Optical and thermal behaviors of high efficient K 2 TiF 6 :Mn 4+ red phosphor prepared by modified two-step co-precipitation method

2016 ◽  
Vol 83 ◽  
pp. 316-323 ◽  
Author(s):  
Miaomiao Du ◽  
Fei Tang ◽  
Jiaqi Long ◽  
Chaoyang Ma ◽  
Xuanyi Yuan ◽  
...  
Materials ◽  
2020 ◽  
Vol 13 (4) ◽  
pp. 874
Author(s):  
Haifeng Wang ◽  
Jianwei Lu ◽  
Ruoxuan Wang ◽  
Yungu Dong ◽  
Linfeng Ding

The synthesis process has a significant influence on the properties of Ca1-xTiO3:Eu3+x phosphors; thus, an optimized process will lead to a better performance of the Ca1-xTiO3:Eu3+x phosphors. In this work, the feasibility of synthesizing the Ca1-xTiO3:Eu3+x phosphor with a good luminescent performance by combining the chemical co-precipitation method and microwave-assisted sintering was studied. The precursor of Ca1-xTiO3:Eu3+x phosphors were prepared by the chemical co-precipitation method. To find an optimized process, we applied both of the traditional (furnace) sintering and the microwave-assisted sintering to synthesize the Ca1-xTiO3:Eu3+x phosphors. We found out that a sintering power of 528 W for 50 min (temperature around 950 °C) by a microwave oven resulted in similar emission intensity results compared to traditional furnace sintering at 900 °C for 2.5 h. The synthesized Ca1-xTiO3:Eu3+x phosphors has an emission peak at 617 nm (5D0→7F2), which corresponds to the red light band. This new synthesized method is an energy efficient, time saving, and environmentally friendly means for the preparation of Ca1-xTiO3:Eu3+x red phosphor with good luminescent performance.


2017 ◽  
Vol 5 (29) ◽  
pp. 7253-7261 ◽  
Author(s):  
L. Y. Wang ◽  
E. H. Song ◽  
Y. Y. Zhou ◽  
T. T. Deng ◽  
S. Ye ◽  
...  

Phosphor Rb2ZrF6:Mn4+has been synthesizedviaa co-precipitation method. Series of WLEDs were fabricated by combining YAG:Ce3+yellow phosphor and different amount of Rb2ZrF6:Mn4+red phosphor with InGaN blue chips.


2020 ◽  
Vol 7 (18) ◽  
pp. 3371-3378
Author(s):  
Yang Zhou ◽  
Xiaoming Wang ◽  
Cuiping Wang ◽  
Tian Zhang ◽  
Yonggang Wang ◽  
...  

A novel red fluoride phosphor BaNbF7:Mn4+ was synthesized by co-precipitation method. Under UV and blue light excitation, this phosphor shows strong ZPL emission intensity at 630 nm and which makes it an attractive red phosphor candidate for WLEDs.


2017 ◽  
Vol 5 (11) ◽  
pp. 2910-2918 ◽  
Author(s):  
T. T. Deng ◽  
E. H. Song ◽  
J. Sun ◽  
L. Y. Wang ◽  
Y. Deng ◽  
...  

Herein, a new red phosphor Na3GaF6:Mn4+ has been designed and synthesized by a facile two-step co-precipitation method at room temperature.


2018 ◽  
Vol 914 ◽  
pp. 87-95
Author(s):  
Di Wu ◽  
Xin Yu Ye ◽  
Xin Hua Yang ◽  
Fan Liu ◽  
Jian Wen Zhao ◽  
...  

Sc0.88Lu0.05(V1-xPx)O4:Eu3+0.07(0≤x≤0.5) phosphors were synthesized by co-precipitation method. The structure, morphology and luminescence spectra of samples were investigated by XRD, SEM and fluorescence spectrophotometer, respectively. The samples doped with Eu3+, Lu3+and PO43-can maintain the body-centered tetragonal structure of ScVO4and the morphology essentially remains unchanged with slight agglomeration. The excitation spectrum intensity of Sc0.88Lu0.05(V1-xPx)O4:Eu3+0.07increase within the near UV excitation (360-410nm). The optimum doping concentration of PO43-is 0.2(x value), and the maximum emission intensity of Sc0.88Lu0.05(V0.8P0.2)O4:Eu3+0.07is about 35 % higher than the Sc0.88Lu0.05VO4:Eu3+0.07under 365 nm excitation. Decay curve of5D0state for as-prepared samples fits the single order exponential behavior, the lifetime of5D0increase first and then decrease with the increase of PO43-doping concentration. The internal quantum efficiency is up to 66.73% under 365nm excitation, When the temperature rises to 200°C, the emission intensity maintains 79.3% of that in the room temperature. Sc0.88Lu0.05(V0.8P0.2)O4:Eu3+0.07phosphor shows high internal quantum efficiency and thermal stability, which is suitable for the UV-pumped white LED as red phosphor.


2010 ◽  
Vol 148-149 ◽  
pp. 1469-1472
Author(s):  
Chao Jun Liu ◽  
Yue Hua Xu

Monoclinic BiVO4 photocatalysts were synthesized via facile and straightforward co-precipitation method at room temperature without high temperature treatment and characterized with X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), flourier transfer infrared spectroscopy (FT-IR), Brunauer-Emmett-Teller (BET), and transmission electron microscopy (TEM). The results indicate that through proper selection of synthesis conditions, it is possible to obtain high efficient BiVO4 nanoparticles. The as-prepared monoclinic BiVO4 photocatalysts have an average crystallite size of about 20 nm with the particle size of about 20 to 50 nm. Their photocatalytic activities were evaluated by decolorization of rhodamine B in aqueous solution under visible light irradiation, and the relationship between the photocatalytic activity of BiVO4 and their physicochemical properties were investigated.


Crystals ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 219 ◽  
Author(s):  
Tien A. Nguyen ◽  
V. Pham ◽  
Thanh L. Pham ◽  
Linh T. Tr. Nguyen ◽  
I. Ya. Mittova ◽  
...  

In this study, a nanostructured NdFeO3 material was synthesized via a simple process of the hydrolysis of Nd (III) and Fe (III) cations in hot water with 5% NaOH as a precipitating agent. According to the results of the thermal behaviors of each hydroxide, either containing Fe (III) or Nd (III), the perovskite type of neodymium orthoferrite NdFeO3 was simply synthesized by annealing a mixture of Fe (III) and Nd (III) hydroxides at 750 °C. The nanostructured NdFeO3 was obtained in spherical granules with diameters of around 30 nm. The magnetic properties of the material were a coercive force (Hc) of 136.76 Oe, a remanent magnetization (Mr) of 0.68 emu·g–1, and a saturation magnetization (Ms) of 0.79 emu·g–1.


2019 ◽  
Vol 556 ◽  
pp. 6-11 ◽  
Author(s):  
Lingxiang Yang ◽  
Da-chuan Zhu ◽  
Shasha Liu ◽  
Jin-shan Wang ◽  
Cong Zhao ◽  
...  

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