TEM observation of cylindrite
Cylindrite, approximately FePb3Sn4Sb2S14, contains two different types of layers, pseudo-tetragonal(t-lattice) with PbS structure and pseudo-hexagonal (h-lattice) with SnS2 structure. The two kinds of layers are superimposed in the order of htht.., and the repeat periodicity is a. In the past only the composite SAED pattern corresponding to the b*c* plane of the two lattices was obtained as shown in Fig. 1a. Now we have succeeded, by careful tilting, in taking separate SAED patterns and HREM images of these two lattices(Figs. 2 and 3). The CBED pattern containing two [100] zone axes indicates: , as shown in Fig. lb.In the SAED patterns shown in Figs. 2, 3 and 4, each main reflection is accompanied by a row of satellite spots caused by the common structural modulation of the two lattices shown by the dark bands inthe HREM images. The rows of satellites, defined by q, in general donot parallel to any axes defined by the main reflections. In the q direction, the additional long-range periodicity corresponding to the satellites and the basic periodicity of both lattices are incommensurate.