characteristics of epoxy embedded Sn-3.0Ag-0.5Cu (SAC305) solder paste for automotive applications

2017 ◽  
Vol 704 ◽  
pp. 795-803 ◽  
Author(s):  
Ashutosh Sharma ◽  
Young-Joo Jang ◽  
Jang Baeg Kim ◽  
Jae Pil Jung
Keyword(s):  
Thermal Cycling ◽  
Solder Paste ◽  
Automotive Applications ◽  
Sac305 Solder

scholarly journals Study on the Reliability of Sn–Bi Composite Solder Pastes with Thermosetting Epoxy under Thermal Cycling and Humidity Treatment

Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 733
Author(s):  
Lu Liu ◽  
Songbai Xue ◽  
Ruiyang Ni ◽  
Peng Zhang ◽  
Jie Wu
Keyword(s):  
Solder Joint ◽  
Thermal Cycling ◽  
Composite Solder ◽  
Solder Joints ◽  
Solder Paste ◽  
Epoxy System ◽  
Mechanical Reinforcement ◽  
Microstructure Observation ◽  
Temperature And Humidity ◽  
Thermosetting Epoxy

In this study, a Sn–Bi composite solder paste with thermosetting epoxy (TSEP Sn–Bi) was prepared by mixing Sn–Bi solder powder, flux, and epoxy system. The melting characteristics of the Sn–Bi solder alloy and the curing reaction of the epoxy system were measured by differential scanning calorimeter (DSC). A reflow profile was optimized based on the Sn–Bi reflow profile, and the Organic Solderability Preservative (OSP) Cu pad mounted 0603 chip resistor was chosen to reflow soldering and to prepare samples of the corresponding joint. The high temperature and humidity reliability of the solder joints at 85 °C/85% RH (Relative Humidity) for 1000 h and the thermal cycle reliability of the solder joints from −40 °C to 125 °C for 1000 cycles were investigated. Compared to the Sn–Bi solder joint, the TSEP Sn–Bi solder joints had increased reliability. The microstructure observation shows that the epoxy resin curing process did not affect the transformation of the microstructure. The shear force of the TSEP Sn–Bi solder joints after 1000 cycles of thermal cycling test was 1.23–1.35 times higher than the Sn–Bi solder joint and after 1000 h of temperature and humidity tests was 1.14–1.27 times higher than the Sn–Bi solder joint. The fracture analysis indicated that the cured cover layer could still have a mechanical reinforcement to the TSEP Sn–Bi solder joints after these reliability tests.

scholarly journals Suppression of the Growth of Intermetallic Compound Layers with the Addition of Graphene Nano-Sheets to an Epoxy Sn–Ag–Cu Solder on a Cu Substrate

Materials ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 936 ◽  
Author(s):  
Min-Soo Kang ◽  
Do-Seok Kim ◽  
Young-Eui Shin
Keyword(s):  
Intermetallic Compound ◽  
Isothermal Aging ◽  
Solder Joints ◽  
Solder Paste ◽  
Shear Tests ◽  
Sac305 Solder ◽  
Epoxy Solder ◽  
The Relationship ◽  
Bonding Characteristics ◽  
Preventive Effects

This study investigated the suppression of the growth of the intermetallic compound (IMC) layer that forms between epoxy solder joints and the substrate in electronic packaging by adding graphene nano-sheets (GNSs) to 96.5Sn–3.0Ag–0.5Cu (wt %, SAC305) solder whose bonding characteristics had been strengthened with a polymer. IMC growth was induced in isothermal aging tests at 150 °C, 125 °C and 85 °C for 504 h (21 days). Activation energies were calculated based on the IMC layer thickness, temperature, and time. The activation energy required for the formation of IMCs was 45.5 KJ/mol for the plain epoxy solder, 52.8 KJ/mol for the 0.01%-GNS solder, 62.5 KJ/mol for the 0.05%-GNS solder, and 68.7 KJ/mol for the 0.1%-GNS solder. Thus, the preventive effects were higher for increasing concentrations of GNS in the epoxy solder. In addition, shear tests were employed on the solder joints to analyze the relationship between the addition of GNSs and the bonding characteristics of the solder joints. It was found that the addition of GNSs to epoxy solder weakened the bonding characteristics of the solder, but not critically so because the shear force was higher than for normal solder (i.e., without the addition of epoxy). Thus, the addition of a small amount of GNSs to epoxy solder can suppress the formation of an IMC layer during isothermal aging without significantly weakening the bonding characteristics of the epoxy solder paste.

Creep Behavior of Various Materials Within PBGA Packages Subjected to Thermal Cycling Loading

2020 ◽  
Author(s):  
Abdullah Fahim ◽  
Kamrul Hasan ◽  
Jeffrey C. Suhling ◽  
Pradeep Lall
Keyword(s):  
Solder Joint ◽  
Thermal Cycling ◽  
Creep Behavior ◽  
Creep Deformation ◽  
Nanoindentation Test ◽  
Electronic Packages ◽  
Sac305 Solder ◽  
Die Attachment ◽  
Nanoindentation Technique ◽  
Solder Mask

Abstract Electronic packages are frequently exposed to a thermal cycling environment in real life applications. Particularly, the plastic ball grid array (PBGA) is one of the most widely used electronic package, and consists of various component materials, e.g. solder joint, silicon die, die attachment adhesive, mold compound, solder mask, etc. All of these materials play a significant role on the reliability of the overall package. Failure under creep deformation is one of the significant failure mode for electronic packages. Hence, it is important to study their creep behavior and evolution under the thermal cycling environment. These changes must be evaluated in order to understand and predict their failure behavior due to creep damage in operation. In our previous study, evolution of mechanical properties of SAC305 solder joints in a PBGA package up to 250 thermal cycles was evaluated using the nanoindentation technique. In this work, nanoindentation technique was utilized to understand the evolution of creep behavior of the SAC305 solder joint, die attachment adhesive, silicon die, and solder mask material for various durations of thermal cycling. Test specimens were first prepared by cross sectioning a PBGA package to reveal the different materials, followed by surface polishing to facilitate SEM imaging and nanoindentation testing. After preparation, the package samples were thermally cycled from T = −40 to 125 °C in an environmental chamber. At various points in the cycling (e.g. after 0, 50, 100, 250 and 500 cycles), the package was taken out from the chamber, and nanoindentation was performed on above mentioned materials to obtain creep behavior at room temperature (25 °C). From the nanoindentation test data, it was found that creep deformation of SAC305 increased upto 500 cycles. Die attachment and solder mask materials showed initial decrease in creep deformation up to 250 cycles and then increased value at 500 cycles. As expected, the silicon die material does not show any significant change in creep deformation behavior upto 500 cycles.

Development of BiAgX® HT Solder Paste for 200°C Application

2016 ◽  
Vol 2016 (HiTEC) ◽  
pp. 000128-000133 ◽  
Author(s):  
Hongwen Zhang ◽  
Jonathan Minter ◽  
Ning-Cheng Lee
Keyword(s):  
Shear Strength ◽  
Thermal Cycling ◽  
Melting Temperature ◽  
Thermal Aging ◽  
Joint Strength ◽  
Solder Paste ◽  
Thermal Cycling Test ◽  
Cycling Test ◽  
Die Attach ◽  
Board Level

Abstract BiAgX® paste with the remelting temperature around 262°C has been tested and adopted successfully for die attach applications [1–5]. BiAgX® HT pastes with the enhanced remelting temperature above 265°C have been designed for the application of 200°C or even higher. The joint strength has been well maintained for most of the tested pastes after thermal aging @ 200°C for 1000hrs. The thermal cycling test (from −55°C to 200°C) degrades the bond shear strength but some of the tested pastes can still keep the joint strength well above IEC standard (IEC 60749-19) required. The melting temperature and the reliability have been observed to closely associate with the alloying elements Z%wt. The BiAgX® pastes have also been modified for board level assembly application. BiAgX® solder wire is under development too.

Advanced DBC - Highly Reliable and Conductive Copper Ceramic Substrates

2016 ◽  
Vol 2016 (CICMT) ◽  
pp. 000073-000078
Author(s):  
Paul Gundel ◽  
Anton Miric ◽  
Kai Herbst ◽  
Melanie Bawohl ◽  
Jessica Reitz ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Thermal Cycling ◽  
Power Electronics ◽  
Thick Film ◽  
Low Cost ◽  
Automotive Applications ◽  
Ceramic Substrates ◽  
Hybrid Technologies

Abstract So far Direct Bonded Copper (DBC) substrates have been the standard for power electronics. They provide excellent electrical and thermal conductivity at low cost. Weaknesses of DBC technology are the inevitable warpage and the relatively low reliability under thermal cycling. The low reliability poses a significant hurdle in particular for automotive applications with high lifetime requirements. Thick Print Copper (TPC) substrates with low warpage and excellent reliability overcome these weaknesses, but also provide a reduced conductivity at a higher cost. We present two thick-film/DBC hybrid technologies which combine the best properties of DBC and TPC: excellent conductivity, low cost, reduced warpage and excellent reliability.

HIGH RELIABILITY HIGH MELTING LEAD-FREE MIXED BIAGX SOLDER PASTE SYSTEM

2012 ◽  
Vol 2012 (1) ◽  
pp. 000119-000126 ◽  
Author(s):  
HongWen Zhang ◽  
Ning-Cheng Lee
Keyword(s):  
Thermal Cycling ◽  
Thermal Aging ◽  
High Reliability ◽  
Solder Paste ◽  
High Melting ◽  
Mixed Powder ◽  
Alloy Solder ◽  
Dislocation Movement ◽  
Melting Lead ◽  
High Lead

In the current work, a mixed solder powder BiAgX solder paste system with the melting temperature above 260°C and the comparable or even better reliability to the high lead solders has been studied. The mixed solder powder paste system is composed of a high melting first alloy solder powder as majority and the additive solder powder as minority. The additive solder is designed to react aggressively with various surface finish materials before or together with the melting of the majority solder to form a controllable IMC layer. The IMC layer of the mixed powder system is controllable by the species and the quantity of the additive solder and it is observed to be insensitive to thermal aging and thermal cycling in current tests while the high lead ones do show a considerable increase in IMC layer thickness. Microstructure investigation shows the fishbone shape IMC layer interlocks the bonding interface between solder and components. Both micron-sized and nano-sized Ag-rich precipitations in the joints have been observed to be well distributed in the joint. The exposed Ag-rich particles and the surrounding stepwise pattern in Bi matrix on the fracture surface indicate that these Ag-rich particles constrain the dislocation movement in Bi matrix thus enhance the strength and the ductility of the joint. Under thermal aging and thermal cycling, both the micron-sized and nano-sized Ag-rich precipitations exhibit only discernible and localized coarsening. The stable interfacial IMC together with the existence of the well dispersed Ag-rich particles are attributed to the promising reliability in BiAgX solder paste system.

The Reliability Impact of Reballing COTS Pb-Free BGAs to Sn/Pb for Military Applications

2011 ◽  
Vol 2011 (1) ◽  
pp. 000703-000710
Author(s):  
Greg Caswell ◽  
Joelle Arnold
Keyword(s):  
Thermal Cycling ◽  
Hazardous Substances ◽  
Post Processing ◽  
Sac305 Solder ◽  
Post Process ◽  
Physical Testing ◽  
Solder Balls ◽  
Commercial Off The Shelf ◽  
Tin Silver Copper ◽  
The Cost

The electronics assembly market has experienced a material shift from lead (Pb) based solders to Pb-free solders. This is a result of the widespread adoption of Reduction of Hazardous Substances (RoHS) legislation and practices in commercial industry. As a result, it is becoming increasingly difficult to procure commercial off-the-shelf (COTS) components with tin-lead (SnPb) solder balls or finish. There are essentially three responses to the scarcity of acceptable SnPb parts: custom order, post process or adapt. Custom ordering parts with SnPb finishes negates the benefits of COTS based acquisition; however, has a reduced reliability risk because the material and processes are known. Reprocessing parts once in house saves money because the parts are COTS, but expends money and resources by performing post processing on them. Also, the additional touch labor and handling increases the risk of damaging the part. Finally, adapting to Pb-free finishes is the preferred long term approach because it preserves the cost benefits of using COTS parts and does not require post processing. It is the riskiest approach due to the lack of historical data in the DoD environment. This paper presents results regarding reballing 208 I/O Ball Grid Array (BGA) parts from tin-silver-copper (SAC305) solder to SnPb eutectic solder. It is important to understand the reliability risks associated with the reballing procedure, particularly as it relates to thermal cycling, shock and vibration environments. Three major efforts will be presented to answer these concerns. First, a survey of reballing vendors was performed to better understand the processes and variables associated with that industry. The results of that survey were used to down-select to five vendors that were used for the physical testing portion of the effort. Finally, physical testing consisting of thermal cycling, shock, and vibration was performed. The physical testing was performed on parts from the five different reballing vendors as well as native SnPb parts and native SAC305 parts. The results of these activities will be presented.

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