scholarly journals Solvent engineered synthesis of layered SnO for high-performance anodes

2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Sonia Jaśkaniec ◽  
Seán R. Kavanagh ◽  
João Coelho ◽  
Seán Ryan ◽  
Christopher Hobbs ◽  
...  
Keyword(s):  
High Performance ◽  
Synthesis Method ◽  
Structure Theory ◽  
Wulff Construction ◽  
Synthesis Conditions ◽  
Chemical Mechanisms ◽  
Electrochemically Active ◽  
Battery Electrode ◽  
Nanoparticle Morphology ◽  
High Level

AbstractBatteries are the most abundant form of electrochemical energy storage. Lithium and sodium ion batteries account for a significant portion of the battery market, but high-performance electrochemically active materials still need to be discovered and optimized for these technologies. Recently, tin(II) oxide (SnO) has emerged as a highly promising battery electrode. In this work, we present a facile synthesis method to produce SnO microparticles whose size and shape can be tailored by changing the solvent nature. We study the complex relationship between wet-chemistry synthesis conditions and resulting layered nanoparticle morphology. Furthermore, high-level electronic structure theory, including dispersion corrections to account for van der Waals forces, is employed to enhance our understanding of the underlying chemical mechanisms. The electronic vacuum alignment and surface energies are determined, allowing the prediction of the thermodynamically favoured crystal shape (Wulff construction) and surface-weighted work function. Finally, the synthesized nanomaterials were tested as Li-ion battery anodes, demonstrating significantly enhanced electrochemical performance for morphologies obtained from specific synthesis conditions.

What Can Digitization Do For Formulated Product Innovation and Development

2020 ◽  
Author(s):  
James McDonagh ◽  
William Swope ◽  
Richard L. Anderson ◽  
Michael Johnston ◽  
David J. Bray
Keyword(s):  
High Performance ◽  
Quality Data ◽  
High Quality Data ◽  
Base Level ◽  
Hybrid Approaches ◽  
Digital Ecosystem ◽  
Recent Developments ◽  
Chemical Simulation ◽  
High Level ◽  
Physical And Chemical

Digitization offers significant opportunities for the formulated product industry to transform the way it works and develop new methods of business. R&D is one area of operation that is challenging to take advantage of these technologies due to its high level of domain specialisation and creativity but the benefits could be significant. Recent developments of base level technologies such as artificial intelligence (AI)/machine learning (ML), robotics and high performance computing (HPC), to name a few, present disruptive and transformative technologies which could offer new insights, discovery methods and enhanced chemical control when combined in a digital ecosystem of connectivity, distributive services and decentralisation. At the fundamental level, research in these technologies has shown that new physical and chemical insights can be gained, which in turn can augment experimental R&D approaches through physics-based chemical simulation, data driven models and hybrid approaches. In all of these cases, high quality data is required to build and validate models in addition to the skills and expertise to exploit such methods. In this article we give an overview of some of the digital technology demonstrators we have developed for formulated product R&D. We discuss the challenges in building and deploying these demonstrators.<br>

Superionic Lithium Intercalation through 2 nm x 2 nm Columns in the Crystallographic Shear Phase Nb18W8O69

2019 ◽  
Author(s):  
Kent Griffith ◽  
Clare Grey
Keyword(s):  
High Performance ◽  
Rate Capability ◽  
Block Size ◽  
Lithium Intercalation ◽  
Resonance Spectroscopy ◽  
Complex Metal Oxides ◽  
Battery Electrode ◽  
Crystallographic Shear ◽  
Battery Material ◽  
First Time

Nb18W8O69 (9Nb2O5×8WO3) is the tungsten-rich end-member of the Wadsley–Roth crystallographic shear (cs) structures within the Nb2O5–WO3 series. It has the largest block size of any known, stable Wadsley–Roth phase, comprising 5 ´ 5 units of corner-shared MO6 octahedra between the shear planes, giving rise to 2 nm ´ 2 nm blocks. Rapid lithium intercalation is observed in this new candidate battery material and 7Li pulsed field gradient nuclear magnetic resonance spectroscopy – measured in a battery electrode for the first time at room temperature – reveals superionic lithium conductivity. In addition to its promising rate capability, Nb18W8O69 adds a piece to the larger picture of our understanding of high-performance Wadsley–Roth complex metal oxides.

https://imsciences.edu.pk/files/journals/vol12_2/New%201%20MA.864.pdf

2020 ◽  
Vol 12 (2) ◽  
pp. 19-50 ◽  
Author(s):  
Muhammad Siddique ◽  
Shandana Shoaib ◽  
Zahoor Jan
Keyword(s):  
Organizational Performance ◽  
Structural Equation ◽  
High Performance ◽  
Service Sector ◽  
Performance Outcomes ◽  
Theory And Practice ◽  
Relational Coordination ◽  
Multiple Sources ◽  
And Performance ◽  
High Level

A key aspect of work processes in service sector firms is the interconnection between tasks and performance. Relational coordination can play an important role in addressing the issues of coordinating organizational activities due to high level of interdependence complexity in service sector firms. Research has primarily supported the aspect that well devised high performance work systems (HPWS) can intensify organizational performance. There is a growing debate, however, with regard to understanding the “mechanism” linking HPWS and performance outcomes. Using relational coordination theory, this study examines a model that examine the effects of subsets of HPWS, such as motivation, skills and opportunity enhancing HR practices on relational coordination among employees working in reciprocal interdependent job settings. Data were gathered from multiple sources including managers and employees at individual, functional and unit levels to know their understanding in relation to HPWS and relational coordination (RC) in 218 bank branches in Pakistan. Data analysis via structural equation modelling, results suggest that HPWS predicted RC among officers at the unit level. The findings of the study have contributions to both, theory and practice.

scholarly journals Defect-induced B4C electrodes for high energy density supercapacitor devices

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Özge Balcı ◽  
Merve Buldu ◽  
Ameen Uddin Ammar ◽  
Kamil Kiraz ◽  
Mehmet Somer ◽  
...  
Keyword(s):  
Active Carbon ◽  
High Performance ◽  
Carbon Sources ◽  
High Energy ◽  
High Energy Density ◽  
Synthesis Conditions ◽  
High Energy Ball Mill ◽  
Energy Ball ◽  
G Ratio ◽  
Energy And Power Density

AbstractBoron carbide powders were synthesized by mechanically activated annealing process using anhydrous boron oxide (B2O3) and varying carbon (C) sources such as graphite and activated carbon: The precursors were mechanically activated for different times in a high energy ball mill and reacted in an induction furnace. According to the Raman analyses of the carbon sources, the I(D)/I(G) ratio increased from ~ 0.25 to ~ 0.99, as the carbon material changed from graphite to active carbon, indicating the highly defected and disordered structure of active carbon. Complementary advanced EPR analysis of defect centers in B4C revealed that the intrinsic defects play a major role in the electrochemical performance of the supercapacitor device once they have an electrode component made of bare B4C. Depending on the starting material and synthesis conditions the conductivity, energy, and power density, as well as capacity, can be controlled hence high-performance supercapacitor devices can be produced.

scholarly journals Dietary and Ergogenic Supplementation to Improve Elite Soccer Players’ Performance

2021 ◽  
pp. 1-7
Author(s):  
Haniel Fernandes
Keyword(s):  
Dietary Supplements ◽  
High Performance ◽  
Scientific Literature ◽  
Soccer Players ◽  
Competitive Sport ◽  
Beetroot Juice ◽  
Improve Performance ◽  
Sustained Release Tablets ◽  
High Level ◽  
Ergogenic Supplements

<b><i>Background:</i></b> Soccer is an extremely competitive sport, where the most match important moments can be defined in detail. Use of ergogenic supplements can be crucial to improve the performance of a high-performance athlete. Therefore, knowing which ergogenic supplements are important for soccer players can be an interesting strategy to maintain high level in this sport until final and decisive moments of the match. In addition, other supplements, such as dietary supplements, have been studied and increasingly referenced in the scientific literature. But, what if ergogenic supplements were combined with dietary supplements? This review brings some recommendations to improve performance of soccer athletes on the field through dietary and/or ergogenic supplements that can be used simultaneously. <b><i>Summary:</i></b> Soccer is a competitive sport, where the match important moments can be defined in detail. Thus, use of ergogenic supplements covered in this review can improve performance of elite soccer players maintaining high level in the match until final moments, such as creatine 3–5 g day<sup>−1</sup>, caffeine 3–6 mg kg<sup>−1</sup> BW around 60 min before the match, sodium bicarbonate 0.1–0.4 g kg<sup>−1</sup> BW starting from 30 to 180 min before the match, β-alanine 3.2 and 6.4 g day<sup>−1</sup> provided in the sustained-release tablets divided into 4 times a day, and nitrate-rich beetroot juice 60 g in 200 mL of water (6 mmol of NO3<sup>−</sup> L) around 120 min before match or training, including a combination possible with taurine 50 mg kg<sup>−1</sup> BW day<sup>−1</sup>, citrulline 1.2–3.4 g day<sup>−1</sup>, and arginine 1.2–6 g day<sup>−1</sup>. <b><i>Key Messages:</i></b> Soccer athletes can combine ergogenic and dietary supplements to improve their performance on the field. The ergogenic and dietary supplements used in a scientifically recommended dose did not demonstrate relevant side effects. The use of various evidence-based supplements can add up to further improvement in the performance of the elite soccer players.

scholarly journals Long Term Interactions of Native and Invasive Species in a Marine Protected Area Suggest Complex Cascading Effects Challenging Conservation Outcomes

Diversity ◽  
2021 ◽  
Vol 13 (2) ◽  
pp. 71
Author(s):  
Charalampos Dimitriadis ◽  
Ivoni Fournari-Konstantinidou ◽  
Laurent Sourbès ◽  
Drosos Koutsoubas ◽  
Stelios Katsanevakis
Keyword(s):  
Invasive Species ◽  
Native Species ◽  
High Performance ◽  
Marine Protected Area ◽  
Habitat Degradation ◽  
Population Increase ◽  
Rocky Reef ◽  
Cascading Effects ◽  
High Level

Understanding the interactions among invasive species, native species and marine protected areas (MPAs), and the long-term regime shifts in MPAs is receiving increased attention, since biological invasions can alter the structure and functioning of the protected ecosystems and challenge conservation efforts. Here we found evidence of marked modifications in the rocky reef associated biota in a Mediterranean MPA from 2009 to 2019 through visual census surveys, due to the presence of invasive species altering the structure of the ecosystem and triggering complex cascading effects on the long term. Low levels of the populations of native high-level predators were accompanied by the population increase and high performance of both native and invasive fish herbivores. Subsequently the overgrazing and habitat degradation resulted in cascading effects towards the diminishing of the native and invasive invertebrate grazers and omnivorous benthic species. Our study represents a good showcase of how invasive species can coexist or exclude native biota and at the same time regulate or out-compete other established invaders and native species.

scholarly journals Oxygen-Deficient Stannic Oxide/Graphene for Ultrahigh-Performance Supercapacitors and Gas Sensors

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 372
Author(s):  
Liyang Lin ◽  
Susu Chen ◽  
Tao Deng ◽  
Wen Zeng
Keyword(s):  
Energy Storage ◽  
Gas Sensors ◽  
High Performance ◽  
Gas Sensing ◽  
Synthesis Method ◽  
Rate Capability ◽  
Stannic Oxide ◽  
Energy Storage Devices ◽  
Graphene Nanocomposites ◽  
Storage Devices

The metal oxides/graphene nanocomposites have great application prospects in the fields of electrochemical energy storage and gas sensing detection. However, rational synthesis of such materials with good conductivity and electrochemical activity is the topical challenge for high-performance devices. Here, SnO2/graphene nanocomposite is taken as a typical example and develops a universal synthesis method that overcome these challenges and prepares the oxygen-deficient SnO2 hollow nanospheres/graphene (r-SnO2/GN) nanocomposite with excellent performance for supercapacitors and gas sensors. The electrode r-SnO2/GN exhibits specific capacitance of 947.4 F g−1 at a current density of 2 mA cm−2 and of 640.0 F g−1 even at 20 mA cm−2, showing remarkable rate capability. For gas-sensing application, the sensor r-SnO2/GN showed good sensitivity (~13.8 under 500 ppm) and short response/recovering time toward methane gas. These performance features make r-SnO2/GN nanocomposite a promising candidate for high-performance energy storage devices and gas sensors.

scholarly journals Evaluation of Static Mapping for Dynamic Space-Shared Multi-task Processing on FPGAs

2021 ◽  
Author(s):  
Umar Ibrahim Minhas ◽  
Roger Woods ◽  
Georgios Karakonstantis
Keyword(s):  
High Performance ◽  
Design Space Exploration ◽  
Design Space ◽  
System Throughput ◽  
Design Parameters ◽  
Temporal Constraints ◽  
Shared Resources ◽  
Task Processing ◽  
High Level ◽  
Performance Computing

AbstractWhilst FPGAs have been used in cloud ecosystems, it is still extremely challenging to achieve high compute density when mapping heterogeneous multi-tasks on shared resources at runtime. This work addresses this by treating the FPGA resource as a service and employing multi-task processing at the high level, design space exploration and static off-line partitioning in order to allow more efficient mapping of heterogeneous tasks onto the FPGA. In addition, a new, comprehensive runtime functional simulator is used to evaluate the effect of various spatial and temporal constraints on both the existing and new approaches when varying system design parameters. A comprehensive suite of real high performance computing tasks was implemented on a Nallatech 385 FPGA card and show that our approach can provide on average 2.9 × and 2.3 × higher system throughput for compute and mixed intensity tasks, while 0.2 × lower for memory intensive tasks due to external memory access latency and bandwidth limitations. The work has been extended by introducing a novel scheduling scheme to enhance temporal utilization of resources when using the proposed approach. Additional results for large queues of mixed intensity tasks (compute and memory) show that the proposed partitioning and scheduling approach can provide higher than 3 × system speedup over previous schemes.

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