High surface N-/O-doped microporous carbons for stable supercapacitor and carbon dioxide sorption applications

2020 ◽  
Vol 308 ◽  
pp. 110526
Author(s):  
Hyun-Chul Kim ◽  
Minsun Park ◽  
Sukbin Yoon ◽  
Seong Huh
2021 ◽  
Vol 171 ◽  
pp. 105182
Author(s):  
S. López ◽  
M.J. Ramos ◽  
J.M. García-Vargas ◽  
M.T. García ◽  
J.F. Rodríguez ◽  
...  

Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 1962
Author(s):  
Mahboubeh Nabavinia ◽  
Baishali Kanjilal ◽  
Noahiro Fujinuma ◽  
Amos Mugweru ◽  
Iman Noshadi

To address the issue of global warming and climate change issues, recent research efforts have highlighted opportunities for capturing and electrochemically converting carbon dioxide (CO2). Despite metal doped polymers receiving widespread attention in this respect, the structures hitherto reported lack in ease of synthesis with scale up feasibility. In this study, a series of mesoporous metal-doped polymers (MRFs) with tunable metal functionality and hierarchical porosity were successfully synthesized using a one-step copolymerization of resorcinol and formaldehyde with Polyethyleneimine (PEI) under solvothermal conditions. The effect of PEI and metal doping concentrations were observed on physical properties and adsorption results. The results confirmed the role of PEI on the mesoporosity of the polymer networks and high surface area in addition to enhanced CO2 capture capacity. The resulting Cobalt doped material shows excellent thermal stability and promising CO2 capture performance, with equilibrium adsorption of 2.3 mmol CO2/g at 0 °C and 1 bar for at a surface area 675.62 m2/g. This mesoporous polymer, with its ease of synthesis is a promising candidate for promising for CO2 capture and possible subsequent electrochemical conversion.


2021 ◽  
Vol 2 (1) ◽  
Author(s):  
Philipp de Vrese ◽  
Tobias Stacke ◽  
Jeremy Caves Rugenstein ◽  
Jason Goodman ◽  
Victor Brovkin

AbstractSimple and complex climate models suggest a hard snowball – a completely ice-covered planet – is one of the steady-states of Earth’s climate. However, a seemingly insurmountable challenge to the hard-snowball hypothesis lies in the difficulty in explaining how the planet could have exited the glaciated state within a realistic range of atmospheric carbon dioxide concentrations. Here, we use simulations with the Earth system model MPI-ESM to demonstrate that terminal deglaciation could have been triggered by high dust deposition fluxes. In these simulations, deglaciation is not initiated in the tropics, where a strong hydrological cycle constantly regenerates fresh snow at the surface, which limits the dust accumulation and snow aging, resulting in a high surface albedo. Instead, comparatively low precipitation rates in the mid-latitudes in combination with high maximum temperatures facilitate lower albedos and snow dynamics that – for extreme dust fluxes – trigger deglaciation even at present-day carbon dioxide levels.


Polymer ◽  
1997 ◽  
Vol 38 (23) ◽  
pp. 5807-5813 ◽  
Author(s):  
Tapan Banerjee ◽  
G. Glenn Lipscomb

Sensors ◽  
2019 ◽  
Vol 19 (18) ◽  
pp. 3848 ◽  
Author(s):  
Ami Hannon ◽  
Jing Li

Detection of carbon dioxide (CO2) is very important for environmental, health, safety and space applications. We have studied novel multiwall carbon nanotubes (MWCNTs) and an iron oxide (Fe2O3) nanocomposite based chemiresistive sensor for detection of CO2 at room temperature. The sensor has been miniaturized to a chip size (1 cm × 2 cm). Good sensing performance was observed with a wide detection range of CO2 concentrations (100–6000 ppm). Structural properties of the sensing materials were characterized using Field-Emission Scanning Electron Microscopy, Fourier-Transform Infrared and Raman spectroscopies. The greatly improved sensitivity of the composite materials to CO2 can be attributed to the formation of a depletion layer at the p-n junction in an MWCNT/iron oxide heterostructure, and new CO2 gas molecules adhere to the high surface area of MWCNTs due to the concentration gradient. The test results showed that the CO2 sensor possesses fast response, compact size, ultra-low power consumption, high sensitivity and wide dynamic detection range.


2019 ◽  
Vol 10 (33) ◽  
pp. 4611-4620 ◽  
Author(s):  
Ningning Song ◽  
Tianjiao Wang ◽  
Hongyan Yao ◽  
Tengning Ma ◽  
Kaixiang Shi ◽  
...  

Microporous polyimide networks with high surface area and excellent CO2 adsorption performance have been constructed based on cross-linkable linear polyimides through crosslinking reaction.


1995 ◽  
Vol 33 (9) ◽  
pp. 1371-1384 ◽  
Author(s):  
M. Wessling ◽  
I. Huisman ◽  
Th. v. d. Boomgaard ◽  
C. A. Smolders

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