Comparison of ICP-MS and direct mercury analyzer for the analysis of mercury in pharmaceuticals

Planta Medica ◽  
2015 ◽  
Vol 81 (16) ◽  
Author(s):  
Y Kho ◽  
M Kim ◽  
NY Park ◽  
H Park ◽  
JH Shin
Keyword(s):  
Direct Mercury Analyzer ◽  
Icp Ms ◽  
Mercury Analyzer

Direct mercury analysis in environmental solids by ICP-MS with on-line sample ashing and mercury pre-concentration using a direct mercury analyzer

2015 ◽  
Vol 30 (7) ◽  
pp. 1668-1672 ◽  
Author(s):  
Derek D. Bussan ◽  
Ryan F. Sessums ◽  
James V. Cizdziel
Keyword(s):  
Inductively Coupled Plasma ◽  
Atomic Absorption Spectrophotometry ◽  
Inductively Coupled ◽  
Absorption Spectrophotometry ◽  
Mercury Analysis ◽  
Direct Mercury Analyzer ◽  
Icp Ms ◽  
On Line ◽  
Mercury Analyzer ◽  
Line Sample

A commercially available direct mercury analyzer (DMA) based on sample combustion, pre-concentration by amalgamation with gold, and atomic absorption spectrophotometry (AAS) was coupled to a sector field inductively coupled plasma mass spectrometer (ICP-MS).

scholarly journals Determination of Metals in Tree Rings by ICP-MS Using Ash from a Direct Mercury Analyzer

Molecules ◽  
2020 ◽  
Vol 25 (9) ◽  
pp. 2126
Author(s):  
Byunggwon Jeon ◽  
James V. Cizdziel
Keyword(s):  
Tree Rings ◽  
Loblolly Pine ◽  
Acid Digestion ◽  
Shortleaf Pine ◽  
Volatile Elements ◽  
Microwave Assisted ◽  
Direct Mercury Analyzer ◽  
Icp Ms ◽  
Mercury Analyzer

Elemental profiles in cores of tree trunks (bole wood) have been used for environmental monitoring and reconstruction of metal pollution history. Mercury (Hg) is a global pollutant that can be accurately measured in tree rings in a simple and pragmatic fashion using a direct mercury analyzer (DMA) that is based on thermal decomposition, amalgamation, and atomic absorption spectrophotometry. In this feasibility study, we demonstrate that the ash remaining after the DMA analyses can be used to quantify a wide range of other non-volatile elements (Ba, Be, Co, Cr, Cu, Fe, Ga, Mg, Mn, Ni, Pb, Sr, Th, and U) in that same sample of wood by inductively coupled plasma mass spectrometry (ICP-MS) after microwave-assisted acid digestion. Other elements (Ag, Cd, Cs, Rb, Tl, and V) exhibited poor recoveries, possibly due to losses during sample preparation. We assessed the accuracy with reference materials, spikes, and by comparison with EPA Method 3052 (Microwave Assisted Acid Digestion of Siliceous and Organically Based Matrices). For the first group of elements (deemed suitable for the method), recoveries ranged between 80% and 120% and the relative standard deviation was generally < 15%, indicating acceptable precision. We applied the method to five species of trees: eastern red cedar (Juniperus virginiana), loblolly pine (Pinus taeda), shortleaf pine (Pinus echinata), white oak (Quercus alba), and tulip poplar (Liriodendron tulipifera) from Holly Springs National Forest in north Mississippi, USA. Mercury concentrations (ng/g ± SE) were highest in the cedar (1.8 ± 0.3; n = 5), followed by loblolly pine (1.6 ± 0.3, n = 3), shortleaf pine (1.2 ± 0.2; n = 3), oak (1.1 ± 0.2; n = 5), and poplar (0.5 ± 0.1; n = 5). Concentrations of other elements were generally Fe > Mg > Ba ≈ Sr ≈ Mn > Cr ≈ Cu > Ni ≈ Rb > Co > Ga ≈ Ag, with the other elements generally below the method detection limit (MDL). Overall, we showed that the DMA can be used to not only determine total Hg in segments of tree core, but can serve as the ashing step in the preparation of wood for ICP-MS analysis, thus allowing the determination of non-volatile elements along with Hg in the very same sample.

scholarly journals Determination of Mercury in Ayurvedic Dietary Supplements That Are Not Rasa Shastra Using the Hydra-C Direct Mercury Analyzer

2013 ◽  
Vol 2013 ◽  
pp. 1-4
Author(s):  
Amir A. Abdalla ◽  
Robert E. Smith
Keyword(s):  
Dietary Supplements ◽  
Inductively Coupled Plasma ◽  
Microwave Digestion ◽  
Standard Reference Materials ◽  
Inductively Coupled ◽  
Mercury Analysis ◽  
Direct Mercury Analyzer ◽  
Icp Ms ◽  
Limit Of Quantitation ◽  
Mercury Analyzer

Mercury has been determined in Ayurvedic dietary supplements (Trifala, Trifala Guggulu, Turmeric, Mahasudarshan, Yograj, Shatawari, Hingwastika, Shatavari, and Shilajit) by inductively coupled plasma-mass spectrometry (ICP-MS) and direct mercury analysis using the Hydra-C direct mercury analyzer (Teledyne Leeman Labs Hudson, NH, USA). Similar results were obtained from the two methods, but the direct mercury analysis method was much faster and safer and required no microwave digestion (unlike ICP-MS). Levels of mercury ranged from 0.002 to 56 μg/g in samples of dietary supplements. Standard reference materials Ephedra 3240 and tomato leaves that were from the National Institute of Standard and Technology (NIST) and dogfish liver (DOLT3) that was from the Canadian Research Council were analyzed using Hydra-C method. Average mercury recoveries were 102% (RSD% 0.0018), 100% (RSD% 0.0009), and 101% (RSD% 0.0729), respectively. Hydra-C method Limit Of Quantitation was 0.5 ng.

scholarly journals Investigation of Hg Content by a Rapid Analytical Technique in Mediterranean Pelagic Fishes

2018 ◽  
Author(s):  
Giuseppa Di Bella ◽  
Roberta Tardugno ◽  
Nicola Cicero
Keyword(s):  
Mediterranean Sea ◽  
Mediterranean Area ◽  
Pelagic Fish ◽  
Analytical Technique ◽  
Weekly Intake ◽  
Tolerable Weekly Intake ◽  
Direct Mercury Analyzer ◽  
Mercury Analyzer ◽  
Global Concern ◽  
The Mediterranean

Mercury (Hg) fish and seafood contamination is a global concern and needs worldwide sea investigations in order to protect consumers. The aim of this study was to investigate the Hg concentration by means of a rapid and simple analytical technique with direct Mercury Analyzer (DMA-80) in pelagic fish species, Tetrapturus belone (spearfish), Thunnus thynnus (tuna) and Xiphias gladius (swordfish) caught in the Mediterranean Sea. Hg contents were evaluated also in Salmo salar (salmon) as pelagic fish not belonging to the Mediterranean area. The results obtained were variable ranging between 0,015-2,562 mg kg-1 for T. thynnus specie, 0,477-3,182 mg kg-1 for X. gladius, 0,434-1,730 mg kg-1 for T. belone and 0,004-0,019 mg kg-1 for S. salar, respectively. The total Hg tolerable weekly intake (TWI) and % tolerable weekly intake (TWI%) values according to the European Food Safety Authority (EFSA) were calculated. The results highlighted that the pelagic species caught in the Mediterranean Sea should be constantly monitored due to their high Hg contents as well as their TWI and TWI% with respect to S. salar samples.

scholarly journals Hg Levels in Marine Porifera of Montecristo and Giglio Islands (Tuscan Archipelago, Italy)

2020 ◽  
Vol 10 (12) ◽  
pp. 4342
Author(s):  
Camilla Roveta ◽  
Daniela Pica ◽  
Barbara Calcinai ◽  
Federico Girolametti ◽  
Cristina Truzzi ◽  
...  
Keyword(s):  
National Park ◽  
Total Mercury ◽  
Additional Data ◽  
Dry Weight ◽  
Mercury Content ◽  
Mediterranean Species ◽  
Direct Mercury Analyzer ◽  
Mercury Analyzer ◽  
Main Input ◽  
First Time

Porifera are filter-feeding organisms known to bioaccumulate different contaminants in their tissues. The presence of mercury (Hg) has been reported in different Mediterranean species, mainly collected in the southern coast of France. In the present study, mercury concentrations in the tissue of the sponges of Montecristo and Giglio, two islands of Tuscany Archipelago National Park (TANP), are presented for the first time. Analyses of total mercury content were performed by Direct Mercury Analyzer. Statistical differences have been reported in the Hg concentrations of species collected in both islands, but they do not appear related to the anthropic impacts of the islands. Among the collected species, a high intra- and inter-variability have been recorded, with Cliona viridis showing the lowest concentration (0.0167–0.033 mg·kg−1 dry weight), and Chondrosia reniformis and Sarcotragus spinosulus the highest (0.57 ± 0.15 and 0.64 ± 0.01 mg·kg−1 dry weight, respectively). The variability of Hg measured did not allow us to identify sponges as bioindicators of toxic elements. Anyway, these results improve knowledge on the ecosystem of the TANP, underlining the species-specificity of metal concentrations for Porifera, and providing additional data to address the main input of the Marine Strategy guidelines to protect coasts, seas and oceans.

scholarly journals Dredging Activities Carried Out in a Brazilian Estuary Affect Mercury Levels in Swimming Crabs

2020 ◽  
Vol 17 (12) ◽  
pp. 4396
Author(s):  
Paloma de Almeida Rodrigues ◽  
Rafaela Gomes Ferrari ◽  
Rachel Ann Hauser-Davis ◽  
Luciano Neves dos Santos ◽  
Carlos Adam Conte-Junior
Keyword(s):  
Total Mercury ◽  
Abiotic Factors ◽  
Human Consumption ◽  
Consumer Health ◽  
Swimming Crab ◽  
Health Issues ◽  
Guanabara Bay ◽  
Direct Mercury Analyzer ◽  
Mercury Analyzer

(1) Although suffers from intense pollution inputs, Guanabara Bay, the most socioeconomically and environmentally important estuary in Rio de Janeiro, Brazil, is still home to a diverse fauna, including several fish and crab species consumed by humans. The bay presents high sedimentation rates and sediment contamination, further aggravated by dredging processes carried out in recent years. In this context, this study aimed to verify the effect of the dredging process on total mercury (THg) concentrations at Guanabara Bay through swimming crab assessments sampled before (2016), during (2017), and after (2018) the dredging process, and mainly, if the detected concentrations can be harmful to consumer health; (2) Methods: Swimming crab samplings were carried out at the same time and sampling points in 2016, 2017 and 2018 and the total Hg was determined using a Direct Mercury Analyzer (DMA-80, Milestone, Bergamo, Italy); (3) Results: Increased Hg concentrations were observed during the dredging process, decreasing to lower values, close to the initial concentrations, at the end of the process. Some of the investigated abiotic factors favor Hg dynamics in the aquatic environment, while others were positively altered at some of the assessed sampling areas at the end of the dredging process; (4) Conclusions: Although crab Hg levels were below maximum permissible limits for human consumption, it is important to note that these animals are significantly consumed around Guanabara Bay, which may lead to public health issues in the long term.

scholarly journals Direct Mercury Analyzer (DMA) determination of mercury distribution in the sediments of lake Nokoué in Benin Republic-West Africa

2021 ◽  
Vol 15 (1) ◽  
pp. 306-316
Author(s):  
N.B. Nadia Azon ◽  
Peace Hounkpe ◽  
Julien G. Adounkpe ◽  
Hermione W. Degila ◽  
Martin P. Aina
Keyword(s):  
Mercury Content ◽  
Equal Mass ◽  
Mercury Contamination ◽  
Aquatic Life ◽  
Average Value ◽  
Direct Mercury Analyzer ◽  
Eastern Zone ◽  
The Us ◽  
Us Epa ◽  
Mercury Analyzer

Mercury pollution of water bodies constitutes a hazard to both the aquatic life and the populations consuming fishery products. To anticipate the probable eco-toxicological risks that may arise from the largest lake in southern Benin, the present work aims at assessing the mercury status of the sediments of Lake Nokoué, while identifying the areas exposed to anthropogenic mercury contamination. 45 sites were sampled according to a grid plan covering the entire ecosystem of the lake. Employing a Van Veen grab, surface sediments are collected at a depth from 0 to 5 cm in three catches at each site. The composite samples formed at equal mass on the three portions were frozen, lyophilized at - 40 °C, crushed, sieved and homogenized. Fraction less than 63 µm was collected for the mercury content determination by Direct Mercury Analyzer (DMA) operating by atomic absorption according to the US EPA 7473 method. The mercury concentration varies from 1.56 µg/kg to 164.88 µg/kg with an average value of 35.18 µg per kg of sediment. The south-eastern zone of the lake is more concentrated in mercury with a summation of the mercury content of 530.3 µg/kg of sediment. However, the lake has moderate contamination overall (1 ≤ FC ≤ 3). Keywords: Pollution, contamination, mercury, sediment, Lake Nokoué.

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