Efficient combination of Roll-to-Roll compatible techniques towards the large area deposition of a polymer dielectric film and the solution-processing of an organic semiconductor for the field-effect transistors fabrication on plastic substrate

Solvent treated and untreated polyimide dielectric films show the same smooth surface, and the electrical performances of organic field-effect transistors over a large area are identical.

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A Facile Method for the Growth of Organic Semiconductor Single Crystal Arrays on Polymer Dielectric toward Flexible Field‐Effect Transistors

Advanced Functional Materials ◽

10.1002/adfm.201902494 ◽

2019 ◽

Vol 29 (32) ◽

pp. 1902494 ◽

Cited By ~ 13

Author(s):

Wanqin Zhao ◽

Jiansheng Jie ◽

Qi Wei ◽

Zhengjun Lu ◽

Ruofei Jia ◽

...

Keyword(s):

Single Crystal ◽

Organic Semiconductor ◽

Field Effect ◽

Field Effect Transistors ◽

Polymer Dielectric ◽

Semiconductor Single Crystal

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Stable growth of large-area single crystalline thin films from an organic semiconductor/polymer blend solution for high-mobility organic field-effect transistors

Organic Electronics ◽

10.1016/j.orgel.2016.09.006 ◽

2016 ◽

Vol 39 ◽

pp. 127-132 ◽

Cited By ~ 18

Author(s):

Junshi Soeda ◽

Toshihiro Okamoto ◽

Chikahiko Mitsui ◽

Jun Takeya

Keyword(s):

Thin Films ◽

Polymer Blend ◽

Organic Semiconductor ◽

Field Effect ◽

Field Effect Transistors ◽

High Mobility ◽

Organic Field Effect Transistors ◽

Large Area ◽

Single Crystalline ◽

Stable Growth

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Experimental and molecular dynamics studies of an ultra-fast sequential hydrogen plasma process for fabricating phosphorene-based sensors

Scientific Reports ◽

10.1038/s41598-021-95463-z ◽

2021 ◽

Vol 11 (1) ◽

Author(s):

M. Rajabali ◽

H. Asgharyan ◽

V. Fadaei Naeini ◽

A. Boudaghi ◽

B. Zabihi ◽

...

Keyword(s):

Electron Microscopy ◽

Molecular Dynamics ◽

Field Effect ◽

Field Effect Transistors ◽

Hydrogen Plasma ◽

Device Fabrication ◽

Dynamics Simulation ◽

Red Phosphorus ◽

Large Area ◽

Low Concentration

AbstractLow concentration phosphorene-based sensors have been fabricated using a facile and ultra-fast process which is based on an exfoliation-free sequential hydrogen plasma treatment to convert the amorphous phosphorus thin film into mono- or few-layered phosphorene sheets. These sheets have been realized directly on silicon substrates followed by the fabrication of field-effect transistors showing the low leakage current and reasonable mobility for the nano-sensors. Being capable of covering the whole surface of the silicon substrate, red phosphorus (RP) coated substrate has been employed to achieve large area phosphorene sheets. Unlike the available techniques including mechanical exfoliation, there is no need for any exfoliation and/or transfer step which is significant progress in shortening the device fabrication procedure. These phosphorene sheets have been examined using transmission electron microscopy (TEM), Scanning electron microscopy (SEM), Raman spectroscopy and atomic-force microscopy (AFM). Electrical output in different states of the crystallization as well as its correlation with the test parameters have been also extensively used to examine the evolution of the phosphorene sheets. By utilizing the fabricated devices, the sensitivity of the phosphorene based-field effect transistors to the soluble L-Cysteine in low concentrations has been studied by measuring the FET response to the different concentrations. At a gate voltage of − 2.5 V, the range of 0.07 to 0.60 mg/ml of the L-Cysteine has been distinguishably detected presenting a gate-controlled sensor for a low-concentration solution. A reactive molecular dynamics simulation has been also performed to track the details of this plasma-based crystallization. The obtained results showed that the imparted energy from hydrogen plasma resulted in a phase transition from a system containing red phosphorus atoms to the crystal one. Interestingly and according to the simulation results, there is a directional preference of crystal growth as the crystalline domains are being formed and RP atoms are more likely to re-locate in armchair than in zigzag direction.

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Nanonet: Low-temperature-processed tellurium nanowire network for scalable p-type field-effect transistors and a highly sensitive phototransistor array

NPG Asia Materials ◽

10.1038/s41427-021-00314-y ◽

2021 ◽

Vol 13 (1) ◽

Author(s):

Muhammad Naqi ◽

Kyung Hwan Choi ◽

Hocheon Yoo ◽

Sudong Chae ◽

Bum Jun Kim ◽

...

Keyword(s):

Low Temperature ◽

Field Effect ◽

High Performance ◽

Field Effect Transistors ◽

Optical Measurements ◽

Electrical Performance ◽

Large Area ◽

Nanowire Network ◽

P Type ◽

Nanowire Networks

AbstractLow-temperature-processed semiconductors are an emerging need for next-generation scalable electronics, and these semiconductors need to feature large-area fabrication, solution processability, high electrical performance, and wide spectral optical absorption properties. Although various strategies of low-temperature-processed n-type semiconductors have been achieved, the development of high-performance p-type semiconductors at low temperature is still limited. Here, we report a unique low-temperature-processed method to synthesize tellurium nanowire networks (Te-nanonets) over a scalable area for the fabrication of high-performance large-area p-type field-effect transistors (FETs) with uniform and stable electrical and optical properties. Maximum mobility of 4.7 cm2/Vs, an on/off current ratio of 1 × 104, and a maximum transconductance of 2.18 µS are achieved. To further demonstrate the applicability of the proposed semiconductor, the electrical performance of a Te-nanonet-based transistor array of 42 devices is also measured, revealing stable and uniform results. Finally, to broaden the applicability of p-type Te-nanonet-based FETs, optical measurements are demonstrated over a wide spectral range, revealing an exceptionally uniform optical performance.

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Mercury-Mediated Organic Semiconductor Surface Doping Monitored by Electrolyte-Gated Field-Effect Transistors

Advanced Functional Materials ◽

10.1002/adfm.201703899 ◽

2017 ◽

Vol 27 (46) ◽

pp. 1703899 ◽

Cited By ~ 7

Author(s):

Qiaoming Zhang ◽

Francesca Leonardi ◽

Stefano Casalini ◽

Marta Mas-Torrent

Keyword(s):

Organic Semiconductor ◽

Field Effect ◽

Field Effect Transistors ◽

Semiconductor Surface ◽

Surface Doping

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Large Area Emission in p-Type Polymer-Based Light-Emitting Field-Effect Transistors by Incorporating Charge Injection Interlayers

Materials ◽

10.3390/ma14040901 ◽

2021 ◽

Vol 14 (4) ◽

pp. 901

Author(s):

Gizem Acar ◽

Muhammad Javaid Iqbal ◽

Mujeeb Ullah Chaudhry

Keyword(s):

Field Effect ◽

Field Effect Transistors ◽

Charge Injection ◽

Limiting Factors ◽

Hole Injection ◽

Large Area ◽

Device Structure ◽

Light Emitting ◽

Emission Area ◽

P Type

Organic light-emitting field-effect transistors (LEFETs) provide the possibility of simplifying the display pixilation design as they integrate the drive-transistor and the light emission in a single architecture. However, in p-type LEFETs, simultaneously achieving higher external quantum efficiency (EQE) at higher brightness, larger and stable emission area, and high switching speed are the limiting factors for to realise their applications. Herein, we present a p-type polymer heterostructure-based LEFET architecture with electron and hole injection interlayers to improve the charge injection into the light-emitting layer, which leads to better recombination. This device structure provides access to hole mobility of ~2.1 cm2 V−1 s−1 and EQE of 1.6% at a luminance of 2600 cd m−2. Most importantly, we observed a large area emission under the entire drain electrode, which was spatially stable (emission area is not dependent on the gate voltage and current density). These results show an important advancement in polymer-based LEFET technology toward realizing new digital display applications.

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All-Organic, Low Voltage, Transparent and Compliant Organic Field-Effect Transistor Fabricated by Means of Large-Area, Cost-Effective Techniques

Applied Sciences ◽

10.3390/app10196656 ◽

2020 ◽

Vol 10 (19) ◽

pp. 6656

Author(s):

Stefano Lai ◽

Giulia Casula ◽

Pier Carlo Ricci ◽

Piero Cosseddu ◽

Annalisa Bonfiglio

Keyword(s):

Field Effect ◽

Low Voltage ◽

Field Effect Transistors ◽

High Mobility ◽

Chemical Vapor ◽

Cost Effective ◽

Large Area ◽

Parylene C ◽

Biomedical Sensing ◽

Novel Applications

The development of electronic devices with enhanced properties of transparency and conformability is of high interest for the development of novel applications in the field of bioelectronics and biomedical sensing. Here, a fabrication process for all organic Organic Field-Effect Transistors (OFETs) by means of large-area, cost-effective techniques such as inkjet printing and chemical vapor deposition is reported. The fabricated device can operate at low voltages (as high as 4 V) with ideal electronic characteristics, including low threshold voltage, relatively high mobility and low subthreshold voltages. The employment of organic materials such as Parylene C, PEDOT:PSS and 6,13-Bis(triisopropylsilylethynyl)pentacene (TIPS pentacene) helps to obtain highly transparent transistors, with a relative transmittance exceeding 80%. Interestingly enough, the proposed process can be reliably employed for OFET fabrication over different kind of substrates, ranging from transparent, flexible but relatively thick polyethylene terephthalate (PET) substrates to transparent, 700-nm-thick, compliant Parylene C films. OFETs fabricated on such sub-micrometrical substrates maintain their functionality after being transferred onto complex surfaces, such as human skin and wearable items. To this aim, the electrical and electromechanical stability of proposed devices will be discussed.

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