scholarly journals Mechanical properties of alkali activated geopolymer paste using different Romanian fly ash sources – experimental results

2019 ◽  
Vol 289 ◽  
pp. 11001 ◽  
Author(s):  
Adrian Lăzărescu ◽  
Călin Mircea ◽  
Henriette Szilagyi ◽  
Cornelia Baeră

As concrete demand is constantly increasing in recent years and also considering that cement production is both a consumer of natural resources and a source of carbon dioxide release into the atmosphere, there have been worldwide investigations into green alternatives for making concrete environmentally friendlier and simultaneously to satisfy the development of infrastructure facilities. The use of fly ash as a component of cementitious binders is not new but when considering the specific case of alkaline activation and fly ash representing the only source for the binder formation, it necessitates a more complete understanding of its specific reactions during the alkaline activation process. Since the fly ash varies dramatically, not only from one source to another, but also from one batch to another even when provided by the same power plant, its chemistry in obtaining alkali-activated materials during the geopolymerisation process and the final mechanical properties are considered crucial for the performance of geopolymer concrete. This paper will provide a review of the experimental results concerning the physical and mechanical evaluation of the alkali-activated fly ash-based geopolymer materials, developed with different types of fly ash, for a better understanding of geopolymer concrete production control.

2021 ◽  

Concrete is the most versatile, durable and reliable material and is the most used building material. It requires large amounts of Portland cement which has environmental problems associated with its production. Hence, an alternative concrete – geopolymer concrete is needed. The general aim of this book is to make significant contributions in understanding and deciphering the mechanisms of the realization of the alkali-activated fly ash-based geopolymer concrete and, at the same time, to present the main characteristics of the materials, components, as well as the influence that they have on the performance of the mechanical properties of the concrete. The book deals with in-depth research of the potential recovery of fly ash and using it as a raw material for the development of new construction materials, offering sustainable solutions to the construction industry.


Trials has been made to produce efficient GPC which gives maximum strength. By-Products from industries such as Fly-Ash, Metakaolin and GGBS can be used in concrete replacement which in-turn reduces carbon-di-oxide (CO2 ) emission affecting to green house. Using the above said products also leads to reduction of water demand in concrete and also shows comparatively no effects on long term effects in concrete, these by-products can effectively be used in concrete production. The high silica content in Fly-Ash and Metakaolin increases the bonding in concrete which in-turn increases the mechanical properties of concrete. Geopolymer concrete of M50 grade was proposed to be produced using fly-ash and Metakaolin instead of cement.Alklai solutions Sodium Hydroxide (NaOH), Sodium Silicate (Na2SiO3) were replaced with water for better bonding and mixing. Molarity of Sodium Hydroxide with 10M and 12M was considered for this study. Ratio of Alkaline solution were considered as 1:2,1:2.5&1:3 to determine the optimum ratio which gives effective strength. In this experimental study, tests were carried on concrete specimens with percentage replacement of Fly-Ash with Buff Metakaolin in variable percentages of 20,40,60,80&100. Mechanical properties of concrete specimens were studied and were compared with control mix results.


2019 ◽  
Vol 4 (2) ◽  
pp. 20 ◽  
Author(s):  
Ramamohana Reddy Bellum ◽  
Ruben Nerella ◽  
Sri Rama Chand Madduru ◽  
Chandra Sekhar Reddy Indukuri

Cement is one of the construction materials widely used around the world in order to develop infrastructure and it is also one of the factors affecting economies. The production of cement consumes a lot of raw materials like limestone, which releases CO2 into the atmosphere and thus leads to global warming. Many investigations are underway in this area, essentially focusing on the eco-accommodating environment. In the research, an alternative material to cement binder is geopolymer binder, with the same efficiency. This paper presents scanning electron microscope (SEM) and X-ray diffraction (XRD) analysis of factory byproducts (i.e., fly ash and ground granulated blast furnace slag (GGBFS)). The mix design process for the manufacture of alkali-activated geopolymer binders synthesized by fly ash and GGBFS is presented. The mechanical properties (compression, split tensile and flexural strength, bond strength) of geopolymer concrete at different mix proportions and at dissimilar curing conditions were also investigated. Geopolymer concrete synthesized with 30% fly ash and 70% GGBFS has better properties at 14 M of NaOH and cured in an oven for 24 h at 70 °C.


2019 ◽  
Vol 23 (9) ◽  
pp. 3875-3888 ◽  
Author(s):  
Anant Lal Murmu ◽  
Anamika Jain ◽  
Anjan Patel

2021 ◽  
Vol 11 (7) ◽  
pp. 3032
Author(s):  
Tuan Anh Le ◽  
Sinh Hoang Le ◽  
Thuy Ninh Nguyen ◽  
Khoa Tan Nguyen

The use of fluid catalytic cracking (FCC) by-products as aluminosilicate precursors in geopolymer binders has attracted significant interest from researchers in recent years owing to their high alumina and silica contents. Introduced in this study is the use of geopolymer concrete comprising FCC residue combined with fly ash as the requisite source of aluminosilicate. Fly ash was replaced with various FCC residue contents ranging from 0–100% by mass of binder. Results from standard testing methods showed that geopolymer concrete rheological properties such as yield stress and plastic viscosity as well as mechanical properties including compressive strength, flexural strength, and elastic modulus were affected significantly by the FCC residue content. With alkali liquid to geopolymer solid ratios (AL:GS) of 0.4 and 0.5, a reduction in compressive and flexural strength was observed in the case of geopolymer concrete with increasing FCC residue content. On the contrary, geopolymer concrete with increasing FCC residue content exhibited improved strength with an AL:GS ratio of 0.65. Relationships enabling estimation of geopolymer elastic modulus based on compressive strength were investigated. Scanning electron microscope (SEM) images and X-ray diffraction (XRD) patterns revealed that the final product from the geopolymerization process consisting of FCC residue was similar to fly ash-based geopolymer concrete. These observations highlight the potential of FCC residue as an aluminosilicate source for geopolymer products.


Polymers ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1473
Author(s):  
Jun Zhao ◽  
Kang Wang ◽  
Shuaibin Wang ◽  
Zike Wang ◽  
Zhaohui Yang ◽  
...  

This paper presents results from experimental work on mechanical properties of geopolymer concrete, mortar and paste prepared using fly ash and blended slag. Compressive strength, splitting tensile strength and flexural strength tests were conducted on large sets of geopolymer and ordinary concrete, mortar and paste after exposure to elevated temperatures. From Thermogravimetric analyzer (TGA), X-ray diffraction (XRD), Scanning electron microscope (SEM) test results, the geopolymer exhibits excellent resistance to elevated temperature. Compressive strengths of C30, C40 and C50 geopolymer concrete, mortar and paste show incremental improvement then followed by a gradual reduction, and finally reach a relatively consistent value with an increase in exposure temperature. The higher slag content in the geopolymer reduces residual strength and the lower exposure temperature corresponding to peak residual strength. Resistance to elevated temperature of C40 geopolymer concrete, mortar and paste is better than that of ordinary concrete, mortar and paste at the same grade. XRD, TGA and SEM analysis suggests that the heat resistance of C–S–H produced using slag is lower than that of sulphoaluminate gel (quartz and mullite, etc.) produced using fly ash. This facilitates degradation of C30, C40 and C50 geopolymer after exposure to elevated temperatures.


2016 ◽  
Vol 857 ◽  
pp. 400-404
Author(s):  
Tian Yu Xie ◽  
Togay Ozbakkaloglu

This paper presents the results of an experimental study on the behavior of fly ash-, bottom ash-, and blended fly and bottom ash-based geopolymer concrete (GPC) cured at ambient temperature. Four bathes of GPC were manufactured to investigate the influence of the fly ash-to-bottom ash mass ratio on the microstructure, compressive strength and elastic modulus of GPC. All the results indicate that the mass ratio of fly ash-to-bottom ash significantly affects the microstructure and mechanical properties of GPCs


2018 ◽  
Vol 761 ◽  
pp. 73-78 ◽  
Author(s):  
Matej Špak ◽  
Pavel Raschman

Alkali-activated materials based on fly ash are widely developed and also produced on the present. Some of fly ashes are not suitable for production of alkali-activated materials because of their inconvenient chemical composition. Alumina-silicates are the most important components that are needed to accomplish the successful reaction. The proper content of amorphous phase of alumina-silicates and its proportion as well should be provided for the final composition of alkali-activated materials. The influence of pure aluminum oxide powder as well as raw milled natural perlite on mechanical properties and durability of alkali-activated mortars was investigated. These minerals were used as partial replacement of fly ash coming from black coal combustion. In addition, the mortars were prepared by using different alkali activators.


Sign in / Sign up

Export Citation Format

Share Document