Microstructural Instability in Mosi2/Sic Nanolayers

Thin film multilayers have been the focus of extensive studies recently due to the interesting properties they exhibit. Since the improvement in properties can be attributed directly to the unique nanoscale microstructures, it is essential to understand the factors affecting the microstructural stability in these nanolayer structures. The intermetallic compound, MoSi2, despite its superior oxidation resistance and high melting point, suffers from inadequate high temperature strength and low temperature ductility, properties which hinder its high temperature structural applications [1]. SiC is a potential second phase reinforcement due to its high temperature strength and thermal compatibility with MoSi2. The addition of SiC in a nanolayered configuration has been shown to exhibit significant increase in hardness after annealing [2]. It has also been shown that when annealed above 900°C, the layers break down and grain growth sets in, with a significant decrease in hardness and. Due to the lack of a thermochemical driving force, the two phases remain separate at all temperatures investigated. In this study, the stability of the MoSi2/SiC nanolayers structure under ion irradiation has been investigated.

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Lattice Imaging of Grain Boundaries in Ceramics

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100078171 ◽

1977 ◽

Vol 35 ◽

pp. 114-115

Author(s):

D. R. Clarke ◽

G. Thomas

Keyword(s):

Mechanical Properties ◽

High Temperature ◽

Silicon Nitride ◽

Grain Boundaries ◽

High Temperature Strength ◽

Current Interest ◽

Lattice Imaging ◽

Special Significance ◽

Structural Applications ◽

Refractory Ceramics

Grain boundaries have long held a special significance to ceramicists. In part, this has been because it has been impossible until now to actually observe the boundaries themselves. Just as important, however, is the fact that the grain boundaries and their environs have a determing influence on both the mechanisms by which powder compaction occurs during fabrication, and on the overall mechanical properties of the material. One area where the grain boundary plays a particularly important role is in the high temperature strength of hot-pressed ceramics. This is a subject of current interest as extensive efforts are being made to develop ceramics, such as silicon nitride alloys, for high temperature structural applications. In this presentation we describe how the techniques of lattice fringe imaging have made it possible to study the grain boundaries in a number of refractory ceramics, and illustrate some of the findings.

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Effect of Improved ThO2 Particle Dispersion in Nickel on High-Temperature Strength

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100069211 ◽

1970 ◽

Vol 28 ◽

pp. 444-445

Author(s):

E. R. Kimmel ◽

H. L. Anthony ◽

W. Scheithauer

Keyword(s):

High Temperature ◽

Metal Matrix ◽

Oxide Particle ◽

Oxide Phase ◽

Dislocation Motion ◽

Particle Dispersion ◽

High Temperature Strength ◽

Strengthening Effect ◽

Oxide Particles ◽

The Stability

The strengthening effect at high temperature produced by a dispersed oxide phase in a metal matrix is seemingly dependent on at least two major contributors: oxide particle size and spatial distribution, and stability of the worked microstructure. These two are strongly interrelated. The stability of the microstructure is produced by polygonization of the worked structure forming low angle cell boundaries which become anchored by the dispersed oxide particles. The effect of the particles on strength is therefore twofold, in that they stabilize the worked microstructure and also hinder dislocation motion during loading.

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Microstructural characterization of a rapidly solidified Al-Fe-V-Si alloy for elevated temperature applications

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100104819 ◽

1988 ◽

Vol 46 ◽

pp. 550-551

Author(s):

R. E. Franck ◽

J. A. Hawk ◽

G. J. Shiflet

Keyword(s):

High Temperature ◽

Elevated Temperature ◽

Grain Growth ◽

Volume Fraction ◽

Microstructural Characterization ◽

Second Phase ◽

Microstructural Stability ◽

Elevated Temperature Strength ◽

Temperature Applications

Rapid solidification processing (RSP) is one method of producing high strength aluminum alloys for elevated temperature applications. Allied-Signal, Inc. has produced an Al-12.4 Fe-1.2 V-2.3 Si (composition in wt pct) alloy which possesses good microstructural stability up to 425°C. This alloy contains a high volume fraction (37 v/o) of fine nearly spherical, α-Al12(Fe, V)3Si dispersoids. The improved elevated temperature strength and stability of this alloy is due to the slower dispersoid coarsening rate of the silicide particles. Additionally, the high v/o of second phase particles should inhibit recrystallization and grain growth, and thus reduce any loss in strength due to long term, high temperature annealing.The focus of this research is to investigate microstructural changes induced by long term, high temperature static annealing heat-treatments. Annealing treatments for up to 1000 hours were carried out on this alloy at 500°C, 550°C and 600°C. Particle coarsening and/or recrystallization and grain growth would be accelerated in these temperature regimes.

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Precipitation of NiHfsi phase in NiAl single crystals containing Hf

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100139032 ◽

1995 ◽

Vol 53 ◽

pp. 532-533

Author(s):

A. Garg ◽

R. D. Noebe ◽

R. Darolia

Keyword(s):

High Temperature ◽

Single Crystals ◽

High Temperature Strength ◽

Bridgman Technique ◽

Shell Mold ◽

Third Phase ◽

Unknown Phase ◽

Transmission Electron ◽

Two Phases ◽

Nial Matrix

Small additions of Hf to NiAl produce a significant increase in the high-temperature strength of single crystals. Hf has a very limited solubility in NiAl and in the presence of Si, results in a high density of G-phase (Ni16Hf6Si7) cuboidal precipitates and some G-platelets in a NiAl matrix. These precipitates have a F.C.C structure and nucleate on {100}NiAl planes with almost perfect coherency and a cube-on-cube orientation-relationship (O.R.). However, G-phase is metastable and after prolonged aging at high temperature dissolves at the expense of a more stable Heusler (β'-Ni2AlHf) phase. In addition to these two phases, a third phase was shown to be present in a NiAl-0.3at. % Hf alloy, but was not previously identified (Fig. 4 of ref. 2 ). In this work, we report the morphology, crystal-structure, O.R., and stability of this unknown phase, which were determined using conventional and analytical transmission electron microscopy (TEM).Single crystals of NiAl containing 0.5at. % Hf were grown by a Bridgman technique. Chemical analysis indicated that these crystals also contained Si, which was not an intentional alloying addition but was picked up from the shell mold during directional solidification.

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Phase transformation and layer evolution in molybdenum disilicide-silicon carbide nanolayered coatings

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100170426 ◽

1994 ◽

Vol 52 ◽

pp. 538-539

Author(s):

H. Kung ◽

T. R. Jervis ◽

J.-P. Hirvonen ◽

M. Nastasi ◽

T. E. Mitchell ◽

...

Keyword(s):

Phase Transformation ◽

High Temperature ◽

Oxidation Resistance ◽

Elevated Temperatures ◽

Matrix Material ◽

Molybdenum Disilicide ◽

High Temperature Strength ◽

Cross Sectional ◽

Good Oxidation Resistance ◽

Structural Applications

MoSi2 is a potential matrix material for high temperature structural composites due to its high melting temperature and good oxidation resistance at elevated temperatures. The two major drawbacksfor structural applications are inadequate high temperature strength and poor low temperature ductility. The search for appropriate composite additions has been the focus of extensive investigations in recent years. The addition of SiC in a nanolayered configuration was shown to exhibit superior oxidation resistance and significant hardness increase through annealing at 500°C. One potential application of MoSi2- SiC multilayers is for high temperature coatings, where structural stability ofthe layering is of major concern. In this study, we have systematically investigated both the evolution of phases and the stability of layers by varying the heat treating conditions.Alternating layers of MoSi2 and SiC were synthesized by DC-magnetron and rf-diode sputtering respectively. Cross-sectional transmission electron microscopy (XTEM) was used to examine three distinct reactions in the specimens when exposed to different annealing conditions: crystallization and phase transformation of MoSi2, crystallization of SiC, and spheroidization of the layer structures.

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Factors Affecting the Stability of Scale Inhibitors Used for Capillary Injection in High Temperature Wells

10.2118/164128-ms ◽

2013 ◽

Cited By ~ 2

Author(s):

J. Rick Griffin ◽

James R Johnstone ◽

Terry E Cotter ◽

Ashleigh E O'Brien

Keyword(s):

High Temperature ◽

Factors Affecting ◽

The Stability

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Development of Creep-Resistant, Alumina-Forming Ferrous Alloys for High-Temperature Structural Use

ASME 2018 Symposium on Elevated Temperature Application of Materials for Fossil, Nuclear, and Petrochemical Industries ◽

10.1115/etam2018-6727 ◽

2018 ◽

Cited By ~ 3

Author(s):

Y. Yamamoto ◽

M. P. Brady ◽

G. Muralidharan ◽

B. A. Pint ◽

P. J. Maziasz ◽

...

Keyword(s):

High Temperature ◽

Elevated Temperatures ◽

Extreme Environments ◽

Alloy Design ◽

Austenitic Steels ◽

Strength Development ◽

Second Phase ◽

Ferrous Alloys ◽

Steel Alloys ◽

Structural Applications

This paper overviews recent advances in developing novel alloy design concepts of creep-resistant, alumina-forming Fe-base alloys, including both ferritic and austenitic steels, for high-temperature structural applications in fossil-fired power generation systems. Protective, external alumina-scales offer improved oxidation resistance compared to chromia-scales in steam-containing environments at elevated temperatures. Alloy design utilizes computational thermodynamic tools with compositional guidelines based on experimental results accumulated in the last decade, along with design and control of the second-phase precipitates to maximize high-temperature strengths. The alloys developed to date, including ferritic (Fe-Cr-Al-Nb-W base) and austenitic (Fe-Cr-Ni-Al-Nb base) alloys, successfully incorporated the balanced properties of steam/water vapor-oxidation and/or ash-corrosion resistance and improved creep strength. Development of cast alumina-forming austenitic (AFA) stainless steel alloys is also in progress with successful improvement of higher temperature capability targeting up to ∼1100°C. Current alloy design approach and developmental efforts with guidance of computational tools were found to be beneficial for further development of the new heat resistant steel alloys for various extreme environments.

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Factors Affecting Choice of Working Stresses for High-Temperature Service

Journal of Applied Mechanics ◽

10.1115/1.4012192 ◽

1933 ◽

Vol 1 (3) ◽

pp. 99-102

Author(s):

P. G. McVetty

Keyword(s):

High Temperature ◽

Published Data ◽

Creep Tests ◽

Fundamental Study ◽

Factors Affecting ◽

Creep Characteristics ◽

The Stability ◽

Safe Working

Abstract This paper discusses the various methods which have been proposed to determine safe working stresses for high-temperature service. The question of the stability of alloys during the test and in subsequent service is considered, with particular emphasis upon probable changes in creep characteristics during long exposure to stress and temperature. It is shown that published data in general do not admit of extrapolation, and that attempts to estimate total creep in service from such data are not usually satisfactory. The author stresses the need for more fundamental study of the laws governing creep rather than creep tests of many different materials.

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Effect of Helium on Dispersoid Evolution under Self-Ion Irradiation in A Dual-Phase 12Cr Oxide-Dispersion-Strengthened Alloy

Materials ◽

10.3390/ma12203343 ◽

2019 ◽

Vol 12 (20) ◽

pp. 3343 ◽

Cited By ~ 2

Author(s):

Hyosim Kim ◽

Tianyao Wang ◽

Jonathan G. Gigax ◽

Shigeharu Ukai ◽

Frank A. Garner ◽

...

Keyword(s):

High Temperature ◽

Ion Irradiation ◽

Critical Mass ◽

Control Sample ◽

Oxide Dispersion Strengthened ◽

Future Generation ◽

High Temperature Strength ◽

Oxide Dispersion ◽

Dual Phase ◽

Peak Displacement

As one candidate alloy for future Generation IV and fusion reactors, a dual-phase 12Cr oxide-dispersion-strengthened (ODS) alloy was developed for high temperature strength and creep resistance and has shown good void swelling resistance under high damage self-ion irradiation at high temperature. However, the effect of helium and its combination with radiation damage on oxide dispersoid stability needs to be investigated. In this study, 120 keV energy helium was preloaded into specimens at doses of 1 × 1015 and 1 × 1016 ions/cm2 at room temperature, and 3.5 MeV Fe self-ions were sequentially implanted to reach 100 peak displacement-per-atom at 475 °C. He implantation alone in the control sample did not affect the dispersoid morphology. After Fe ion irradiation, a dramatic increase in density of coherent oxide dispersoids was observed at low He dose, but no such increase was observed at high He dose. The study suggests that helium bubbles act as sinks for nucleation of coherent oxide dispersoids, but dispersoid growth may become difficult if too many sinks are introduced, suggesting that a critical mass of trapping is required for stable dispersoid growth.

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