Characterization of Algerian dune sand as a source to metallurgical-grade silicon production

Author(s):  
Nassima Meftah ◽  
Amina Hani
2020 ◽  
Vol 1 (1) ◽  
pp. 22-30
Author(s):  
Kifaet Kamal ◽  
◽  
Ashifa Akber ◽  
Md. Aminul Islam ◽  
Md. Abdus Satter ◽  
...  

The knowledge related to available high-quality sand deposits, Si manufacturing process and different challenging issues in manufacturing is essential for developing the silicon industry in Bangladesh, which is addressed in this article. For high-tech applications, the primary element silica needs to be 98% pure, at least. A case study in Bangladesh shows that Bipinganj sand, with the high quartz percentages, low moisture content, is suitable for the industrial-grade silicon production. No trace of Boron content has been found in the sand of Shameshwari river near Bipinganj locality. Some other potential sand deposits in Bangladesh which contain a high amount of silica are Balijuri of Sherpur district, Moulvibazar, Dakshin zangal of Hathhazari Upazila in Chittagong district, Chauddagram of Comilla district and Shajibazar of Habiganj district etc. Metallurgical grade silicon (MG-Si) is the precursor for the solar grade (SoG) and electronic-grade silicon. In photovoltaic and electronic applications, an electric arc furnace is used for the growth of MGS. Some parameters, such as furnace temperature and heat loss, need to be considered for good quality material production. MG-Si can be produced through both carbon reduction and magnesium reduction processes. Mg reduction is comparatively expensive. Silicon production from waste glasses can be a potential technology for MG-Si production in respective to Bangladesh.


1990 ◽  
Vol 5 (9) ◽  
pp. 1894-1899 ◽  
Author(s):  
J. C. Anglézio ◽  
C. Servant ◽  
F. Dubrous

Optical metallography, scanning electron microscopy, electron microprobe analysis, and transmission electron microscopy were used to characterize metallurgical grade silicon, produced in an electric are furnace. Coincidence fraction determinations were assumed to be Σ7 and Σ9 when grain boundaries are underlined by precipitated phases and Σ3 when they are not. The study of intergranular compounds was emphasized; ten compounds were found, the main ones being Si2Ca, Si8Al6Fe4Ca, Si2Al2Ca, Si2FeTi, and Si2.4Fe (α leboitc). The precipitation of these compounds was discussed according to the principal impurity concentrations in silicon. The crystalline structure of Si8Al6Fe4Ca was determined to be triclinic with a = 1.3923 nm, b = 1.3896 nm, c = 1.3900 nm and α = 92.4°, β = 110.3°, γ = 119.9°.


2021 ◽  
Vol 316 ◽  
pp. 649-654
Author(s):  
Andrey A. Tyutrin ◽  
Andrey S. Vologin

The paper is devoted to the urgent issue of processing the dust waste of metallurgical-grade silicon production, i.e. wet cleaning sludge, which contains a significant amount of valuable silica. The paper analyzes the formation of finely dispersed techno-genic materials that are generated in significant quantities (up to 120 t/d) at the Kremniy JSC. The composition and properties of the silicon production wet cleaning product have been studied. In analytical studies of the wet cleaning sludge samples, the modern certified analysis techniques have been used: laser diffraction, X-ray diffraction, and X-ray fluorescence. According to the analysis, the L:S ratio of liquid sludge is 2.1:1; after dehydration, the sludge cake has a grain size of 150 μm, with the prevailing (90 %) grain size of 59.65 μm in the test sample. The chemical composition of the sludge is 95.86 % SiO2; therefore, the wet cleaning sludge is a valuable raw material to produce metallurgical-grade silicon. Based on the analysis of the composition and properties of the silicon production wet cleaning sludge sample, we have developed a program for its processing. Sustainable sludge processing techniques are aimed at obtaining a briquetted charge, which can be used as an additive to the main raw material.


2015 ◽  
Vol 270 ◽  
pp. 98-103 ◽  
Author(s):  
Eloi Kewes ◽  
Franck Dahlem ◽  
Sandrine Bec ◽  
Nicolas Estime ◽  
Khalid Hoummada ◽  
...  

Silicon ◽  
2012 ◽  
Vol 4 (4) ◽  
pp. 289-295 ◽  
Author(s):  
Jijun Wu ◽  
Wenhui Ma ◽  
Bin Yang ◽  
Dachun Liu ◽  
Yongnian Dai

Author(s):  
Erlend L. Bjørnstad ◽  
Gabriella Tranell

AbstractOxidative ladle refining (OLR) is the most used refining method in industrial production of metallurgical grade silicon. OLR is performed by purging the liquid alloy with oxygen-enhanced air at 1823 K to 1873 K, reacting with silicon and the primary slag forming impurities to a SiO$$_{2}$$ 2 -CaO-Al$$_{2}$$ 2 O$$_{3}$$ 3 slag. To further increase our capability to control this process, it is paramount to understand how the slag nucleates and forms, and represent it such that it is useful for predicting and controlling the process behavior. This work aims to formulate a comprehensive theoretical description of slag nucleation and formation at nano/microscale using classical macroscale thermodynamics, bridging these spatial regimes. To achieve this, the work argues that silica’s liquid structure allows its nuclei to exhibit “well defined” surfaces. Furthermore, silica is predicted to be highly surface active, so if its concentration is high while the slag nucleus is small, the SiO$$_{2}$$ 2 -CaO-Al$$_{2}$$ 2 O$$_{3}$$ 3 slag should retain silica’s surface properties. An experiment confirmed the surface active nature of silica in the SiO$$_{2}$$ 2 -CaO-Al$$_{2}$$ 2 O$$_{3}$$ 3 system. It was also shown that increasing the slag’s calcia concentration has a greater effect on the interfacial tension between the molten slag and liquid alloy than alumina, confirming industrial observations of the coupling between refining rate and relative alloy/slag composition.


Vacuum ◽  
2011 ◽  
Vol 86 (4) ◽  
pp. 471-475 ◽  
Author(s):  
Xu Peng ◽  
Wei Dong ◽  
Yi Tan ◽  
Dachuan Jiang

2010 ◽  
Vol 156-157 ◽  
pp. 882-885 ◽  
Author(s):  
Yu Yan Hu ◽  
Dong Liang Lu ◽  
Tao Lin ◽  
Yu Liu ◽  
Bo Wang ◽  
...  

Refining of solar grade silicon by metallurgical method is the research hotspot of polycrystalline field. Slagging method is benefit to the removal of the impurities especially to boron exsisted in the raw silicon. In this study, the influence of the density, the viscosity and liquidus temperature of the slag components on the refining process were discussed, and then the slag system SiO2-Na2CO3 was choosed as the slagging agents. And then the impact factors on the removal efficiency of boron such as the composition of SiO2 and Na2CO3, the ratio of slag to silicon and the refining time were investigated by the orthogonal experiment. The results showed that the optimum parameters of the oxidation refining for removing boron were as follows: the main composition of the oxidant is “SiO2 : Na2CO3 = 60% : 40%”; the slag/silicon ratio is 0.5; time for refining is 60min at 1550 . The results indicated that the removal efficiency of boron was 88.28%, and the content of boron in MG-Si can be reduced to 7ppmw under the best refining process¬.


2004 ◽  
Vol 230-232 ◽  
pp. 1-16 ◽  
Author(s):  
William M. Vetter

Synchrotron white-beam x-ray topographs taken in the back-reflection mode have proved a powerful tool in the study of defects in semiconductor-grade silicon carbide crystals. Capable of mapping the distribution of axial dislocations across a wafer's area (notably the devastating micropipe defect), it can also provide information on their natures. Under favorable conditions, various other types of defect may be observed in back-reflection topographs of SiC, among which are subgrain boundaries, inclusions, and basal plane dislocations. Observed defect images in backreflection topographs may be simulated using relatively simple computer algorithms based on ray tracing. It has been possible to use back-reflection topographs of SiC substrates with device structures deposited upon them to relate the incidence of defects to device failure.


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