Formation of resorcinol-formaldehyde hollow nanoshells through a dissolution–regrowth process

Nanoscale ◽  
2020 ◽  
Vol 12 (28) ◽  
pp. 15460-15465
Author(s):  
Shuai Zhou ◽  
Yaocai Bai ◽  
Wenjing Xu ◽  
Ji Feng ◽  
Xiaojing Wang ◽  
...  
Keyword(s):  
Shell Thickness ◽  
Colloidal Particles ◽  
Resorcinol Formaldehyde ◽  
Hollow Nanostructures

Dissolution and regrowth of resorcinol formaldehyde (RF) colloidal particles can occur spontaneously when they are subjected to etching in solvents such as ethanol and tetrahydrofuran, resulting in the formation of hollow nanostructures with controllable shell thickness.

scholarly journals Thin shell aerogel fabrication for FIREX-I targets using high viscosity (phloroglucinol carboxylic acid)/formaldehyde solution

2008 ◽  
Vol 26 (3) ◽  
pp. 449-453 ◽  
Author(s):  
H. Yang ◽  
K. Nagai ◽  
M. Nakai ◽  
T. Norimatsu
Keyword(s):  
Carboxylic Acid ◽  
Thin Shell ◽  
Shell Thickness ◽  
High Viscosity ◽  
Formaldehyde Solution ◽  
Resorcinol Formaldehyde ◽  
Foam Structure ◽  
Final Density ◽  
Emulsion Process ◽  
High Level

AbstractCapsules with a thin aerogel shell were prepared by the OO/W/OIemulsion process. (Phloroglucinol carboxylic acid)/formaldehyde (PF) was used as the water phase (W) solution to form the shell of the capsule. PF is a linear polymer prepared from phloroglucinol carboxylic acid. The viscosity of the PF solution can reach a high level of 9×10−5m2/s without gelation while resorcinol/formaldehyde (RF) gelates at ~3–4×10−5m2/s. Using the viscous PF solution, capsule with a 17 µm gel shell was fabricated. This thickness satisfies the specification of the first phase of Fast Ignition Realization Experiment (FIREX-I) at Osaka University. When PF gel was extracted to remove the organic solvent, shrinkage of 9% occurred. The final density of the PF aerogel was 145 mg/cm3. Both the shell thickness and density can satisfy the specification of FIREX-I. The pore size of the PF aerogel was less than 100 nm while that of RF was 200–500 nm. The SEM showed that PF had particle-like foam structure while RF had fibrous-like foam structure.

scholarly journals Resorcinol-Formaldehyde Carbon Gels Adsorption: A Commentary

2019 ◽  
Vol 27 (2) ◽  
pp. 227-250
Author(s):  
Azrul Nurfaiz Mohd Faizal ◽  
Muhammad Abbas Ahmad Zaini
Keyword(s):  
Recent Progress ◽  
Colloidal Particles ◽  
Scale Up ◽  
Batch Mode ◽  
Resorcinol Formaldehyde ◽  
Lack Of Information ◽  
Column Adsorption ◽  
Carbon Gels ◽  
Adsorption Of Water ◽  
Carbon Gel

Abstract This work is aimed at highlighting the recent progress of resorcinol-formaldehyde carbon gels adsorption of water pollutants. The synthesis strategies of the carbon gels were discussed to shed some light on the development of mesoporous matrix of carbon gel via the agglomeration of colloidal particles. The surface area of adsorbent can reach as high as 3000 m2/g by CO2 activation, while the surface functionalities are introduced through modification techniques for improving the removal performance. However, most of the recent studies are inclined at batch mode of adsorption with lack of information on the scale-up of the process in continuous mode. Carbon gel is a special class of porous material that can be moulded into desired size, hence a promising adsorbent candidate for monoliths and packings in column adsorption. Therefore, more dedicated works should be established to materialize the applications of carbon gel in column adsorption, particularly at industrial scale.

Effect of high pressure on growth of colloidal particles during sol–gel phase transition of resorcinol–formaldehyde solution

Adsorption ◽  
2019 ◽  
Vol 25 (6) ◽  
pp. 1115-1120 ◽  
Author(s):  
T. Yamamoto ◽  
M. Tayakout-Fayolle ◽  
K. Iimura ◽  
H. Satone ◽  
T. Kakibe ◽  
...  
Keyword(s):  
Phase Transition ◽  
High Pressure ◽  
Colloidal Particles ◽  
Sol Gel ◽  
Formaldehyde Solution ◽  
Resorcinol Formaldehyde ◽  
Gel Phase

A Resorcinol-Formaldehyde Resin as an Embedding Material for Electron Microscopy of Membranes

1969 ◽  
Vol 27 ◽  
pp. 328-329 ◽  
Author(s):  
J. G. Robertson ◽  
D. F. Parsons
Keyword(s):  
Electron Microscopy ◽  
Osmium Tetroxide ◽  
Neutral Lipids ◽  
Lipid Extraction ◽  
Water Soluble ◽  
Formaldehyde Resin ◽  
Electron Microscope Autoradiography ◽  
Resorcinol Formaldehyde ◽  
Major Disadvantage ◽  
Cell Organization

The extraction of lipids from tissues during fixation and embedding for electron microscopy is widely recognized as a source of possible artifact, especially at the membrane level of cell organization. Lipid extraction is also a major disadvantage in electron microscope autoradiography of radioactive lipids, as in studies of the uptake of radioactive fatty acids by intestinal slices. Retention of lipids by fixation with osmium tetroxide is generally limited to glycolipids, phospholipids and highly unsaturated neutral lipids. Saturated neutral lipids and sterols tend to be easily extracted by organic dehydrating reagents prior to embedding. Retention of the more saturated lipids in embedded tissue might be achieved by developing new cross-linking reagents, by the use of highly water soluble embedding materials or by working at very low temperatures.

Ultrastructure of Lymphatic Capillaries in the Transport of Colloidal Particles

1967 ◽  
Vol 25 ◽  
pp. 186-187
Author(s):  
L. V. Leak ◽  
J. F. Burke
Keyword(s):  
Connective Tissue ◽  
Colloidal Particles ◽  
Ultrastructural Level ◽  
Vital Role ◽  
Time Intervals ◽  
Thorium Dioxide ◽  
Lymphatic Capillary ◽  
Tissue Area ◽  
Rapid Removal ◽  
Tissue Fluids

The vital role played by the lymphatic capillaries in the transfer of tissue fluids and particulate materials from the connective tissue area can be demonstrated by the rapid removal of injected vital dyes into the tissue areas. In order to ascertain the mechanisms involved in the transfer of substances from the connective tissue area at the ultrastructural level, we have injected colloidal particles of varying sizes which range from 80 A up to 900-mμ. These colloidal particles (colloidal ferritin 80-100A, thorium dioxide 100-200 A, biological carbon 200-300 and latex spheres 900-mμ) are injected directly into the interstitial spaces of the connective tissue with glass micro-needles mounted in a modified Chambers micromanipulator. The progress of the particles from the interstitial space into the lymphatic capillary lumen is followed by observing tissues from animals (skin of the guinea pig ear) that were injected at various time intervals ranging from 5 minutes up to 6 months.

Deposited emulsion particles in the pores of aluminum oxide film

1978 ◽  
Vol 36 (1) ◽  
pp. 450-451
Author(s):  
Michio Ashida ◽  
Yasukiyo Ueda
Keyword(s):  
Oxide Film ◽  
Acid Solution ◽  
Barrier Layer ◽  
Colloidal Particles ◽  
Oxalic Acid Solution ◽  
Anodic Oxide ◽  
Anodic Oxide Film ◽  
Carbon Replica ◽  
Sectioning Method ◽  
Thin Sectioning

An anodic oxide film is formed on aluminum in an acidic elecrolyte during anodizing. The structure of the oxide film was observed directly by carbon replica method(l) and ultra-thin sectioning method(2). The oxide film consists of barrier layer and porous layer constructed with fine hexagonal cellular structure. The diameter of micro pores and the thickness of barrier layer depend on the applying voltage and electrolyte. Because the dimension of the pore corresponds to that of colloidal particles, many metals deposit in the pores. When the oxide film is treated as anode in emulsion of polyelectrolyte, the emulsion particles migrate onto the film and deposit on it. We investigated the behavior of the emulsion particles during electrodeposition.Aluminum foils (99.3%) were anodized in either 0.25M oxalic acid solution at 30°C or 3M sulfuric acid solution at 20°C. After washing with distilled water, the oxide films used as anode were coated with emulsion particles by applying voltage of 200V and then they were cured at 190°C for 30 minutes.

COUPLING OF COLLOIDAL PARTICLES AND RECOILLESS FRACTION

1976 ◽  
Vol 37 (C6) ◽  
pp. C6-273-C6-276
Author(s):  
H. J. ÜBELHACK ◽  
F. H. WITTMANN
Keyword(s):  
Colloidal Particles ◽  
Recoilless Fraction

How to use alum with cationic dispersed rosin size

TAPPI Journal ◽  
2016 ◽  
Vol 15 (5) ◽  
pp. 331-335 ◽  
Author(s):  
LEBO XU ◽  
JEREMY MYERS ◽  
PETER HART
Keyword(s):  
Zeta Potential ◽  
Colloidal Particles ◽  
Streaming Potential ◽  
Excessive Amount ◽  
Paper Machine ◽  
Optimum Amount ◽  
Potential Measurement ◽  
Streaming Current ◽  
Wide Range ◽  
Laboratory Results

Retention of cationic dispersed rosin size was studied via turbidity measurements on stock filtrate with different alum and dispersed rosin size dosages. Stock charge characteristics were analyzed using both an analysis of charge demand determined via a streaming current detector and an evaluation of zeta potential of the fibers by streaming potential measurement. The results indicated that an optimum amount of alum existed such that good sizing retention was maintained throughout a wide range of dispersed rosin size dosages. However, when an excessive amount of alum was used and fines and colloidal particles were transitioned from anionic to cationic, the cationic size retention was reduced. Laboratory results were confirmed with a paper machine trial. All data suggested that a stock charge study was necessary to identify optimal alum dosage for a cationic dispersed rosin sizing program.

Japon Bıldırcını Rasyonlarında Soya Küspesi Yerine Pamuk Tohumu Küspesi İkamesinin Yumurta Verim ve Kalite Özelliklerine Etkisi

2013 ◽  
Vol 1 (1) ◽  
pp. 44 ◽  
Author(s):  
Arda Yıldırım ◽  
Ergin Öztürk
Keyword(s):  
Protein Content ◽  
Cottonseed Meal ◽  
Soybean Meal ◽  
Shell Thickness ◽  
Egg Production ◽  
Egg Quality ◽  
Yield Traits

This study was conducted to determine the effect of cottonseed meal (CSM) incorporated into laying rations in place of soybean meal (SBM) at different ratios on yield traits. The birds began to lay at 6th week, 180 female and 45 male quails were used in laying period experiment. Birds were fed with rations containing 20% CP and 3000 Kcal/kg ME up to 20-week age (Laying period). CSM as a substitute, five different rations of the protein content (0, 30, 58, 86 and 100%) for SBM to basal diets based on corn-soybean meal were used. The results showed that there were no differences in terms of egg yield traits, cumulative feed consumptions and viabilities during the laying period. The highest dry shell rate and shell thickness were obtained from 5th group and 1st group, respectively. As a result, adding CSM instead of SBM in laying period were no significantly differences in terms of egg production and egg quality in laying period.

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