scholarly journals REEVALUATING THE EVIDENCE FOR MIDDLE WOODLAND MAIZE FROM THE HOLDING SITE

2017 ◽  
Vol 82 (1) ◽  
pp. 140-150 ◽  
Author(s):  
Mary L. Simon

Maize fragments recovered from the Middle Woodland Holding site (11MS118) in the American Bottom have for several decades been recognized as the oldest directly dated maize east of the Mississippi River. A reevaluation of maize samples from this site indicates that finding was in error. Carbon isotope assessment (δ13C ratios) run on the original samples dated in 1994 indicated that they were not maize. Six additional samples originally identified as maize were submitted to the Illinois State Geological Survey for carbon ratio assessment and direct accelerated mass spectrometry dating. Three of the fragments, including one from the same feature dated previously, returned non-maize δ13C ratios. The other three samples were correctly identified as maize, but all returned post–A.D. 900 dates. These results invalidate the original report of Middle Woodland maize at Holding and support our ongoing reevaluations of maize histories in the American Bottom and western Illinois, which show that it was not an important cultivated crop plant in this part of the Midwest until about A.D. 900.


1994 ◽  
Vol 59 (3) ◽  
pp. 490-498 ◽  
Author(s):  
Thomas J. Riley ◽  
Gregory R. Walz ◽  
Charles J. Bareis ◽  
Andrew C. Fortier ◽  
Kathryn E. Parker

Two accelerator mass spectrometry (AMS) dates obtained from samples of Zea mays from the Holding site, 11MS118, in the American Bottom near East St. Louis, Illinois, establish the presence of maize in the Mississippi Valley between 170 B.C. and A.D. 60. The dates finally establish the occurrence of Middle Woodland maize in Illinois and are the earliest dates thus far for maize east of the Mississippi River. Other reports of early Middle Woodland maize in the Midcontinent region should not be discounted unless AMS dating and other supporting information show the maize to be a contaminant at the site at which it occurs. Recent stable carbon-isotope experiments suggest that the relative contribution of maize to Middle Woodland diets is still an open question.



2021 ◽  
pp. 1-12
Author(s):  
Mary L. Simon ◽  
Kandace D. Hollenbach ◽  
Brian G. Redmond

Accelerated mass spectrometry (AMS) and carbon isotope analyses provide strong tandem methodologies used by archaeologists to evaluate and reevaluate the histories of maize use in the Midwest. In this article, we present newly obtained AMS dates and carbon isotope assays of alleged maize samples from the Icehouse Bottom (40MR23) and Edwin Harness sites (22RO33). Based on original studies, samples were thought to date to the Middle Woodland period (ca. 300 BC–AD 400). The results show that samples either were not maize or date to post-AD 900. As of this finding, there are no longer any securely dated Middle Woodland macrobotanical remains of maize from the Eastern Woodlands of North America.



Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2335
Author(s):  
Gabriella Pinto ◽  
Sabrina De Pascale ◽  
Maria Aponte ◽  
Andrea Scaloni ◽  
Francesco Addeo ◽  
...  

Plant polyphenols have beneficial antioxidant effects on human health; practices aimed at preserving their content in foods and/or reusing food by-products are encouraged. The impact of the traditional practice of the water curing procedure of chestnuts, which prevents insect/mould damage during storage, was studied to assess the release of polyphenols from the fruit. Metabolites extracted from pericarp and integument tissues or released in the medium from the water curing process were analyzed by matrix-assisted laser desorption ionization-time of flight-mass spectrometry (MALDI-TOF-MS) and electrospray-quadrupole-time of flight-mass spectrometry (ESI-qTOF-MS). This identified: (i) condensed and hydrolyzable tannins made of (epi)catechin (procyanidins) and acid ellagic units in pericarp tissues; (ii) polyphenols made of gallocatechin and catechin units condensed with gallate (prodelphinidins) in integument counterparts; (iii) metabolites resembling those reported above in the wastewater from the chestnut curing process. Comparative experiments were also performed on aqueous media recovered from fruits treated with processes involving: (i) tap water; (ii) tap water containing an antifungal Lb. pentosus strain; (iii) wastewater from a previous curing treatment. These analyses indicated that the former treatment determines a 6–7-fold higher release of polyphenols in the curing water with respect to the other ones. This event has a negative impact on the luster of treated fruits but qualifies the corresponding wastes as a source of antioxidants. Such a phenomenon does not occur in wastewater from the other curing processes, where the release of polyphenols was reduced, thus preserving the chestnut’s appearance. Polyphenol profiling measurements demonstrated that bacterial presence in water hampered the release of pericarp metabolites. This study provides a rationale to traditional processing practices on fruit appearance and qualifies the corresponding wastes as a source of bioactive compounds for other nutraceutical applications.



Nanomaterials ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 1301
Author(s):  
Oscar E. Medina ◽  
Jaime Gallego ◽  
Sócrates Acevedo ◽  
Masoud Riazi ◽  
Raúl Ocampo-Pérez ◽  
...  

This study focuses on evaluating the volumetric hydrogen content in the gaseous mixture released from the steam catalytic gasification of n-C7 asphaltenes and resins II at low temperatures (<230 °C). For this purpose, four nanocatalysts were selected: CeO2, CeO2 functionalized with Ni-Pd, Fe-Pd, and Co-Pd. The catalytic capacity was measured by non-isothermal (from 100 to 600 °C) and isothermal (220 °C) thermogravimetric analyses. The samples show the main decomposition peak between 200 and 230 °C for bi-elemental nanocatalysts and 300 °C for the CeO2 support, leading to reductions up to 50% in comparison with the samples in the absence of nanoparticles. At 220 °C, the conversion of both fractions increases in the order CeO2 < Fe-Pd < Co-Pd < Ni-Pd. Hydrogen release was quantified for the isothermal tests. The hydrogen production agrees with each material’s catalytic activity for decomposing both fractions at the evaluated conditions. CeNi1Pd1 showed the highest performance among the other three samples and led to the highest hydrogen production in the effluent gas with values of ~44 vol%. When the samples were heated at higher temperatures (i.e., 230 °C), H2 production increased up to 55 vol% during catalyzed n-C7 asphaltene and resin conversion, indicating an increase of up to 70% in comparison with the non-catalyzed systems at the same temperature conditions.



Author(s):  
Xing Wang ◽  
Henk G. Jansen ◽  
Haico Duin ◽  
Harro A. J. Meijer

AbstractThere are two officially approved methods for stable isotope analysis for wine authentication. One describes δ18O measurements of the wine water using Isotope Ratio Mass Spectrometry (IRMS), and the other one uses Deuterium-Nuclear Magnetic Resonance (2H-NMR) to measure the deuterium of the wine ethanol. Recently, off-axis integrated cavity output (laser) spectroscopy (OA-ICOS) has become an easier alternative to quantify wine water isotopes, thanks to the spectral contaminant identifier (SCI). We utilized an OA-ICOS analyser with SCI to measure the δ18O and δ2H of water in 27 wine samples without any pre-treatment. The OA-ICOS results reveal a wealth of information about the growth conditions of the wines, which shows the advantages to extend the official δ18O wine water method by δ2H that is obtained easily from OA-ICOS. We also performed high-temperature pyrolysis and chromium reduction combined with IRMS measurements to illustrate the “whole wine” isotope ratios. The δ18O results of OA-ICOS and IRMS show non-significant differences, but the δ2H results of both methods differ much more. As the δ2H difference between these two methods is mainly caused by ethanol, we investigated the possibility to deduce deuterium of wine ethanol from this difference. The results present large uncertainties and deviate from the obtained 2H-NMR results. The deviation is caused by the other constituents in the wine, and the uncertainty is due to the limited precision of the SCI-based correction, which need to improve to obtain the 2H values of ethanol as alternative for the 2H-NMR method.



2021 ◽  
Vol 21 (7) ◽  
pp. 4081-4084
Author(s):  
Seul-Bee Lee ◽  
Young-Min Kim ◽  
Ji-Hui Park ◽  
Young-Kwon Park

This study examined the thermal and catalytic pyrolysis of waste Achyranthes Root (AR) using pyrolyzer-gas chromatography/mass spectrometry (Py-GC/MS). The non-catalytic pyrolysis of waste AR produced various kinds of oxygenates, such as acetic acid, hydroxy propanone, furfural, phenol, cresol, guaiacols, syringols, and so on. By applying nanoporous Al-MCM-41 with acidic properties and mesopores to the pyrolysis of waste AR, the levels of furan and aromatic hydrocarbons production increased with a concomitant decrease in the other oxygenates. The formation efficiency of furans was improved further by increasing the amount of Al-MCM-41 applied to the catalytic pyrolysis of waste AR.



2018 ◽  
Vol 11 (9) ◽  
pp. 770-780 ◽  
Author(s):  
Guang Liu ◽  
Limei Wang ◽  
Junmin Pan

Abstract The motility of cilia or eukaryotic flagella is powered by the axonemal dyneins, which are preassembled in the cytoplasm by proteins termed dynein arm assembly factors (DNAAFs) before being transported to and assembled on the ciliary axoneme. Here, we characterize the function of WDR92 in Chlamydomonas. Loss of WDR92, a cytoplasmic protein, in a mutant wdr92 generated by DNA insertional mutagenesis resulted in aflagellate cells or cells with stumpy or short flagella, disappearance of axonemal dynein arms, and diminishment of dynein arm heavy chains in the cytoplasm, suggesting that WDR92 is a DNAAF. Immunoprecipitation of WDR92 followed by mass spectrometry identified inner dynein arm heavy chains and multiple DNAAFs including RuvBL1, RPAP3, MOT48, ODA7, and DYX1C. The PIH1 domain-containing protein MOT48 formed a R2TP-like complex with RuvBL1/2 and RPAP3, while PF13, another PIH1 domain-containing protein with function in dynein preassembly, did not. Interestingly, the third PIH1 domain-containing protein TWI1 was not related to flagellar motility. WDR92 physically interacted with the R2TP-like complex and the other identified DNNAFs. Our data suggest that WDR92 functions in association with the HSP90 co-chaperone R2TP-like complex as well as linking other DNAAFs in dynein preassembly.



1906 ◽  
Vol 3 (5) ◽  
pp. 206-216 ◽  
Author(s):  
J. B. Hill

The author, who has long been engaged on the Palæozoics of West Cornwall, divided the killas extending westward from Gerrans Bay into four groups that formed a natural sequence. Moreover, as they included definite Lower Silurian horizons, as characterized by the fossiliferous quartzite of Carne, these divisions were linked with the Lower Palæozoics. They consist of the Veryan, Portscatho, Falmouth, and Mylor groups. On the latest issues of the old Survey maps the area occupied by the first of these divisions is coloured as Silurian, and the region occupied by the remainder as Devonian. That colouring, however, was not adopted by De la Beche, who surveyed the region, nor was it the result of any subsequent survey of the area. In the original Geological Survey map of Cornwall the killas was separated by De la Beche into two divisions, viz., a grauwacke group and a carbonaceous series. Thus, the former lying below the Culm-measures was undifferentiated for the reason, as explained in his Report, that the progress of geology at that time only warranted the broadest generalizations. He moreover expressed the opinion that the terms Cambrian and Silurian should be restricted to the areas that gave rise to the prolonged researches of Murchison and Sedgwick, and deprecated the extension of that nomenclature to districts that had not received the same detailed investigations. In a later and undated issue of the map the grauwacke group is divided into Devonian and Silurian, presumably by the authority Sir Roderick Murchison. The Devonian colour was not only applied to fossiliferous strata in East and Mid Cornwall, but was extended over the unfossiliferous strata in the west. The Silurian tint, on the other hand, was restricted to a zone that had yielded organic remains. Murchison, however, was of opinion that the older zone extended far beyond those limits into the barren strata coloured as Devonian, and it is evident that the latter tint was adopted as a matter of convenience, as no re-examination of the area seems to have been undertaken. The known Silurian region was confined to the coastal belt between Chapel Point and Gerrans Bay, a boundary connecting those localities admitting of the ready isolation of that zone from the rest of the country. That such a broad generalization, however, was only regarded as provisional may be inferred from the absence of a line on the map between the two divisions. It will be seen, therefore, that the subdivision of the killas, as the result of the recent survey, neither invalidates the map published by De la Beche nor the subsequent conclusions of Murcliison. It has, on the other hand, not only brought their generalizations within more definite limits, but has carried the investigation a step farther by demonstrating the relations between the older and newer Palæozoics of Cornwall.



1986 ◽  
Vol 250 (1) ◽  
pp. F86-F91
Author(s):  
R. V. Pinnick ◽  
V. J. Savin

We measured glomerular ultrafiltration coefficient (Kf) of isolated superficial (S) and deep (D) glomeruli of normovolemic and volume-depleted rats. Filtration was induced in vitro, and Kf was calculated from the maximum rate of change in glomerular size. Basement membrane area (A) for each glomerulus was estimated from morphometric analyses, and glomerular capillary hydraulic conductivity (Lp) was calculated by the formula Lp = Kf/A. Kf of S and D glomeruli of normovolemic rats were 2.98 +/- 0.98 and 4.25 +/- 0.07 nl . min-1 . mmHg-1, respectively. In hypovolemic rats, Kf of S glomeruli fell by approximately 50% to 1.52 +/- 0.14 nl . min-1 . mmHg-1 (P less than 0.001), whereas Kf of D glomeruli remained unchanged at 4.28 +/- 0.10 nl . min-1 . mmHg-1. Lp, calculated using the peripheral capillary area, averaged 1.98 +/- 0.09 and 1.98 +/- 0.06 microliter . min-1 . mmHg-1 . cm-2 in S and D glomeruli of normovolemic rats and 1.89 +/- 0.11 microliter . min-1 . mmHg-1 . cm-2 in D glomeruli of hypovolemic rats. Lp of S glomeruli of volume-depleted rats (0.90 +/- 0.03 microliter . min-1 . mmHg-1 . cm-2) was lower than in any of the other three samples. Mild hypovolemia causes the Kf of S glomeruli to decline, whereas Kf of D glomeruli remains constant. The decrease in Kf occurs without an alteration in capillary area and is most likely due to a decrease in Lp.



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