scholarly journals PVDF/PVDF-g-PACMO blend hollow fiber membranes for hemodialysis: preparation, characterization, and performance

RSC Advances ◽  
2017 ◽  
Vol 7 (43) ◽  
pp. 26593-26600 ◽  
Author(s):  
Zihan An ◽  
Rui Xu ◽  
Fengying Dai ◽  
Gaojian Xue ◽  
Xiaoling He ◽  
...  
Keyword(s):  
Hollow Fiber ◽  
Hollow Fiber Membrane ◽  
Hollow Fiber Membranes ◽  
Fiber Membrane ◽  
Novel Approach ◽  
Fiber Membranes ◽  
And Performance

A novel approach to improve the biocompatibility of PVDF hollow fiber membrane by blending PVDF-g-PACMO copolymer for hemodialysis is provided.

Structure Morphology of Polyethersulfone Hollow Fiber Membrane via Immersion Precipitation Phase Inversion Process

2012 ◽  
Vol 152-154 ◽  
pp. 574-578 ◽  
Author(s):  
Ping Lan ◽  
Wei Wang
Keyword(s):  
Hollow Fiber ◽  
Phase Inversion ◽  
Hollow Fiber Membrane ◽  
Pure Water ◽  
Water Flux ◽  
Additive Concentration ◽  
Hollow Fiber Membranes ◽  
Fiber Membrane ◽  
Fiber Membranes ◽  
And Performance

Polyethersulfone (PES) hollow fiber membranes have been widely used in many fields, such as ultrafiltration, microfiltration, reverse osmosis, liquid/liquid or liquid/solid separation, gas separation, hemodialysis, and so on. In this paper, the sheet PES hollow fiber membranes were prepared. The morphology and performance of membranes can be controlled. By studying the influence of the compositions and conditions on the morphology and performance of PES hollow fiber membrane, the relationship of morphology and performance of the membrane is acquired. The additives were used such as glycerol, BuOH and PEG. In addition, immerse phase inversion was used as membranes preparation method. The morphology of the membrane was controlled by changing kinds of additive, concentration of additive and so on. It was found that the membrane morphologies were changed by additive obviously. Porosity , pure water flux, scanning electron microscopy(SEM) were used to characterize the morphology and performance of the membranes.

scholarly journals Fabrication of Manganese Oxide/PTFE Hollow Fiber Membrane and Its Catalytic Degradation of Phenol

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3651
Author(s):  
Yan Wang ◽  
Diefei Hu ◽  
Zhaoxia Zhang ◽  
Juming Yao ◽  
Jiri Militky ◽  
...  
Keyword(s):  
Manganese Oxide ◽  
Hollow Fiber ◽  
Photoelectron Spectroscopy ◽  
Hollow Fiber Membrane ◽  
Weak Acid ◽  
Environmental Pollutant ◽  
Catalytic Degradation ◽  
Hollow Fiber Membranes ◽  
Fiber Membrane ◽  
Fiber Membranes

P-aminophenol is a hazardous environmental pollutant that can remain in water in the natural environment for long periods due to its resistance to microbiological degradation. In order to decompose p-aminophenol in water, manganese oxide/polytetrafluoroethylene (PTFE) hollow fiber membranes were prepared. MnO2 and Mn3O4 were synthesized and stored in PTFE hollow fiber membranes by injecting MnSO4·H2O, KMnO4, NaOH, and H2O2 solutions into the pores of the PTFE hollow fiber membrane. The resultant MnO2/PTFE and Mn3O4/PTFE hollow fiber membranes were characterized using scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and thermal analysis (TG). The phenol catalytic degradation performance of the hollow fiber membranes was evaluated under various conditions, including flux, oxidant content, and pH. The results showed that a weak acid environment and a decrease in flux were beneficial to the catalytic degradation performance of manganese oxide/PTFE hollow fiber membranes. The catalytic degradation efficiencies of the MnO2/PTFE and Mn3O4/PTFE hollow fiber membranes were 70% and 37% when a certain concentration of potassium monopersulfate (PMS) was added, and the catalytic degradation efficiencies of MnO2/PTFE and Mn3O4/PTFE hollow fiber membranes were 50% and 35% when a certain concentration of H2O2 was added. Therefore, the manganese oxide/PTFE hollow fiber membranes represent a good solution for the decomposition of p-aminophenol.

A MORPHOLOGICAL STUDY OF NICKEL OXIDE HOLLOW FIBER MEMBRANES: EFFECT OF AIR GAP & SINTERING TEMPERATURE

2016 ◽  
Vol 78 (12) ◽  
Author(s):  
Mohd Izzat Iqbal Mohd Zahar ◽  
Mohd Hafiz Dzarfan Othman ◽  
Mukhlis A Rahman ◽  
Juhana Jaafar ◽  
Siti Khadijah Hubadillah
Keyword(s):  
Mechanical Strength ◽  
Nickel Oxide ◽  
Hollow Fiber ◽  
Hollow Fiber Membrane ◽  
Air Gap ◽  
Hollow Fibers ◽  
Asymmetric Structure ◽  
Hollow Fiber Membranes ◽  
Fiber Membrane ◽  
Fiber Membranes

A systematic study of the air gap effects on morphology and mechanical strength of Nickel Oxide (NiO) hollow fiber membranes has been carried out. The hollow fibers were prepared using the dry-jet wet spinning process using a dope solution containing NiO/N-methyl-2-pyrrolidone (NMP)/Arlacel/Poly(ethylene sulphide) with a weight ratio of 70/22.9/0.1/7. Tap water was used as internal and external coagulants. The cross-sectional structure of precursors hollow fiber membrane was studied by scanning electron microscopy (SEM). The results showed that both inner and outer finger-like voids of the hollow membrane were determined by the air gap distance. Experimental results indicated that an increase in air gap distance, from 100 mm to 200 mm, gave a hollow fiber with a lower mechanical strength and higher percentages of cross section surface area covered by finger-like voids structures. This study also revealed that the air gap introduced an elongation stress because of gravity on the internal or external surfaces of the NiO hollow fibers. A more effective hollow fiber membrane which is in asymmetric structure instead of symmetric structure can be produced by using air gap higher than 200 mm. 

scholarly journals Effective Parameters on Fabrication and Modification of Braid Hollow Fiber Membranes: A Review

Membranes ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 884
Author(s):  
Azadeh Nazif ◽  
Hamed Karkhanechi ◽  
Ehsan Saljoughi ◽  
Seyed Mahmoud Mousavi ◽  
Hideto Matsuyama
Keyword(s):  
Hollow Fiber ◽  
Hollow Fiber Membrane ◽  
High Surface ◽  
High Surface Area ◽  
Hollow Fiber Membranes ◽  
Fiber Membrane ◽  
Effective Parameters ◽  
Fiber Membranes ◽  
Aeration Process ◽  
Fabrication Parameters

Hollow fiber membranes (HFMs) possess desired properties such as high surface area, desirable filtration efficiency, high packing density relative to other configurations. Nevertheless, they are often possible to break or damage during the high-pressure cleaning and aeration process. Recently, using the braid reinforcing as support is recommended to improve the mechanical strength of HFMs. The braid hollow fiber membrane (BHFM) is capable apply under higher pressure conditions. This review investigates the fabrication parameters and the methods for the improvement of BHFM performance.

Computational Study of Reverse Osmosis Desalination Process: Hollow Fiber Module

2017 ◽  
Author(s):  
Mustafa Usta ◽  
Ali E. Anqi ◽  
Michael Morabito ◽  
Alaa Hakim ◽  
Mohammed Alrehili ◽  
...  
Keyword(s):  
Flow Field ◽  
Mass Transport ◽  
Reverse Osmosis ◽  
Hollow Fiber ◽  
Hollow Fiber Membrane ◽  
Hollow Fiber Membranes ◽  
Fiber Membrane ◽  
Flow Rates ◽  
Fiber Membranes ◽  
Feed Channel

Reverse Osmosis (RO) is a process whereby solutes are removed from a solution by means of a semipermeable membrane. Providing access to clean water is one of our generation’s grand engineering challenges, and RO processes are taking center stage in the global implementation of water purification technologies. In this work, computational fluid dynamics simulations are performed to elucidate the steady state phenomena associated with the mass transport of solution through cylindrical hollow fiber membranes in hopes of optimizing RO technologies. The Navier-Stokes and mass transport equations are solved numerically to determine the flow field and solute concentration distribution in the hollow fiber membrane bank, which is a portion of the three-dimensional feed channel containing a small collection of fibers. The k-ω Shear Stress Transport turbulence model is employed to characterize the flow field. Special attention is given to the prediction of water passage through hollow fiber membranes by the use of the solution-diffusion model, which couples the salt gradient, water flux, and local pressure at the membrane surface. This work probes hollow fiber membrane arrangement in the feed channel by considering inline and staggered alignments. Feed flow rates for Reynolds number values ranging between 400 and 1000 are considered. Increased momentum mixing within the feed channel solution can substantially enhance the system efficiency, and hollow fiber membrane arrangements and feed flow rates dictate the momentum mixing intensity. Velocity and vorticity iso-surfaces of the flow domain are presented in order to assess the momentum mixing achieved with various hollow fiber membrane arrangements and flow rates. The total water permeation rate per hour is calculated to compare system efficiencies, and the coefficient of performance is calculated to compare membrane performance relative to the necessary power input, both for the various hollow fiber membrane arrangements and feed flow rates.

scholarly journals Study on the effect of spinning conditions on the performance of PSf/PVP ultrafiltration hollow fiber membrane

2018 ◽  
Vol 14 (3) ◽  
pp. 343-347 ◽  
Author(s):  
Sumarni Mansur ◽  
Mohd Hafiz Dzarfan Othman ◽  
Ahmad Fauzi Ismail ◽  
Muhammad Nidzhom Zainol Abidin ◽  
Noresah Said ◽  
...  
Keyword(s):  
Pore Size ◽  
Hollow Fiber ◽  
Phase Inversion ◽  
Hollow Fiber Membrane ◽  
Hollow Fibers ◽  
Hollow Fiber Membranes ◽  
Fiber Membrane ◽  
Membrane Pore ◽  
Phase Inversion Technique ◽  
Fiber Membranes

Asymmetric, porous ultrafiltration polysulfone (PSf) hollow fiber membranes were fabricated via the dry-wet phase inversion spinning technique specifically for haemodialysis membrane. The objective was to discover the suitable spinning condition for the fabrication of ultrafiltration hollow fiber membrane with desired sponge-like structure. During haemodialysis procedure, uremic toxins such as urea and creatinine range from size 10,000-55,000 Da needs to be excreted out from the blood. While, proteins such as albumin (66,000 Da) need to be retained. The physical structure or morphology of a fabricated membrane is a major concern in determining the efficiency of a dialysis membrane. Different type of membrane morphology will give a different result in term of its permeability and clearance efficiency. The phase inversion spinning technique is suitable in producing ultrafiltation (UF) membrane where the average pore size of the fabricated membrane is in the range of 0.001 – 0.1 µm. However, there is many factors need to be controlled and manipulated in the phase inversion technique. In this study, the effect of the PVP on membrane pore size and performances were analysed. The contact angle measurement was measured to determine the hydrophilicity of the fibers. The hydrophilic polymer is favorable to avoid fouling and increase its biocompatibility. Furthermore, the diameter of the hollow fibers was determined using a scanning electron microscope (SEM). The effects of different morphology of the hollow fibers on the performance of the membranes were evaluated by pure water flux and BSA rejection. Both techniques were tested using permeation flux system. Based on the results obtained, it is found that the finger-like macrovoids in PSf hollow fiber membranes were suppressed by adding 8% PVP (Mw of 360 kDa) into the spinning dope solution as the result of a drastic increase in dope viscosity. On top of that, fiber spun with 8% PVP show more porous structure which contribute to higher permeability of the membrane. The result of this study can benefit to the membrane field of research especially in membrane technology for haemodialysis application.

scholarly journals Pore Structure and Properties of PEEK Hollow Fiber Membranes: Influence of the Phase Structure Evolution of PEEK/PEI Composite

Polymers ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1398 ◽  
Author(s):  
Gong Chen ◽  
Yuan Chen ◽  
Tingjian Huang ◽  
Zhongchen He ◽  
Jianjun Xu ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Hollow Fiber ◽  
Phase Structure ◽  
Annealing Temperature ◽  
Hollow Fiber Membrane ◽  
Structure Evolution ◽  
Structure And Properties ◽  
Hollow Fiber Membranes ◽  
Fiber Membrane ◽  
Fiber Membranes

Poly(ether ether ketone) (PEEK) hollow fiber membranes were successfully prepared from miscible blends of PEEK and polyetherimide (PEI) via thermally-induced phase separation (TIPS) with subsequent extraction of the PEI diluent. The phase structure evolution, extraction kinetics, membrane morphology, pore size distribution and permeability for the hollow fiber membrane were studied in detail. Extraction experiments, differential scanning calorimetry (DSC) and dynamic mechanical thermal analysis (DMA) studies showed that the heat treatment had a significant influence on the two-phase structure of PEEK/PEI, and that it was controlled by the crystallization kinetic of PEEK and the diffusion kinetic of PEI. As the annealing temperature increased, the controlling factor of the phase separation changed from PEEK crystallization to PEI diffusion, and the main distribution of the amorphous PEI chains were changed from the interlamellar region to the interfibrillar or interspherulitic regions of PEEK crystallization. When the annealing temperature increased from 240 °C to 280 °C, the extracted amount of PEI increased from 85.19 to 96.24 wt %, and the pore diameter of PEEK membrane increased from 10.59 to 37.85 nm, while the surface area of the PEEK membrane decreased from 111.9 to 83.69 m2/g. Moreover, the water flux of the PEEK hollow fiber membranes increased from 1.91 × 10−2 to 1.65 × 10−1 L h−1 m−2 bar−1 as the annealing temperature increased from 240 °C to 270 °C. The structure and properties of the PEEK hollow fiber membrane can be effectively controlled by regulating heat treatment conditions.

High Flux Polyamide Composite Hollow Fiber Membranes for Reverse Osmosis Applications

2006 ◽  
Vol 930 ◽  
Author(s):  
Ian D. Norris ◽  
Malcolm C. Morrison ◽  
Benjamin R. Mattes
Keyword(s):  
Hollow Fiber ◽  
Brackish Water ◽  
Interfacial Polymerization ◽  
Hollow Fiber Membrane ◽  
Water Flux ◽  
Membrane Element ◽  
Hollow Fiber Membranes ◽  
Fiber Membrane ◽  
Figures Of Merit ◽  
Fiber Membranes

ABSTRACTHigh flux composite hollow fiber membranes for brackish water desalination based on the interfacial polymerization of a cross-linked polyamide salt rejecting layer onto a semi-permeable hollow fiber support have been developed. These hollow fiber membranes exploit the advantages of using a thin-film composite reverse osmosis membrane (higher flux and salt rejection) with the higher surface area/volume ratio of hollow fiber membrane elements. The composite hollow fiber membranes were prepared by coating a polysulfone hollow fiber with a polyamide salt rejecting layer based on the interfacial polymerization reaction between m-phenylenediamine and trimesoyl chloride/isophthaloyl dichloride. The RO figures-of-merit of these composite polyamide hollow fiber membranes were evaluated for the desalination of a synthetic brackish water feed (2,000 ppm NaCl) at 225 psi over a 60 hour period. After an initial break-in period in which the flux declined 30% due to membrane compaction, the stabilized RO figures-of-merit for these hollow fiber membranes were a water flux of 280 L/m2·day and a salt rejection of 99.1%. Based on the water flux and packing density of the membrane, it is estimated that the stable production of potable water of a hollow fiber membrane element containing these composite membranes will be between 20 and 30% greater than that of a similarly sized spiral wound brackish water membrane element.

Influence of Spinneret Dimensional Parameters on Gas Separation Properties of Polysulfone Hollow Fiber Membranes

2021 ◽  
Vol 899 ◽  
pp. 451-455
Author(s):  
Dmitry N. Matveev ◽  
Vladimir P. Vasilevsky
Keyword(s):  
Hollow Fiber ◽  
Gas Permeability ◽  
Hollow Fiber Membrane ◽  
Average Pore Size ◽  
Hollow Fiber Membranes ◽  
Fiber Membrane ◽  
Average Pore ◽  
Fiber Membranes ◽  
Dimensional Parameters ◽  
The Ideal

The design and dimensional characteristics of the spinneret affect not only the geometry of the hollow fiber, but also the transport properties of the hollow fiber membranes. In the literature available today, there is a limited number of works in which the influence of the design and dimensional characteristics of the spinneret is studied. In this work, using the example of polysulfone hollow fiber membranes, it was shown that the use of a spinneret with smaller annular diameters leads to an increase in the gas permeability of the hollow fiber membrane with a decrease in the value of the ideal selectivity for the He/CO2 gas pair. It was found that using the spinneret with large annular diameters, the hollow fiber membrane is obtained with a smaller value of the average pore size of the flow, which is in agreement with the obtained data on gas permeability.

scholarly journals Kinetic Analysis of Lidocaine Elimination by Pig Liver Cells Cultured in 3D Multi-Compartment Hollow Fiber Membrane Network Perfusion Bioreactors

2021 ◽  
Vol 8 (8) ◽  
pp. 104
Author(s):  
Gerardo Catapano ◽  
Juliane K. Unger ◽  
Elisabetta M. Zanetti ◽  
Gionata Fragomeni ◽  
Jörg C. Gerlach
Keyword(s):  
Kinetic Analysis ◽  
Drug Screening ◽  
Hollow Fiber ◽  
Hollow Fiber Membrane ◽  
Liver Cells ◽  
Fiber Membrane ◽  
Bioreactor Design ◽  
Drug Adsorption ◽  
And Performance ◽  
Cells Cultured

Liver cells cultured in 3D bioreactors is an interesting option for temporary extracorporeal liver support in the treatment of acute liver failure and for animal models for preclinical drug screening. Bioreactor capacity to eliminate drugs is generally used for assessing cell metabolic competence in different bioreactors or to scale-up bioreactor design and performance for clinical or preclinical applications. However, drug adsorption and physical transport often disguise the intrinsic drug biotransformation kinetics and cell metabolic state. In this study, we characterized the intrinsic kinetics of lidocaine elimination and adsorption by porcine liver cells cultured in 3D four-compartment hollow fiber membrane network perfusion bioreactors. Models of lidocaine transport and biotransformation were used to extract intrinsic kinetic information from response to lidocaine bolus of bioreactor versus adhesion cultures. Different from 2D adhesion cultures, cells in the bioreactors are organized in liver-like aggregates. Adsorption on bioreactor constituents significantly affected lidocaine elimination and was effectively accounted for in kinetic analysis. Lidocaine elimination and cellular monoethylglicinexylidide biotransformation featured first-order kinetics with near-to-in vivo cell-specific capacity that was retained for times suitable for clinical assist and drug screening. Different from 2D cultures, cells in the 3D bioreactors challenged with lidocaine were exposed to close-to-physiological lidocaine and monoethylglicinexylidide concentration profiles. Kinetic analysis suggests bioreactor technology feasibility for preclinical drug screening and patient assist and that drug adsorption should be accounted for to assess cell state in different cultures and when laboratory bioreactor design and performance is scaled-up to clinical use or toxicological drug screening.

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