scholarly journals On the impact of the laser radiation wavelength and the concentration of quantum dots on the luminescence spectra of colloid solution and QD-doped nanocomposites

2019 ◽  
Vol 220 ◽  
pp. 03014
Author(s):  
A.E. Eskova ◽  
A.I. Arzhanov ◽  
K.A. Magaryan ◽  
N.A. Koverga ◽  
K.R. Karimullin ◽  
...  

The influence of the concentration and the laser excitation wavelength on the width and luminescence spectrum maximum of CdSe/CdS /ZnS quantum dots in the toluene solution and doped on the glass plate was studied. It was shown that the wavelength of the exciting laser does not affect the width and peak center of the luminescence spectrum of the samples under the study. Possible mechanisms of the quantum dots concentration influence on studied parameters are analyzed.

2014 ◽  
Vol 50 (82) ◽  
pp. 12389-12391 ◽  
Author(s):  
Noor Aniza Harun ◽  
Benjamin R. Horrocks ◽  
David A. Fulton

Luminescence and SERS signals are simultaneously enhanced with a single excitation wavelength by co-encapsulating silicon quantum dots and Au–Ag alloy nanoparticles encoded with Raman reporter molecules inside polymeric nanoparticles.


Nanophotonics ◽  
2020 ◽  
Vol 9 (12) ◽  
pp. 4009-4019
Author(s):  
Artur Movsesyan ◽  
Gwénaëlle Lamri ◽  
Sergei Kostcheev ◽  
Anke Horneber ◽  
Annika Bräuer ◽  
...  

AbstractMulti-resonant plasmonic simple geometries like nanocylinders and nanorods are highly interesting for two-photon photoluminescence and second harmonic generation applications, due to their easy fabrication and reproducibility in comparison with complex multi-resonant systems like dimers or nanoclusters. We demonstrate experimentally that by using a simple gold nanocylinder we can achieve a double resonantly enhanced two-photon photoluminescence of quantum dots, by matching the excitation wavelength of the quantum dots with a dipolar plasmon mode, while the emission is coupled with a radiative quadrupolar mode. We establish a method to separate experimentally the enhancement factor at the excitation and at the emission wavelengths for this double resonant system. The sensitivity of the spectral positions of the dipolar and quadrupolar plasmon resonances to the ellipticity of the nanocylinders and its impact on the two-photon photoluminescence enhancement are discussed.


2007 ◽  
Vol 06 (03n04) ◽  
pp. 215-219
Author(s):  
E. P. DOMASHEVSKAYA ◽  
V. A. TEREKHOV ◽  
V. M. KASHKAROV ◽  
S. YU. TURISHCHEV ◽  
S. L. MOLODTSOV ◽  
...  

Ultrasoft X-ray emission spectra (USXES) and X-ray absorption near-edge structure (XANES) spectra with the use of synchrotron radiation in the range of P L2,3-edges were obtained for the first time for nanostructures with InP quantum dots grown on GaAs 〈100〉 substrates by vapor-phase epitaxy from metal–organic compounds. These spectra represent local partial density of states in the valence and conduction bands. The additional XANES peak is detected; its intensity depends on the number of monolayers forming quantum dots. Assumptions are made on the band-to-band origin of luminescence spectra in the studied nanostructures.


2021 ◽  
Author(s):  
Yanyan Li ◽  
Lifan Shen ◽  
E.Y.B. Pun ◽  
Hai Lin

Abstract All-inorganic dual-phase CsPbBr3-Cs4PbBr6 quantum dots (CPB QDs)-based polyacrylonitrile (PAN) fiber synthesized by supersaturated recrystallization and electrospinning technique possesses characteristics of homogeneous morphology, high crystallinity and solution sensitivity. Under 365 nm laser excitation, CPB@PAN fiber exhibits surprising trace-recording capability attributing to the splash-enhanced fluorescence (FL) performance with a narrow-band emission at 477-515 nm. In the process of ethanol-anhydrous (EA) and water splashing, the CPB@PAN fiber presents conspicuous blue and green emission when contacting with EA and water, and maintains intense blue and green FL for more than 4 months. These experimental and theoretical findings provide a facile technology for the development of biological protection display, biotic detection and moisture-proof forewarning based on the trace-recording performance of CPB@PAN fiber.


Nanomaterials ◽  
2018 ◽  
Vol 8 (7) ◽  
pp. 538
Author(s):  
Pengpeng Ren ◽  
Wenfei Zhang ◽  
Yiqun Ni ◽  
Di Xiao ◽  
Honghao Wan ◽  
...  

Two-dimensional (2D) transition-metal dichalcogenides (TMDCs) quantum dots (QDs) are the vanguard due to their unique properties. In this work, WSe2 QDs were fabricated via one step ultrasonic probe sonication. Excitation wavelength dependent photoluminescence (PL) is observed from WSe2 QDs. Room-temperature lasing emission which benefits from 3.7 times enhancement of PL intensity by thermal treatment at ~470 nm was achieved with an excitation threshold value of ~3.5 kW/cm2 in a Fabry–Perot laser cavity. To the best of our knowledge, this is the first demonstration of lasing emission from TMDCs QDs. This indicates that TMDCs QDs are a superior candidate as a new type of laser gain medium.


Molecules ◽  
2021 ◽  
Vol 26 (16) ◽  
pp. 4994
Author(s):  
Weitao Li ◽  
Ningjia Jiang ◽  
Bin Wu ◽  
Yuan Liu ◽  
Luoman Zhang ◽  
...  

Biological imaging is an essential means of disease diagnosis. However, semiconductor quantum dots that are used in bioimaging applications comprise toxic metal elements that are nonbiodegradable, causing serious environmental problems. Herein, we developed a novel ecofriendly solvothermal method that uses ethanol as a solvent and doping with chlorine atoms to prepare highly fluorescent graphene quantum dots (GQDs) from seaweed. The GQDs doped with chlorine atoms exhibit high-intensity white fluorescence. Thus, their preliminary application in bioimaging has been confirmed. In addition, clear cell imaging could be performed at an excitation wavelength of 633 nm.


Inorganics ◽  
2021 ◽  
Vol 9 (10) ◽  
pp. 74
Author(s):  
Franz A. Mautner ◽  
Florian Bierbaumer ◽  
Roland C. Fischer ◽  
Ana Torvisco ◽  
Ramon Vicente ◽  
...  

Ten mononuclear rare earth complexes of formula [La(btfa)3(H2O)2] (1), [La(btfa)3(4,4′-Mt2bipy)] (2), [La(btfa)3(4,4′-Me2bipy)2] (3), [La(btfa)3(5,5′-Me2bipy)2] (4), [La(btfa)3(terpy)] (5), [La(btfa)3(phen)(EtOH)] (6), [La(btfa)3(4,4′-Me2bipy)(EtOH)] (7), [La(btfa)3(2-benzpy)(MeOH)] (8), [Tb(btfa)3(4,4′-Me2bipy)] (9) and (Hpy)[Eu(btfa)4] (10), where btfa = 4,4,4-trifuoro-1-phenylbutane-1,3-dionato anion, 4,4′-Mt2bipy = 4,4′-dimethoxy-2,2′-bipyridine, 4,4′-Me2bipy = 4,4′-dimethyl-2,2′-bipyridine, 5,5′-Me2bipy = 5,5′-dimethyl-2,2′-bipyridine, terpy = 2,2′:6′,2′-terpyridine, phen = 1,10-phenathroline, 2-benzpy = 2-(2-pyridyl)benzimidazole, Hpy = pyridiniumH+ cation) have been synthesized and structurally characterized. The complexes display coordination numbers (CN) eight for 1, 2, 9, 10, nine for 5, 6, 7, 8 and ten for 3 and 4. The solid-state luminescence spectra of Tb-9 and Eu-10 complexes showed the same characteristic bands predicted from the Tb(III) and Eu(III) ions. The Overall Quantum Yield measured (ϕTOT) at the excitation wavelength of 371 nm for both compounds yielded 1.04% for 9 and up to 34.56% for 10.


1990 ◽  
Vol 33 (8) ◽  
pp. 802-803
Author(s):  
V. I. Bobrik ◽  
A. Yu. Grachev ◽  
S. I. Kraval'

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