scholarly journals Electrical properties and charge compensation mechanisms of Cr-doped rutile, TiO2

Author(s):  
Yun Dang ◽  
Xin Li Phuah ◽  
Han Wang ◽  
Bo Yang ◽  
Haiyan Wang ◽  
...  

Ti1−xCrxO2−x/2−δ (0 ≤ x ≤ 0.05) ceramics show high electronic conductivity at low x attributed to oxygen vacancy compensation by co-doping with Ti3+ and Cr3+ ions. At intermediate x, p-type conductivity is attributed to hole location on under-bonded oxygen.

2015 ◽  
Vol 17 (26) ◽  
pp. 16705-16708 ◽  
Author(s):  
Wenzhe Niu ◽  
Hongbin Xu ◽  
Yanmin Guo ◽  
Yaguang Li ◽  
Zhizhen Ye ◽  
...  

The S dopants in S–N co-doped ZnO contribute to easier doping and p-type conductivity, as concluded by experiment and calculations.


2000 ◽  
Vol 5 (S1) ◽  
pp. 216-222
Author(s):  
J.R.L. Fernandez ◽  
V.A. Chitta ◽  
E. Abramof ◽  
A. Ferreira da Silva ◽  
J.R. Leite ◽  
...  

Carrier concentration and mobility were measured for intrinsic cubic InN and GaN, and for Si-doped cubic GaN as a function of temperature. Metallic n-type conductivity was found for the InN, while background p-type conductivity was observed for the intrinsic GaN layer. Doping the cubic GaN with Si two regimes were observed. For low Si-doping concentrations, the samples remain p-type. Increasing the Si-doping level, the background acceptors are compensated and the samples became highly degenerated n-type. From the carrier concentration dependence on temperature, the activation energy of the donor and acceptor levels was determined. Attempts were made to determine the scattering mechanisms responsible for the behavior of the mobility as a function of temperature.


2019 ◽  
Vol 7 (40) ◽  
pp. 23038-23045 ◽  
Author(s):  
Rongrong Pan ◽  
Jia Liu ◽  
Yuemei Li ◽  
Xinyuan Li ◽  
Erhuan Zhang ◽  
...  

Here we show a novel strategy for tailoring the synergistic electrical properties of metal@semiconductor hybrid nanocrystals (HNCs) based on cation exchange-enabled electronic doping.


CrystEngComm ◽  
2018 ◽  
Vol 20 (11) ◽  
pp. 1520-1526 ◽  
Author(s):  
M. V. Derdzyan ◽  
K. L. Hovhannesyan ◽  
A. V. Yeganyan ◽  
R. V. Sargsyan ◽  
A. Novikov ◽  
...  

Using a combination of experimental methods, the substitution tendencies of Li+ and involved charge compensation mechanisms are determined and compared in two important similar scintillators, LuAG:Ce and YAG:Ce.


2008 ◽  
Vol 01 (02) ◽  
pp. 97-104 ◽  
Author(s):  
JANINA MOLENDA ◽  
JACEK MARZEC

The paper presents a review of the structural, electrical and electrochemical properties of LiFePO 4 pospho-olivine dopped with W , Ti , Al and manganese substituted LiFe 1-y Mn y PO 4, synthesized at high temperatures as well as preparation method of LiFePO 4– Fe 2 P composite phases. The nature of the metallic type conductivity of doped phospho-olivine is discussed and some fundamental arguments against the bulk nature of the observed high electronic conductivity are presented.


2019 ◽  
Vol 20 (4) ◽  
pp. 372-375
Author(s):  
V.V. Prokopiv ◽  
O.B. Kostyuk ◽  
B.S. Dzundza ◽  
T.M. Mazur ◽  
L.V. Turovska ◽  
...  

The technique of obtaining thin layers of cadmium telluride of p-type conductivity by chemical doping of the surface of cadmium telluride crystals by calcium is described. The dependences of the electrical properties of the obtained films on the technological factors of their production are investigated. The conductivity of the doped layer, velocity and depth of diffusion are determined.


2015 ◽  
Vol 2015 ◽  
pp. 1-13 ◽  
Author(s):  
S. C. Canobre ◽  
F. F. S. Xavier ◽  
W. S. Fagundes ◽  
A. C. de Freitas ◽  
F. A. Amaral

Polypyrrole (PPy) is one of the most studied conducting polymers and a very promising material for various applications such as lithium-ion secondary batteries, light-emitting devices, capacitors, and supercapacitors, owing to its many advantages, including good processability, easy handling, and high electronic conductivity. In this work, PPy films were chemically and electrochemically synthesized, both in and around carbon nanotubes (CNTs). The cyclic voltammograms of the device, composed of the electrochemically synthesized PPy/CNT composites as working and counter electrodes (Type I supercapacitor with p-type doping), showed a predominantly capacitive profile with low impedance values and good electrochemical stability, with the anodic charge remaining almost constant (11.38 mC), a specific capacitance value of 530 F g−1after 50 charge and discharge cycles, and a coulombic efficiency of 99.2%. The electrochemically synthesized PPy/CNT composite exhibited better electrochemical properties compared to those obtained for the chemically synthesized composite. Thus, the electrochemically synthesized PPy/CNT composite is a promising material to be used as electrodes in Type I supercapacitors.


2015 ◽  
Vol 821-823 ◽  
pp. 9-13 ◽  
Author(s):  
Takeshi Mitani ◽  
Naoyoshi Komatsu ◽  
Tetsuo Takahashi ◽  
Tomohisa Kato ◽  
Toru Ujihara ◽  
...  

We have investigated the solution growth under various Al-N co-doping conditions. Both p-type and n-type 4H-SiC were successfully grown under Al-N co-doping conditions, while using the effect of Al-addition to stabilize both growth surface and polytype. The doping and electrical properties were investigated systematically. Interaction between Al and N in the incorporation process and electrical property under heavily co-doped conditions were discussed.


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